无载气氢化物发生－石英缝管捕集原子吸收光谱法测定地质试样中的铋     

陈恒武  褚人才  吴德秀 《岩矿测试》1994,(4):298-301

文章介绍石英缝管原子捕集技术在氢化物－火焰原子吸收光谱法测定Ｂｉ中的应用。采用自制的无载气氢化物发生装置，对实验条件进行了最佳化。实验结果表明，原子捕集技术的应用使氢化物－火焰原子吸收法的灵敏度提高２．２倍；方法检出限（３σ）达２．５ｎｇ；２０ｎｇ／ｍｌＢｉ的标准溶液１０次测定的ＲＳＤ为２．９％。方法用于地质标样中微量Ｂｉ的测定，结果与推荐值符合。  相似文献   

用双硫腙－泡沫塑料反相色层萃取原子吸收法测定废水中的微量银   总被引：1，自引：0，他引：1  

衷明华  乐长高 《华东地质学院学报》1994,(4)

本文研究了双硫腙负载的聚氨酯泡沫塑料对水溶液中银离子的反相色层萃取行为，试验了Ｐｈ，流速、洗脱液及洗脱方法的影响。回收率试验表明，该法能定量捕集废水中银离子，结果令人满意。  相似文献   

Measurements of tropospheric OH concentrations: A comparison of field data with model predictions     

D. Perner  U. Platt  M. Trainer  G. Hübler  J. Drummond  W. Junkermann  J. Rudolph  B. Schubert  A. Volz  D. H. Ehhalt  K. J. Rumpel  G. Helas 《Journal of Atmospheric Chemistry》1987,5(2):185-216

Using long path UV absorption spectroscopy we have measured OH concentrations close to the earth's surface. The OH values observed at two locations in Germany during 1980 through 1983 range from 0.7×10⁶ to 3.2×10⁶ cm^-3. Simultaneously we measured the concentrations of O₃, H₂O, NO, NO₂, CH₄, CO, and the light non methane hydrocarbons. We also determined the photolysis rates of O₃ and NO₂. This allows calculations of OH using a zero dimensional time depdendent model. The modelled OH concentrations significantly exceed the measured values for low NO _x concentrations. It is argued that additional, so far unidentified. HO _x loss reactions must be responsible for that discrepancy.  相似文献   

小秦岭石英脉（构造带）含金性评价的包裹体指标研究     

卿敏  白万成 《黄金地质》1995,1(3):54-60

选择了小秦岭含金石英脉脉石英的显微镜下特征、红外光谱及近脉（矿）围岩全岩爆裂温测等３种包裹体研究方法，对比研究了东闯金、铅矿区和杨砦峪矿区不同含金性石英脉、含矿脉中的富矿、贫矿地段及矿体不同部位的包裹体特征，提出出了石英脉含金性评价及差别矿体剥蚀程度的包裹体指标。  相似文献   

赤砂沸石对氮磷钾吸附与释放的研究     

胡预生  马友华  周自默 《安徽地质》1995,(4)

本文以安徽省繁昌县赤砂沸石为试验材料，以黄红壤为参照，研究了丝光沸石为主的天然沸石对ＮＨ、Ｈ＿２ＰＯ及Ｋ￣＋的吸附与释放，结果表明：赤砂沸石的吸铵量和吸磷量为黄红壤的３倍；其中易释放铵和可释放铵占总吸铵量８０％以上；易释放磷和可释放磷占７０％以上；赤砂沸石的速效钾含量为黄红壤的７倍左右，而钾位缓冲容量（ＰＢＣ￣Ｋ）则为黄红壤的３５倍左右。赤砂沸石用做肥料调理剂和土壤改良剂，将能够减少土壤中氮、磷、钾的流失，并提高肥料中养分的利用率。  相似文献   

Ultraviolet absorption spectra of some Br-containing haloalkanes     

V. L. Orkin  E. E. Kasimovskaya 《Journal of Atmospheric Chemistry》1995,21(1):1-11

The ultraviolet absorption cross sections were measured for CF₃Br, CF₂ClBr, CF₂Br-CF₂Br, CF₂Br₂, CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃ in the wavelength range 190–320 nm at 295 K. The photolysis is concluded to be the minor atmospheric sink for CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃.  相似文献   

大气中微量气体的红外吸收          下载免费PDF全文

王松皋  张广顺 《应用气象学报》1995,6(1):70-75

文章介绍了测定大气中微量气体CO2与CH4透过率的试验。所用的主要设备是FTIR分光计及可变光程吸收池。文中叙述了主要实验结果与数据处理方法，同时用FASCODE-2程序计算了对应实验条件下CO2与CH4的透过率，并与实验结果作了比较。  相似文献   

紫外线辐射增加对大豆的影响及其估算   总被引：8，自引：0，他引：8       下载免费PDF全文

郑有飞  颜景义 《应用气象学报》1995,6(4):442-448

在田间及盆栽试验中观测到经超量紫外线（UV280～400 nm）辐射处理的大豆作物，其株型、生理活动及产量均受到不同程度的影响，其影响量随UV辐射强度，大豆品种以及环境条件不同而异。文章还给出了计算紫外线辐射对大豆影响程度的公式，该计算方法效果较好。  相似文献   

Coda waves: A review     

M. Herraiz  A. F. Espinosa 《Pure and Applied Geophysics》1987,125(4):499-577

The analysis and interpretation of coda waves have received increasing attention since the early seventies. In the past few years interest in this subject has spread worldwide, and the study of high-frequency seismic coda waves has become a very important seismological topic. As a conclusion of the studies accomplished in this time, coda waves are considered the result of scattering processes caused by heterogeneities acting on seismic waves.P andS waves play a particularly important role in this interaction. The process introduces an attenuation which, added to the intrinsic absorption, gives the observed apparent attenuation. Therefore, coda waves constitute a thumbprint left by the heterogeneities on the seismograms. Coda waves offer decisive information about the mechanism of how scattering and attenuation take place. This review describes coda waves in detail, and summarizes the work done in this subject to 1986. The relation between coda waves and attenuation in the context of research on seismic scattering problems is stressed. Particular attention has been given to the application of coda waves to estimate source and medium parameters. The state-of-the-art of the temporal variations of coda wave shape, and the possible use of these variations as an earthquake precursor also are presented. Care has been taken to introduce the statistical models used to deal with the heterogeneities responsible for scattering.  相似文献   

镉—5—Br—PADAP—溴化十六烷基三甲基铵—十八醇聚氧乙烯(20)醚显色体系的研究及应用     

周发连  周文 《华东地质学院学报》1987,(1)

本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。  相似文献