DMS and SO2 at Baring Head, New Zealand: Implications for the Yield of SO2 from DMS     

Warren J. de Bruyn  Mike Harvey  Jill M. Cainey  Eric S. Saltzman 《Journal of Atmospheric Chemistry》2002,41(2):189-209

Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO₂) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO₂ diurnalcycles, consistent with the photochemical production of SO₂ from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO₂ from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO₂ yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO₂ yield is lower in the range of 20–40%.  相似文献   

全谱直读等离子发射光谱法直接测定天然矿泉水中的SO2-4   总被引：2，自引：0，他引：2  

查立新  刘洪青  马玲  戴先蓉 《安徽地质》2002,12(1):75-77

采用全谱直读等离子发射光谱(ICP-AES)直接测定天然矿泉水中SO2-4的方法在优化工作条件下SO42-的测定下限为0.09mgL-1,方法简便,快速,适用于批量生产.  相似文献   

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)   总被引：5，自引：0，他引：5  

Conxita Taberner  James D. Marshall†  James P. Hendry‡  Catherine Pierre§  & M. F. Thirlwall¶ 《Sedimentology》2002,49(1):171-190

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.  相似文献   

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur     

Shunso ISHIHARA  Myung–Shik JIN  Yoshimichi KAJIWARA 《Resource Geology》2002,52(1):41-48

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.  相似文献   

城市地区抗御地震灾害风险评估项目综述     

何玉林  韩渭宾  裴锡瑜  李广俊 《四川地震》2002,(4):35-38

城市地区抗御地震灾害风险评估项目系联合国在上世纪末为减轻地震灾害所实施的规模宏大，影响甚远的国际性研究项目，其宗旨是为了提高社会公众防灾意识，有效地减轻城市地区的地震灾害。这一历时2年的项目在有限的经费支持下，取得了令人瞩目的成绩。结合自贡市开展这个项目的实践。综合介绍和总结了该项目的情况及经验。  相似文献   

Evapotranspiration from citrus trees growing in sandy soilunder drip irrigation with saline water     

杨胜利  Tomohisa Yano 《中国科学D辑(英文版)》2002,45(Z1)

An experiment on evapotranspiration from citrus trees under irrigation with saline waterwas carried out for 4 months. Two lysimeters planted with a citrus tree in the green house wereused. One lysimeter was irrigated with saline water (NaCl and CaCl2 of 2000 mg/L equivalence,EC = 3.8 dS/m, SAR = 5.9) and the other was irrigated with freshwater using drip irrigation. Theapplied irrigation water was 1.2 times that of the evapotranspiration on the previous day.Evapotranspiration was calculated as the change in lysimeter weight recorded every 30 minutes.The lysimeters were filled with soil with 95.8% sand. The results of the experiment were as follows.(i) The evapotranspiration from citrus tree was reduced after irrigation with saline water. Theevapotranspiration returns to normal after leaching. However it takes months to exhaust the saltfrom the tree. ( ii ) To estimate the impact of irrigation with saline water on the evapotranspirationfrom citrus trees, the reduction coefficient due to salt stress (Ks) was used in this experiment.Evapotranspiration under irrigation with saline water (ETs) can be calculated from evapotranspira-tion under irrigation with freshwater (ET) by the equation ETs = Ks× ET. Ks can be expressed as afunction of ECsw. (iii) The critical soil-water electrical conductivity (ECsw) is 9.5 dS/m, beyondwhich adverse effects on evapotranspiration begin to appear. If ECsw can be controlled at below9.5 dS/m, saline water can be safely used for irrigation.  相似文献   

粘性泥石流残留层的形成及减阻作用--以云南蒋家沟泥石流为例   总被引：1，自引：0，他引：1  

张军  吴积善  游勇  程尊兰 《山地学报》2003,21(2):223-227

通过对云南蒋家沟粘性泥石流的野外观测 ,讨论了粘性泥石流残留层的定义特征 ,在大量实测数据基础上 ,分析了残留层易形成时段的特性 ;分别对一次泥石流过程、若干阵泥石流和一阵泥石流残留层的变化进行了相关分析 ;最后用观测数据分析了泥石流残留层的减阻作用  相似文献   

极地冰芯中记录的火山作用及其对气候的影响          下载免费PDF全文

闫明  汪大立  凌晓良  谭德军  李院生 《极地研究》2003,15(3):223-232

大多数火山喷发以强酸 (主要是硫酸 )的形式在极地冰芯中留下痕迹 ,通过冰芯连续电导率 (ECM)或各个雪冰样品SO42 - 浓度测定能够恢复历史上的火山作用。极地冰芯中已知年代的火山喷发还可用于冰芯定年。极地冰芯记录的火山信号大小依赖于火山喷发的规模和类型 ,火山喷发的地理位置和酸性气体组成 ,大气气溶胶传输 ,以及沉降地点的年积累率和沉积后生过程等。单个火山喷发通常会导致数月至数年的半球乃至全球范围的气候相对变冷 (这种现象在极区变得更明显 ) ,但过去大规模的爆炸性火山喷发对气候的影响及其与气候变化之间的联系仍有待于进一步研究  相似文献   

The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland     

孙玉壮  WILHELM PüTTMANN 《中国地球化学学报》2003,22(1):1-10

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.  相似文献   

依法行政做好防震减灾工作--纪念《中华人民共和国防震减灾法》实施5周年     

阎正萃  张跃平  郄晓芸 《山西地震》2003,(2):1-3

从立法、法制宣传、建立健全规章制度和科学规范的管理程序、公正严格执法、执法监督和法制工作队伍建设等6个方面，论述了做好防震减灾依法行政工作的重要性，指出。只有依法行政，才能保障防震减灾工作的顺利发展。  相似文献