Estimation on organic carbon content of source rocks by logging evaluation method as exemplified by those of the 4th and 3rd members of the Shahejie Formation in western sag of the Liaohe Oilfield     

Luofu Liu  Xiaoqing Shang  Ping Wang  Yongqiang Guo  Weili Wang  Lin Wu 《中国地球化学学报》2012,31(4):398-407

One of the most important tasks of evaluating natural resources of petroliferous basins is to determine the organic matter abundance of source rocks in the basin.The usual method for assessing the organic carbon content of source rocks is based on laboratory analyses.There is a deviation in calculating organic carbon content due to the heterogeneous distribution of organic matter and the artificial factors when sampling.According to the continuous characteristics of information logging,the conventional logging curves(mainly acoustics and resistivity,etc.) were calibrated with the organic carbon experimental data of cores,cuttings or sidewall cores.The organic carbon content of source rocks of the 4 th(Es 4) and 3 rd(Es 3) members of the Shahejie Formation in western sag in the Liaohe depression was estimated directly by a great amount of continuous data including resistivity and acoustic logging,etc.Comparison between the results from computer processing and lab analysis of logging data shows that the organic carbon contents derived from the computer processing of logging data have the same reliability and accuracy as the lab analysis results.The present data show that this method is suitable to evaluate the source rocks of western sag in the Liaohe depression and has great potential in evaluating natural resources of sedimentary basins in the future.On the basis of logging data of source rocks,experimental data and existing geochemical analyses of the Liaohe Oilfield,the corresponding total organic carbon(TOC) isograms of source rocks were plotted.The source rocks of Es 4 and Es 3 of the Shahejie Formation are thought to be beneficial to hydrocarbon accumulation due to the high TOC.  相似文献   

Abundance and functions of natural organic matter species in soil and water     

Lars?J.?TranvikEmail author  Patrick?A.?W.?van Hees  Ulla?S.?Lundstr?m 《Aquatic Sciences - Research Across Boundaries》2004,66(2):149-150

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Anthropogenic impacts recorded in the sediments of Lunawa, a small tropical estuary, Sri Lanka     

N. P. Ratnayake  Y. Sampei  T. Tokuoka  N. Suzuki  H. Ishida 《Environmental Geology》2005,48(2):139-148

The Lunawa Estuary has been selected as a model for studying the long-term diagnoss of tropical estuarine pollution and its impact on ecosystems. Surface and short-core sediments from the Lunawa Estuary were collected, and analyzed for total organic carbon (TOC), nitrogen, sulfur and hydrocarbon contents, hydrogen index and other related sediment properties. Water quality and surface sediment data indicate that the Lunawa Estuary is presently an anoxic water body. The upper part of the sediment cores, characterized by very high TOC values of more than 10%, and absence of bioturbation along with strong laminations indicate anoxic water since 1970 AD, determined by ¹⁴ C dating. However, before 1970 AD, lower TOC content and presence of bioturbation and homogenous sediments with animal traces suggest the presence of oxic bottom water and thus a much better physicochemical condition. The lower part of the cores may also suggest the influence of gradual global warming. Regular laminations in the upper portions of the cores probably resulted from monsoon pulses with material preserved under anoxic condition.  相似文献   

Late Cenozoic Chemical Weathering and Environmental Changes Recorded in the Co Ngoin Sediments,Central Qinghai-Tibet Plateau   总被引：1，自引：2，他引：1  

CHEN Shiyue  JIN Zhangdong  WANG Sumin  SHEN Ji Nanjing Institute of Geography  Limnology  Chinese Academy of Sciences  Nanjing  Jiangsu  School of Environment  Planning  Liaocheng University  Liaocheng  Shandong Institute of Earth Environment  Chinese Academy of Sciences  Xi’an  Shaanxi 《《地质学报》英文版》2005,79(3):384-391

A series of faulted inland basins were developed in the central Qinghai-Tibet Plateau, among which the Co Ngoin Basin containing thick lacustrine sediments is located in the peripheral area of the Indian monsoon. In this paper, we present the weathering history and paleoclimatic changes in the last 2.8 Ma based on studies of high-resolution temporal distributions of Sr, Rb and Zr concentrations, Rb/Sr and Zr/Rb ratios and δ ^13C and TOC for the Co Ngoin sediments, in combination with the sediment properties, grain size distribution and clay mineralogy. The sedimentary records indicate three environmental stages in the last 2.8Ma. At the core depth of 197-170m (about 2.8-2.5Ma), low-intensity chemical weathering in the Co Ngoin catchment was experienced under warm-dry to cool-wet climate conditions with relatively low Sr concentration and high Rb/Sr and Zr/Rb ratios. The sudden occurrence of both subalpine coniferous forest and coarses and and gravel sediments in the Co Ngoin core reflects a strong tectonic uplift. The high Sr concentrations and low Rb/Sr and Zr/Rb ratios reflect a relatively strong chemical weathering between 2.5Ma and 0.8Ma (at the core depth of 170-38.5m) under a temperate/cool and wet climate, characterized by mud and silt with fine sand, probably indicating a stable process of denudation and planation of the plateau. Above the depth of 38.5m (about 0.8-0Ma), the coarsening of sediments indicates a strong tectonic uplift and a relatively low intensity of chemical weathering as supported by the record of sediments having relatively low Sr concentrations and high Rb/Sr and Zr/Rb ratios. Since then, the plateau has taken the shape of the modern topographic pattern above 4000m a.s.l.  相似文献   

张士灌区土壤中多环芳香烃菲(PHEs)的垂向分布与迁移     

孙大志  李绪谦  商书波  潘晓峰 《吉林大学学报(地球科学版)》2008,38(2):313-318

通过对典型环境功能区张士灌区包气带剖面样品和含水层样品的分析检测,比较和总结了菲的垂向分布特征,研究了总有机碳、粘粒含量、土壤含水率对菲垂向分布与迁移的影响规律和机理。对具有代表性采样点的研究表明,菲总含量在剖面中的变化趋势总体上随剖面的加深而降低,以犁底层为界,表层土壤(5~20 cm)菲含量随剖面深度变化平缓。同时分别对菲含量与总有机碳、土壤粘粒含量、土壤含水率进行二元相关分析,计算出的Pearson系数表明:土壤中总有机碳、土壤粘粒含量是影响菲垂向迁移的重要因素,而土壤含水率对菲垂向分布影响不大。同时利用SPSS的因子分析法进一步确定总有机碳是制约菲垂向运移的主要因素。  相似文献   

Preliminary Estimation of Paleoproductivity via TOC and Habitat Types： Which Method Is More Reliable？ -A Case Study on the Ordovician-Silurian Transitional Black Shales of the Upper Yangtze Platform, South China     

苏文博  王永标  Bradley  D  Cramer  AxelMunnecke  李志明  傅力浦 《中国地质大学学报(英文版)》2008,19(5):534-548

New total organic carbon (TOC) data from the two Ordovician-Silurian transitional graptolite-bearing black shale intervals, the Wnfeng (五峰) Formation and the Longmaxi (龙马溪) Formation in Central Guizhou (贵州) and West Hubei (湖北), respectively, as well as previously reported TOC data from the same intervals in other places on the Yangtze platform of South China, have been used to produce an initial estimate of the primary paleoproductivity via a conventional inverse method (i.e., Rpp-inverse). The values of the Rpp-inverse are estimated to be 32 (43-21) gC/(m2·a) (Wufeng Formation) and 21 (27-16) gC/(m2·a) (Longmaxi Formation). Also, simultaneously, the habitat types (i.e., HT; cf., BA: benthic assemblage) and their temporal and spatial changes have been documented from the same succession, and an initial estimate of the primary paleoproductivity has been produced using a forward method (i.e., Rpp.forward). Being bounded mainly by the peritidai to inner-shelf environment shelly-facies or mixed-facies successions with BAI to BA3 faunas both at the top and the base, which indicates the habitat types from HT Ⅱ1 to HT Ⅲ2, the biohabitat type of the two graptolite-bearing black shale intervals can be limited to HT Ⅲ to HT Ⅳ, corresponding to the inner shelf to the outer shelf, with depths from roughly 60 m to 200-300 m. Based on the current data from the South China Sea and the southern part of the East China Sea, values of Rpp-forward should be about 100 to 400 gC/(m2·a). The difference in the results via the two methods suggests that paleoproductivity estimates from the geological strata need to be made cautiously, with particular attention paid to the paleogeographic setting, oxic-anoxic conditions, as also the preservation factor of organic carbon.  相似文献   

甘南郎木寺中全新世泥炭总有机碳和脂类分子化合物的组合特征   总被引：5，自引：3，他引：2       下载免费PDF全文

周静  张平中  贾继红  王宗礼  王永莉  张虹  张德忠  桑文翠  吴秀平  王江林 《第四纪研究》2008,28(4):754-761

根据青藏高原东北部甘肃南部郎木寺泥炭总有机碳含量的时间序列,重建了该区7.3～4.0kaB.P.（中全新世）期间气候演变的历史,其中较为显著的变冷事件分别集中在6.8cal.kaB.P.,5.0cal.kaB.P.和4.3cal.kaB.P.。同时分析了3个不同深度的泥炭脂类分子化合物。结果表明,正构烷烃和直链烷基-2-酮都由长链组分所构成,具有明显的奇碳优势和很高的碳优势指数值（CPI>5）表明,这些长链组分来自草本高等植物。样品中还检出脂肪酸甲酯系列,也以长链组分为主,可能是沉积早期生物地球化学作用的产物。异构烯烃的存在及菲系列化合物低的甲基菲指数（MPI）和镜质体反射率（Rc）值,说明样品受成岩作用的影响很小而且几乎没有遭受现代的污染,即泥炭保存完好,各个指标可以真实反映泥炭的组成、性质及其形成时的环境条件。根据总有机碳含量的时间序列和不同阶段样品中的脂类分子化石的组合特征,探讨了各阶段气候和植被的演化特征。  相似文献   

过硫酸钾氧化法测定水中总有机碳     

董振芳  刘峰  姚乔尔 《海洋科学进展》2002,20(2):113-117

根据《海洋监测规范》规定的总有机碳分析方法 ,利用HW 5 61 0非色散红外CO2 气体分析仪 ,设计制造成功总有机碳分析装置 ,对《海洋监测规范》的方法进行了根本的改进 ,方法成熟可靠。用该仪器和方法测定TOC ,检出限低于 0 .0 1mg/L ,重现性优于 1 % ,达到了与进口TOC分析仪相近的分析精度及再现性 ,而该TOC分析仪的制造成本仅相当于进口仪器价格的 1 / 1 0～ 1 / 5 ,值得海洋、河流、湖泊等有关监测和研究部门借鉴。  相似文献   

兰州市宛川河中段表层沉积物中重金属元素迁移富集特征   总被引：3，自引：0，他引：3  

刘艳  张成君  雷国良  杨奇丽  欧文佳  漆燕  缑晓辉 《沉积学报》2008,26(5):844-849

通过对兰州市宛川河中段双店子河段表层沉积物元素分析,结合有机质含量和粒度测试,运用聚类分析和相关分析的方法,研究了重金属元素在河流表层沉积环境中的分布及迁移富集等地球化学行为与特征。结果表明Zn元素在研究河段有轻度污染;相关分析表明重金属元素含量与沉积物粒度之间无显著相关性,重金属元素主要是在固-液平衡体系中、通过多相化学反应形成沉淀。污染源分析表明,造纸污水的排放是造成研究区域中上游河段有机质含量较高的主要原因,大分子有机物质的存在不仅改变了此段河流沉积物粒度的变化,且有机质对重金属元素的富集有一定减缓作用。  相似文献   

鄂尔多斯盆地合水地区长7致密油岩性岩相类型识别及其应用   总被引：2，自引：1，他引：1       下载免费PDF全文

冉冶  王贵文  周正龙  赖锦  代全齐  陈晶  范旭强  王抒忱 《中国地质》2016,(4):1331-1340

利用岩心、薄片、常规测井、成像测井等资料结合物性分析等,对鄂尔多斯盆地合水地区长7致密油岩性岩相等特征进行了研究。长7致密油储层以砂质碎屑流、浊流和滑塌成因的砂岩为主,烃源岩以泥岩、油页岩为主,根据粒度参数进一步将长7致密油岩性岩相划分为砂质碎屑流细砂岩相、浊流细砂岩相、浊流粉砂岩相、滑塌岩相、半深湖—深湖泥岩相以及油页岩相6类。通过岩心刻度常规和成像测井,建立了不同岩性岩相的测井识别评价标准,并实现了各单井纵向上的岩性岩相的识别和划分。在此基础上,进一步探讨了不同岩性岩相与TOC含量和脆性指数的关系。最后结合试油气资料和油气解释结论,阐明岩性岩相对致密油储层物性和含油气性的定量控制。致密油岩性岩相的研究可为后期成岩相、孔隙结构以及优质储集体预测等奠定基础,为研究区长7致密油的综合评价和有利发育区带预测提供理论指导和技术支持。  相似文献