The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

探测地雷技术研究综述     

WANG Shi-yu FENG Zhi-hui College of GeoExploration Science  Technology  Jilin University  Changchun  China 《吉林大学学报(地球科学版)》2006,(Z2)

高敏感度、高可靠度、低花费传感器是全自动或半自动探雷机器人的首要和绝对的选择。当前,有许多技术能够被选来综合使用以满足上述的要求。金属探测器是一种传统的、成熟可靠的探测技术。但是,现在多种地雷含有少量的金属或者不包含任何金属,造成了用金属探测器探雷的困难。目前迫切需要研究发展新颖的探测技术以消除100万颗地雷对许多国家的影响。  相似文献   

东天山晚古生代内生金属矿床成矿系列和成矿规律   总被引：12，自引：8，他引：12  

韩春明  毛景文等 《地质与勘探》2002,38(5):5-10

东天山造山带是我国重要的金铜矿产富集区之一，通过初步研究，按照成矿系列的学术思想将区内金属矿床划分为6个矿床成矿亚系列，并对每个成矿亚系列形成的构造环境和主要地质作用进行了简要论述，进而探讨了该地区区域成矿规律与构造演化的关系，总结了该地区构造活动的时－空演化导致该地区独具特色的内生金属矿床侧向分带现象。  相似文献   

阿尔金地区构造应力场及其对金属矿产分布的控制作用   总被引：2，自引：0，他引：2  

陈正乐  杨风等 《地质与勘探》2002,38(5):18-23

构造应力场研究可以为区域矿产预测提供依据。主要根据节理、擦痕的测试分析，结合区域构造解析，确定阿尔金山东西向拉配泉－－红柳沟构造带经历了三期不同方向的应力作用：印支期以前的南北向挤压作用，印支－燕山期的北西－南东向的挤压和中生代晚期－新生代北东东－南南西向的挤压；并利用有限元数值模拟前两期构造应力场的演变过程，进而讨论了区域构造应力场对内生金属矿产分布规律的控制作用指出了区域寻找大型内生金属矿产的有利地段。  相似文献   

An Agricultural Land Resource Assessment Study Based on GIS—An Example from Guiyang City     

刘建军  李春来  万鹰昕 《中国地球化学学报》2002,21(1):79-88

This paper assesses the agricultural land resources of Guiyang City by means of GIS,on the basis of the pressure-state-response model in which soil heavy metal contamination is selected as a pressure indicatror.he results suggest that most of the agricultural land resources are of good quality,However,there are 17.11km^2 dry land and paddy field,which belong to the region of serious heavy metal contamination and are not fit for planting crops.At the same time,the high quality plowland,which is suitable for cultivation,has decreased nearly by 1/3 due to soil heavy metal contamination.These findings may improve our understanding that it is very important to prevent and cure heavy metal contamination of Guiyang City.  相似文献   

Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia)     

O. S. Pokrovsky  J. Schott 《Chemical Geology》2002,190(1-4):141-179

The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.  相似文献   

河南省栾川县马圈一带银铅锌多金属找矿方向探讨     

宋要武 《华北地质》2002,(Z1)

马圈一带出露的主要地层为上元古界栾川群和中元古界官道口群 ,是Pb、Zn、Ag的主要含矿地层。燕山期花岗岩在空间上与矿化关系密切。矿体主要受北西向断裂控制 ,常分布在北西、北东向断裂构造交汇部位。根据地球化学特征、矿产分布规律和找矿标志 ,划分出百炉沟西凹—东凹—磨沟、百炉沟—黄花北沟—杨树凹等两个一级和银窝沟—大石渣沟—小石渣沟、板岔沟等两个二级找矿预测区。  相似文献   

华北地台北缘地球物理场特征与金属矿床预测   总被引：5，自引：0，他引：5       下载免费PDF全文

江为为  管志宁  郝天珧  黄临平 《地球物理学报》2002,45(2):233-245

对华北地台北缘的地球物理场特征进行了探讨,根据重、磁异常数据反演计算了该地区的莫霍界面、居里界面、磁性界面的起伏.利用地球物理场资料和反演计算结果对该地区的构造格架和断裂进行了推断,同时预测了9个成矿远景区:(1)集宁一呼和浩特金成矿区;(2)张家口一赤城金、银多金属成矿区;(3)密云一高岭金、铜成矿区;(4)青龙一马兰庄金成矿区;(5)秦皇岛、金多金属成矿区;(6)郝家营多金属成矿区;(7)承德地区金、多金属成矿区;(8)赤峰一喀喇沁旗金成矿区;(9)宁城东金、多金属成矿区.  相似文献   

海南省五指山土壤中的重金属元素含量   总被引：6，自引：0，他引：6  

廖金凤 《山地学报》2003,21(2):169-172

海南省地处热带地区，山地面积占25．4％，五指山是海南山地的核心，也是海南最高峰，从下而上依次分布着砖红壤、赤红壤、黄壤、灌丛草甸土。五指山土壤普遍遍缺，而Zn、Ni、Pb、Cd、Cr、Co含量属正常值。在成土过程中，Cd有一定积累，其他元素有明显淋溶。在自下而上的垂直带谱中，Zn、Co含量呈现递减，Cd则相反，Ni、Pb、Cu、Cr含量呈现波浪式变化。气候因素是影响五指山土壤重金属元素含量及分布的主导因素。  相似文献   

Sensitivity Analysis of a Feedforward Neural Network for Considering Genetic Mechanisms of Kuroko Deposits     

Matsuda  Setsuro  Koike  Katsuaki 《Natural Resources Research》2003,12(4):291-301

Exploration for volcanogenic massive sulfide deposits of the kuroko-type is underway in many places. Clarifying the spatial patterns of the metals in kuroko deposits will be useful for understanding their genetic mechanisms and for future exploration of such types of deposits. This study represents a spatial distribution analysis on the contents of principal metals of kuroko deposits: Cu, Pb, and Zn, in the Hokuroku district, northern Japan, by a feedforward neural network and 1917 sample data at 143 drillhole sites. The network, which consists of three layers, was trained by the principle of SLANS in which the numbers of neurons in the middle layer and training data are changed to improve estimation accuracy. Using the weight coefficients connecting adjacent neurons, sensitivity analysis of the neural network was carried out to identify factors influencing spatial distributions of the three metals. The coordinates depth (z) direction, Bouguer gravity, and specific lithology such as dacite were determined to be influencing factors. The high frequency of the z coordinate signifies that the metal contents differ to a large extent by depth. The sensitivity vector was defined using sensitivity coefficients for x, y, and z coordinates of an estimation point. We determined that the directions of large vectors were different inside and outside of the Hanawa-Ohdate area. This characteristic is considered to originate from the differences in the permeability of fractures that became the paths for rising ore solutions, and the depths that the solutions mixed with sea water.  相似文献