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采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。 相似文献
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新疆北部后碰撞与幔源岩浆有关的成矿谱系 总被引:18,自引:12,他引:6
新疆北部与后碰撞幔源岩浆作用有关的矿床主要有四类:铜镍硫化物矿床、钒钛磁铁矿矿床、钛铁矿-铜镍硫化物复合矿床和玄武岩型自然铜矿床。上述四类矿床成矿时代相近(主成矿期为二叠纪),空间相邻,跨构造单元分布,彼此之间可出现过渡或复合矿床类型,构成了独特的后碰撞与幔源岩浆作用有关的成矿谱系,也是中亚型造山后碰撞阶段颇具特色的成矿组合。依据其成矿专属性的不同,新疆北部与幔源岩浆有关的矿床可分为两个系列:钛铁系列和铜镍系列。钛铁系列以尾亚矿床为代表,以高钛富碱为特征,为碱性系列,REE总量高,LREE富集,ε_(Nd)(t)近0值,其含矿岩体的地球化学特征与峨嵋大火成岩省钒钛磁铁矿含矿岩体特征一致,推测其含矿岩浆来源与地幔柱活动有关;而以黄山、喀拉通克为代表的铜镍矿床成矿岩体,以相对富镁为特征,属钙碱系列和拉斑玄武岩系列,REE总量较低,模式曲线呈LREE略富集的平缓型分布,ε_(Nd)(t)为明显的正值,可能来自亏损岩石圈地幔的部分熔融。新疆北部后碰撞阶段除发育了与幔源岩浆有关的成矿谱系外,还发育了与造山带有关的构造-岩浆-成矿体系。这种既有地幔柱成矿又有造山带成矿的双重特性,可能是二叠纪地幔柱活动与造山(后碰撞)作用叠加的结果。 相似文献
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Jesús M. Mercado Teodoro Ramírez Dolores Corts Marta Sebastin Andreas Reul Begoa Bautista 《Estuarine, Coastal and Shelf Science》2006,69(3-4):459
The changes in the phytoplankton absorption properties during a diurnal cycle were investigated at one station located in the north-western area of the Alborán Sea. The experiment was performed in spring when the water column was strongly stratified. This hydrological situation permitted the establishment of a deep chlorophyll a (chl a) fluorescence maximum (DFM) which was located on average close to the lower limit of the mixed layer and the nutricline. The relative abundance of pico-phytoplankton (estimated as its contribution to the total chl a) was higher in the surface, however, micro-phytoplankton dominated the community at the DFM level. Chl a specific absorption coefficient (a*(λ)) also varied with optical depth, with a* (the spectrally average specific absorption coefficient) decreasing by 30% at the DFM depth with respect to the surface. A significant negative correlation between the contribution of the micro-phytoplankton to the total chl a and a* was obtained indicating that a* reduction was due to changes in the packaging effect. Below the euphotic layer, a* increased three-fold with respect to the DFM, which agrees with the expected accumulation of accessory pigments relative to chl a as an acclimation response to the low available irradiance. The most conspicuous change during the diurnal cycle was produced in the euphotic layer where the chl a concentration decreased significantly in the afternoon (from a mean concentration of 1.1 μg L−1 to 0.7 μg L−1) and increased at dusk when it averaged 1.4 μg L−1. In addition, a* and the blue-to-red absorption band ratio increased in the afternoon. These results suggest that a*(λ) diurnal variability was due to increase in photo-protective and accessory pigments relative to chl a. The variation ranges of a*(λ) at 675 and 440 nm (the absorption peaks in the red and blue spectral bands, respectively) in the euphotic layer were 0.01–0.04 and 0.02–0.10 m2 mg−1 chl a, respectively. Approximately 30% out of this variability can be attributed to the diurnal cycle. This factor should therefore be taken into account in refining primary production models based on phytoplankton light absorption. 相似文献
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大菱鲆(Scophthalmus maximus)是中国重要的养殖鱼类之一, 其生活史经历不同的栖息地和光环境, 视觉器官结构及视觉功能也具有适应性发育特征和可塑性。本研究以不同发育阶段的大菱鲆幼鱼为对象, 探究了其视网膜结构变化、视蛋白基因的表达特征及其与光谱之间的关系。结果表明, 随着大菱鲆幼鱼的生长发育, 其视网膜的外核层逐渐变厚; 视锥视杆层的厚度变化不明显; 而内核层与神经节细胞层逐渐变薄。视紫红质基因rh1与视蛋白基因总表达量的比例上升, 由2月龄的57.35%上升到9月龄77.19%; 视锥蛋白基因与视蛋白基因总表达量的比例下降; 其中红视蛋白基因lws 由2月龄的4.49%下降至9月龄的0.13%。将7月龄的大菱鲆幼鱼用不同光谱处理75 d后, 其视蛋白基因的表达会随光谱环境的变化而发生改变。与全光谱相比, rh2b1、sws2、sws1在红、黄光下的表达量显著下降, 而rh2b1在蓝、绿光下表达显著上升、sws2在绿光下表达显著上升, 其他则变化不显著(P<0.05)。黄、绿、蓝及全光谱下rh2基因家族与视蛋白基因总表达量的比例最高, 而红光下基因rh1的表达量占比最高。大菱鲆幼鱼在不同阶段以及不同光谱处理下表现出了视蛋白基因表达的可塑性以适应不同水层的光谱环境。本研究为探究大菱鲆对光环境的适应机制及工厂化养殖光照调控技术的建立提供理论参考。 相似文献
27.
Diel patterns in the chlorophyll a specific absorption coefficient of surface picoplankton, a*pico (γ) (m2·[mg chlorophyll a]−1), were studied at 7 stations under daily cycle of in situ light condition in the western subarctic Pacific and Japan Sea. All the data were normalized by dividing the anomaly with daily averaged a*pico (γ). Opposite diel patterns were observed for the normalized a*pico (443) and a*pico (675) with maximum toward dawn or dusk and minimum toward midday at 4 stations under low-irradiance (LI) conditions and vice versa at 3 stations under high-irradiance (HI) conditions. The absorption efficiency factors at red absorption peak, Q
a (675), were determined by reconstruction with intracellular chlorophyll a concentration and cell diameter. The normalized Q
a (675) also showed diel pattern with maximum toward midday and minimum toward dawn or dusk under LI. The diel pattern in a*pico (675) and Q
a (675) were primarily caused by changes in intracellular chlorophyll a concentration due to photoadaptation under LI. The diel pattern in a*pico (443) was influenced by pigmentation, as recognized by blue to red ratio [a*pico (443)/a*pico (675)] under HI. This study proposed that the opposite diel pattern in a*pico (γ) might occur for a wide range of algal species. The results presented here have important consequences for the interpretation of diel variations in optical properties observed in the open ocean. 相似文献
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基于现场实验数据集及人工神经网络技术,论文提出了一种从海中粒子吸收光谱提取浮游植物吸收光谱的方法。这个数据集包含了海中粒子吸收光谱和对应的浮游植物吸收光谱,并被分为三个子集:训练集、印证集和试验集。本研究所利用的人工神经网络系统为多层感知器,训练后的人工神经网络的性能由印证集和试验集来评价。实验结果表明,文中所提出的方法可成功地提取浮游植物的吸收光谱,其提取精度与传统的实验方法相当。 相似文献
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