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951.
In this article, by using the daily precipitation data measured at 58 meteorological stations, spatial and temporal variability of daily precipitation including zero rainfall values (called “precipitation”) and without zero rainfall values (called “rain”) and four precipitation extrema (P0, P20, P50, and P100 representing the daily precipitation with the magnitude smaller than 0.1 mm, bigger than 20 mm, 50 mm, and 100 mm per day, respectively) in the Yangtze River Delta (YRD) during 1958–2007 were analyzed, and the effects of urbanization were further investigated. Results indicate that (i) differing from the downward trends in 1958–1985, daily precipitation and rain in 1986–2007 show slowly downward trends in the mid YRD but show upward trends in the northern and southern YRD. (ii) Spatial and temporal variability of the rain is more complex than daily precipitation. Both of them become smaller but show more obvious fluctuations in 1986–2007. (iii) Urbanizations cause not only the urban rainfall island problem but also more obvious fluctuations of rain intensity in the mid YRD, reflecting more uncertainty of daily precipitation variability. (iv) Urbanizations have little effects on the variability of P0 and P100 but cause notable increases of P20 and P50. (v) The spatial variability of daily precipitation and precipitation extrema in 1958–1985 clearly shows a breakpoint at 30°20′N latitude, but the breakpoint disappears afterward because of the effects of urbanization. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
952.
Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in 13C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C28 regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.  相似文献   
953.
Spatial and temporal distributions of nutrients (N and P) and heavy metals (Cu, Zn, Pb and Cd) in the intertidal sediments at Dongtan wetland of the Changjiang River (Yangtze River) Estuary were examined by laying one transect running seaward to landward during January, April, June, August and October of 2005. Total nitrogen (TN) and heavy metal concentrations in the intertidal sediment showed an increasing trend from open bare °at to the high marsh, with the maximum concentrations in the high marsh and the minimum values in open bare °at. In contrast, sediment total phosphorus (TP) concentrations changed little among sampling sites. One-way ANOVA found that there were signiˉcantly temporal variations of nutrients and heavy metals concentrations in the intertidal sediment (P <0.05). The concentrations of heavy metals generally showed an increasing trend from January to October. As compared with other large estuaries, heavy metal contamination in the intertidal sediment of the Changjiang River Estuary was relatively low.  相似文献   
954.
The Red River shear zone (RRSZ) is a major left‐lateral strike‐slip shear zone, containing a ductilely deformed metamorphic core bounded by brittle strike‐slip and normal faults, which stretches for >1000 km from Tibet through Yunnan and North Vietnam to the South China Sea. The RRSZ exposes four high‐grade metamorphic core complexes along its length. Various lithologies from the southernmost core complex, the Day Nui Con Voi (DNCV), North Vietnam, provide new constraints on the tectonic and metamorphic evolution of this region prior to and following the initial India–Asia collision. Analysis of a weakly deformed anatectic paragneiss using PT pseudosections constructed in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O (MnNCKFMASHTO) system provides prograde, peak and retrograde metamorphic conditions, and in situ U–Th–Pb geochronology of metamorphic monazite yields texturally controlled age constraints. Tertiary metamorphism and deformation, overprinting earlier Triassic metamorphism associated with the Indosinian orogeny and possible Cretaceous metamorphism, are characterized by peak metamorphic conditions of ~805 °C and ~8.5 kbar between c. 38 and 34 Ma. Exhumation occurred along a steep retrograde P–T path with final melt crystallizing at the solidus at ≥~5.5 kbar at ~790 °C. Further exhumation at ~640–700 °C and ~4–5 kbar at c. 31 Ma occurred at subsolidus conditions. U–Pb geochronological analysis of monazite from a strongly deformed pre‐kinematic granite dyke from the flank of the DNCV provides further evidence for exhumation at this time. Magmatic grains suggest initial emplacement at 66.0 ± 1.0 Ma prior to the India–Asia collision, whereas grains with metamorphic characteristics indicate later growth at 30.6 ± 0.4 Ma. Monazite grains from a cross‐cutting post‐kinematic dyke within the core of the DNCV antiform provide a minimum age constraint of 25.2 ± 1.4 Ma for the termination of fabric development. A separate and significant episode of monazite growth at c. 83–69 Ma is suggested to be the result of fluid‐assisted recrystallization following the emplacement of magmatic units.  相似文献   
955.
Annual export of 11 major and trace solutes for the Yukon River is found to be accurately determined based on summing 42 tributary contributions. These findings provide the first published estimates of tributary specific distribution of solutes within the Yukon River basin. First, we show that annual discharge of the Yukon River can be computed by summing calculated annual discharges from 42 tributaries. Annual discharge for the tributaries is calculated from the basin area and average annual precipitation over that area using a previously published regional regression equation. Based on tributary inputs, we estimate an average annual discharge for the Yukon River of 210 km3 year–1. This value is within 1% of the average measured annual discharge at the U.S. Geological Survey gaging station near the river terminus at Pilot Station, AK, for water years 2001 through 2005. Next, annual loads for 11 solutes are determined by combining annual discharge with point measurements of solute concentrations in tributary river water. Based on the sum of solutes in tributary water, we find that the Yukon River discharges approximately 33 million metric tons of dissolved solids each year at Pilot Station. Discharged solutes are dominated by cations calcium and magnesium (5.65 × 109 and 1.42 × 109 g year–1) and anions bicarbonate and sulphate (17.3 × 109 and 5.40 × 109 g year–1). These loads compare well with loads calculated independently at the three continuous gaging stations along the Yukon River. These findings show how annual solute yields vary throughout a major subarctic river basin and that accurate estimates of total river export can be determined from calculated tributary contributions. Copyright © 2011. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   
956.
957.
Abstract

In ice forecasting, a key problem is the forecast of freeze-up and break-up dates. Ice-water mechanics and the principle of heat-exchange were mainly adopted in previous research. However, the mathematical models in these studies are complex and many parameters are required in relation to upstream and/or downstream gauging stations. Moreover, too many assumptions or simplifications for these parameters and constraints directly lead to low accuracy of the models and limitations as to their practical applications. This paper develops a fuzzy optimization neural network approach for the forecast of freeze-up date and break-up date. The Inner Mongolia reach lies in the top north of the Yellow River, China. Almost every year ice floods occur because of its special geographical location, hydrometeorological conditions and river course characteristics. Therefore, it is of particular importance for ice flood prevention to forecast freeze-up date and break-up date accurately. A case study in this region shows that the proposed methodology may allow obtaining useful results.  相似文献   
958.
The Annualized Agricultural Non‐point Source (AnnAGNPS) pollution model has been widely used to assess and predict runoff, soil erosion, sediment and nutrient loading with a geographic information system. This article presents a case study of the effect of land‐use changes on nonpoint source (NPS) pollution using the AnnAGNPS model in the Xizhi River watershed, eastern Pearl River Delta of Guangdong province, China. The land‐use changes in the Xizhi River watershed between 1998 and 2003 were examined using the multitemporal remote sensing data. The runoff, soil erosion, sediment transport and nutrient loading 1998 and 2003 were assessed using AnnAGNPS. The effects of land‐use changes on NPS were studied by comparing the simulation results of each year. Our results showed that (i) the NPS loadings increased when forest and grass land converted into paddy, orchard and farmland land, and population size and gross domestic product size as well as the usage amounts of fertilizer and pesticide in the entire watershed were firmly correlated with the NPS loadings; (ii) the land‐use change during fast urbanization in particular when other land types were converted into the development land and buildup land led to increasing of NPS pollution; and (iii) urban land expansion showed more important effects on total organic carbon (TOC) loading compared with nitrogen and phosphorus loadings. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
959.
The low and high flow characteristic of the Blue Nile River (BNR) basin is presented. The study discusses low and high flow, flow duration curve (FDC) and trend analysis of the BNR and its major tributaries. Different probability density functions were fitted to better describe the low and high flows of the BNR and major tributaries in the basin. Wavelet analysis was used in understanding the variance and frequency‐time localization and detection of dominant oscillations in rainfall and flow. FDCs were developed, and low flow (below 50% exceedance) and high flow (over 75% exceedance) of the curves were analysed and compared. The Gravity Recovery and Climate Experiment (GRACE) satellite‐based maps of monthly changes in gravity converted to water equivalents from 2003 to 2006 for February, May and September showed an increase in the moisture influx in the BNR basin for the month of September, and loss of moisture in February and May. It was also shown that 2004 and 2005 were drier with less moisture influx compared to 2003 and 2006. On the basis of the Kolmogorov‐Smirnov, Anderson‐Darling and Chi‐square tests, Gen. Pareto, Frechet 3P, Log‐normal, Log‐logistics, Fatigue Life and Phased Bi‐Weibull distributions best describe the low and high flows within the BNR basin. This will be beneficial in developing flow hydrographs for similar ungauged watersheds within the BNR basin. The below 50% and above 75% exceedance on the FDC for five major rivers in addition to the BNR showed different characteristics depending on size, land cover, topography and other factors. The low flow frequency analysis of the BNR at Bahir Dar showed 0·55 m3/s as the monthly low flow with recurrence interval of 10 years. The wavelet analysis of the rainfall (at Bahir Dar and basin‐wide) and flows at three selected stations shows inter‐ and intra‐annual variability of rainfall and flows at various scales. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
960.
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