Opening of the Fram Strait gateway: A review of plate tectonic constraints   总被引：1，自引：0，他引：1  

  yvind Engen  Jan Inge Faleide  Toril Karlberg Dyreng 《Tectonophysics》2008,450(1-4):51-69

We have revised the regional crustal structure, oceanic age distribution, and conjugate margin segmentation in and around the Lena Trough, the oceanic part of the Fram Strait between the Norwegian–Greenland Sea and the Eurasia Basin (Arctic Ocean). The Lena Trough started to open after Eurasia–Greenland relative plate motions changed from right-lateral shear to oblique divergence at Chron 13 times (33.3 Ma; earliest Oligocene). A new Bouguer gravity map, supported by existing seismic data and aeromagnetic profiles, has been applied to interpret the continent–ocean transition and the influence of Eocene shear structures on the timing of breakup and initial seafloor spreading. Assuming that the onset of deep-water exchange depended on the formation of a narrow, oceanic corridor, the gateway formed during early Miocene times (20–15 Ma). However, if the initial Lena Trough was blocked by terrigenous sediments or was insufficiently subsided to allow for deep-water circulation, the gateway probably formed with the first well developed magnetic seafloor spreading anomaly around Chron 5 times (9.8 Ma; Late Miocene). Paleoceanographic changes at ODP Site 909 (northern Hovgård Ridge) are consistent with both hypotheses of gateway formation. We cannot rule out that a minor gateway formed across stretched continental crust prior to the onset of seafloor spreading in the Lena Trough. The gravity, seismic and magnetic observations question the prevailing hypotheses on the Yermak Plateau and the Morris Jesup Rise as Eocene oceanic plateaus and the Hovgård Ridge as a microcontinent.  相似文献   

华北克拉通破坏与岩石圈减薄   总被引：20，自引：2，他引：18  

嵇少丞  王茜  许志琴 《地质学报》2008,82(2):174-193

古太古代（约4.0 Ga）时地球上可能只有一个超级大陆, 它的岩石圈厚度高达400 km。在早元古代,这个超级大陆减薄、裂解成十几块,每块中心是太古宙岩石,边缘是元古宙岩石,且各块厚度不等（150~350km）。从元古宙之后这些被称之为稳定克拉通的大陆岩石圈就一直漂游在地幔软流圈之上。中国华北地块就是这些克拉通之一,与众不同的是它在中生代时遭受了第二次破坏,岩石圈厚度从古生代时的180~200 km 减少到现今的80~100 km。本文作者从流变学的视角出发,围绕华北克拉通破坏和岩石圈减薄这一核心问题,从  相似文献   

Sulfur isotope measurement of sulfate and sulfide by high-resolution MC-ICP-MS   总被引：4，自引：0，他引：4  

Paul R. Craddock  Olivier J. Rouxel  Lary A. Ball  Wolfgang Bach   《Chemical Geology》2008,253(3-4):102-113

We have developed a technique for the accurate and precise determination of ³⁴S/³²S isotope ratios (δ³⁴S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O₂⁺. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical.  相似文献   

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary     

Y. Y. Zhang  E. R. Zhang  J. Zhang 《Environmental Geology》2008,53(8):1751-1766

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.  相似文献   

Impact evaluation on groundwater of the infiltration of an urban wastewater geopurification system placed over a detrital aquifer in a semiarid region (Spain)     

L. Moreno  J. J. Durán  M. A. Casermeiro  J. R. Quintana  Ma A. Fernández 《Environmental Geology》2008,54(3):465-477

Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass discharged was relatively large (COD 14,656 g/m², NO₃ 85 g/m², NO₂ 4 g/m², NH₄ 2,425 g/m², PO₄ 1,143 g/m², K 1,531 g/m², B 63 g/m²). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO₄ 94.4%, K 59.17%, N _total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water, and are proposed as the best indicators.  相似文献   

Application of MODFLOW and geographic information system to groundwater flow simulation in North China Plain, China   总被引：2，自引：0，他引：2  

Shiqin Wang  Jingli Shao  Xianfang Song  Yongbo Zhang  Zhibin Huo  Xiaoyuan Zhou 《Environmental Geology》2008,55(7):1449-1462

MODFLOW is a groundwater modeling program. It can be compiled and remedied according to the practical applications. Because of its structure and fixed data format, MODFLOW can be integrated with Geographic Information Systems (GIS) technology for water resource management. The North China Plain (NCP), which is the politic, economic and cultural center of China, is facing with water resources shortage and water pollution. Groundwater is the main water resource for industrial, agricultural and domestic usage. It is necessary to evaluate the groundwater resources of the NCP as an entire aquifer system. With the development of computer and internet information technology it is also necessary to integrate the groundwater model with the GIS technology. Because the geological and hydrogeological data in the NCP was mainly in MAPGIS format, the powerful function of GIS of disposing of and analyzing spatial data and computer languages such as Visual C and Visual Basic were used to define the relationship between the original data and model data. After analyzing the geological and hydrogeological conditions of the NCP, the groundwater flow numerical simulation modeling was constructed with MODFLOW. On the basis of GIS, a dynamic evaluation system for groundwater resources under the internet circumstance was completed. During the process of constructing the groundwater model, a water budget was analyzed, which showed a negative budget in the NCP. The simulation period was from 1 January 2002 to 31 December 2003. During this period, the total recharge of the groundwater system was 49,374 × 10⁶ m³ and the total discharge was 56,530 × 10⁶ m³ the budget deficit was −7,156 × 10⁶ m³. In this integrated system, the original data including graphs and attribution data could be stored in the database. When the process of evaluating and predicting groundwater flow was started, these data were transformed into files that the core program of MODFLOW could read. The calculated water level and drawdown could be displayed and reviewed online.  相似文献   

Anthropogenic affects on lake sedimentation process: a case study from Lake Sapanca, NW Turkey     

Alper Gürbüz  Ömer Feyzi Gürer 《Environmental Geology》2008,56(2):299-307

Lake Sapanca in NW Turkey is a fault originated freshwater basin fed by seasonally variable flows of 15 streams. Considerations of lake–river interaction, supported by statistical measures of 47 bottom samples, suggest that sediment transport and deposition within the lake is controlled by two types of human constructed structures in addition to natural factors: (1) the dykes constructed in the front of streams, which feed the lake by strong flows, to prevent the filling of lakebed by coarse-grained sediments; (2) the constructed regulator on the outflowing Çarksuyu stream results in a higher sedimentation rate of clay-sized material on the NE corner of the lake, which is extraordinary in the shelf environment.  相似文献   

Impacts of at-site wastewater disposal systems on the groundwater aquifer in arid regions: case of Sfax City, Southern Tunisia     

Ibticem Chamtouri  Habib Abida  Hafedh Khanfir  Salem Bouri 《Environmental Geology》2008,55(5):1123-1133

Groundwater in Sfax City (Tunisia) has been known since the beginning of the century for its deterioration in quality, as a result of wastewater recharge into the aquifer. An average value of 12 × 10⁶ m³ of untreated wastewater reaches the groundwater aquifer each year. This would result not only in a chemical and biological contamination of the groundwater, but also in an increase of the aquifer piezometric level. Quantitative impacts were evaluated by examining the groundwater piezometric level at 57 surface wells and piezometers. The survey showed that, during the last two decades, the groundwater level was ever increasing in the urban area with values reaching 7 m in part; and decreasing in Sidi Abid (agricultural area) with values exceeding −3 m. Groundwater samples for chemical and microbial analysis were collected from 41 wells spread throughout the study area. Results showed significantly elevated levels of sodium, chlorides, nitrates and coliform bacteria all over the urban area. High levels (NO₃: 56–254 mg/l; Na >1,500 mg/l; Coliforms >30/100 ml) can be related to more densely populated areas with a higher density of pit latrine and recharge wells. Alternatively results showed a very variable chemical composition of groundwater, e.g. electrical conductivity ranges from 4,040 to19,620 μs/cm and the dry residual varies between 1.4 and 14 g/l with concentrations increasing downstream. Furthermore a softening of groundwater in Set Ezzit (highly populated sector) was observed.  相似文献   

Hydrogeochemical investigations and groundwater provinces of the Friuli Venezia Giulia Plain aquifers,northeastern Italy   总被引：2，自引：0，他引：2  

Franco Cucchi  Giuliana Franceschini  Luca Zini 《Environmental Geology》2008,55(5):985-999

Water resources are a key factor, particularly for the planning of the sustainable regional development of agriculture, as well as for socio-economic development in general. A hydrochemical investigation was conducted in the Friuli Venezia Giulia aquifer systems to identify groundwater evolution, recharge and extent of pollution. Temperature, pH, electric conductivity, total dissolved solids, alkalinity, total hardness, SAR, Ca²⁺, Na⁺, K⁺, Mg²⁺, Cl⁻, SO₄ ²⁻, NO₃ ⁻, HCO₃ ⁻ _, water quality and type, saturation indexes and the environmental stable isotope δ¹⁸O were determined in 149 sampling stations. The pattern of geochemical and oxygen stable isotope variations suggests that the sub-surface groundwater (from phreatic and shallow confined aquifers) is being recharged by modern precipitations and local river infiltrations. Four hydrogeological provinces have been recognised and mapped in the Friuli Venezia Giulia Plain having similar geochemical signatures. These provinces have different degrees of vulnerability to contamination. The deep confined groundwater samples are significantly less impacted by surface activities; and it appears that these important water resources have very low recharge rates and would, therefore, be severely impacted by overabstraction.  相似文献   

Glacier change and glacier runoff variation in the Tuotuo River basin,the source region of Yangtze River in western China   总被引：3，自引：0，他引：3  

Yong Zhang  Shiyin Liu  Junli Xu  Donghui Shangguan 《Environmental Geology》2008,56(1):59-68

Glaciers in the Tuotuo River basin, western China, have been monitored in recent decades by applying topographical maps and high-resolution satellite images. Results indicate that most of glaciers in the Tuotuo River basin have retreated in the period from 1968/1971 to 2001/2002, and their shrinkage area is 3.2% of the total area in the late 1960s. To assess the influence of glacier runoff on river runoff, a modified degree–day model including potential clear-sky direct solar radiation has been applied to the glaciated regions of the river basin over the period 1961–2004. It was found that glacier runoff has increased in the last 44 years, especially in the 1990s when a two-thirds increase in river runoff was derived from the increase in glacier runoff caused by loss of ice mass in the entire Tuotuo River basin.  相似文献