宝珠寺水电站坝基排水孔异常逸出物及其工程危害     

钱会  席临平  赵晓莉  肖莉 《地球科学与环境学报》2001,23(4):48-52

在阐述宝珠寺水电站工程拦河坝坝址区地质及水文地质条件的基础上,对宝珠寺水电站坝基排水孔异常逸出物的分布及其化学成分和矿物成分进行了研究,对异常逸出物的工程危害进行了讨论.结果表明,在宝珠寺水电站坝基排水孔中,异常逸出物主要出现在河床坝段,其成分主要是地层岩石中的一些常见元素及常见的成岩矿物,异常逸出物对大坝工程的危害主要体现在其本身及其形成过程中从大坝基础中携带出了大量的物质.  相似文献   

Targeting European R&D for accidental marine pollution     

Eva Garnacho  Robin J. Law  Ronny Schallier  Joan Albaiges 《Marine Policy》2010

Accidental marine pollution can have major ecological and economic consequences at national and trans-national levels, and there is a need to achieve a better integration of science into actual decision-making systems to support prevention measures, response systems and management activities.. Effective linking mechanisms between R&D and end-users/policy stakeholders are required to ensure the relevance of R&D, effective uptake of R&D outputs, and suitable policy development. Different issues and barriers to effectively link accidental marine pollution R&D effort to end-users concerns and needs and to develop a trans-national strategic approach are identified, analysed, and further developed into recommendations.  相似文献   

Chemistry of metal–humic complexes contained in Megalopolis lignite and potential application in modern organomineral fertilization     

Konstantinos Chassapis  Maria Roulia  Dimitra Tsirigoti 《International Journal of Coal Geology》2009,78(4):288-295

Lignite samples from two deposits located in the Megalopolis Basin, Southern Greece, were evaluated for their potential applicability as raw materials for the production of organomineral fertilizers. Fundamental chemical analyses were carried out to demonstrate high humic substances and metal contents. To determine their relative distribution in the Megalopolis lignite extract, eight elements, namely Na, K, Cd, Mn, Mg, Pb, Zn, and Cu, were studied both in H₂O and in Na₄P₂O₇/NaOH solutions. The behavior of these metals showed significant variations; Zn, Pb, Cd, and Cu associate mostly to the humic substances and proved scarce in the water extract. Contrarily, K and Mg gave a significantly low total yield in the Na₄P₂O₇/NaOH solution, while Mn was classified among the least extracted elements. Further enrichment of Megalopolis humic substances in these metals was achieved; Pb and Mg proved the most and least retained metal, respectively. Decomplexation titration curves of humic matter saturated with these metal ions demonstrated that novel organomineral fertilizing materials may develop based on optimized metal ion and humate contents, which can retain metals in a soluble form within a wide pH range. Formation of complexes between humic substances and Zn, Cd, and Mg was clearly indicated.  相似文献   

Evaluation of Greek low-rank coals as potential raw material for the production of soil amendments and organic fertilizers     

Andriana Giannouli  Stavros Kalaitzidis  George Siavalas  Adamantia Chatziapostolou  Kimon Christanis  Stefanos Papazisimou  Cassiani Papanicolaou  Antonis Foscolos 《International Journal of Coal Geology》2009,77(3-4):383-393

This study evaluates Greek peat and coal samples for applications in the agricultural/horticultural sector and assesses the suitability of a certain peat/coal either as soil conditioner or as raw material for manufacturing organic fertilizers.Twenty-six samples of different rank ranging from peat to subbituminous coal obtained from several Greek peat/coal deposits, were studied. The laboratory tests included: a) pH and electrical conductivity (EC) determinations, as well as proximate, ultimate and maceral analyses, in order to characterize the samples, b) major and trace element analyses of both the total and the easily exchangeable fractions (EEF), in order to assess the phytotoxicity effect, c) cation exchange capacity (CEC) determination in mixtures of the samples (5 wt.%) with a certain soil (95 wt.%), in order to evaluate the peat/coal impact, and d) the determination of the contents of humic substances (HS), as well as of carboxylic and phenolic groups.The majority of the samples reveal moderate to high ash yields (16–80 wt.%), a slightly acidic to neutral character and electrical conductivity ranging from 100–2500 μS/cm. Concerning the environmental impact of the sensitive trace elements, which might be leached, As, Mn, Ni and Sr show relatively strong mobilization in some samples, although severe impacts are not expected. The soil's CEC is generally improved, although it remains at moderate levels. The most interesting aspect is the humic acids content, which ranges between 9.6 and 52.2 wt.% on a dry basis, exceeding 25 wt.% for most of the samples. The obtained results enable an initial correlation among the different parameters and a rating of the samples according to their suitability for soil-amelioration agents.  相似文献   

Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances          下载免费PDF全文

Renato Henrique‐Pinto  Sarah‐Jane Barnes  Dany Savard  Sadia Mehdi 《Geostandards and Geoanalytical Research》2017,41(1):41-62

We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases.  相似文献   

安徽定远小庙山金矿床流体包裹体研究     

张军  杨劼  徐兆文  毛鸿丽 《岩石矿物学杂志》2010,29(5):551-561

小庙山金矿床原生流体包裹体分为4种类型:富气相的两相水溶液包裹体、富液相的两相水溶液包裹体、含CO2三相水溶液包裹体和含子矿物的三相水溶液包裹体,均一温度变化于133～378℃之间,峰值区间分别为180～200℃和220～260℃;盐度介于0.2%～44.6%之间,峰值区间为3%～6%。激光拉曼分析显示,流体包裹体的气相成分主要为CO2、H2O及少量CH4;包裹体群分析显示,成矿流体气相成分主要为CO2、N2、H2O、CH4、C2H2和C2H6,液相成分主要为Na+、K+、Ca2+、F-、Cl-、NO3-和SO42-,其中K+/Na+为1.55～2.75,F-/Cl-为0.02～0.03。矿化石英脉中,流体的δ18OH2O值介于-2.39‰～2.14‰之间,δDH2O值介于-51.2‰～-45.9‰之间,表明成矿流体主要来自岩浆,后期混入大气降水。依据成矿地质背景和矿区内成矿流体的地球化学及同位素资料,认为近南北向断裂是成矿流体运移通道和金富集沉淀的场所。在断裂破碎带中,高温高盐度成矿流体与大气降水混合,引起成矿流体的温度和盐度降低,压力变小,使得流体中的金沉淀成矿。  相似文献   

Dolomite formation within microbial mats in the coastal sabkha of Abu Dhabi (United Arab Emirates)   总被引：1，自引：0，他引：1  

TOMASO R. R. BONTOGNALI  CRISÓGONO VASCONCELOS  ROLF J. WARTHMANN  STEFANO M. BERNASCONI  CHRISTOPHE DUPRAZ  CHRISTIAN J. STROHMENGER  JUDITH A. McKENZIE 《Sedimentology》2010,57(3):824-844

Microbial mediation is the only demonstrated mechanism to precipitate dolomite under Earth surface conditions. A link between microbial activity and dolomite formation in the sabkha of Abu Dhabi has, until now, not been evaluated, even though this environment is cited frequently as the type analogue for many ancient evaporitic sequences. Such an evaluation is the purpose of this study, which is based on a geochemical and petrographic investigation of three sites located on the coastal sabkha of Abu Dhabi, along a transect from the intertidal to the supratidal zone. This investigation revealed a close association between microbial mats and dolomite, suggesting that microbes are involved in the mineralization process. Observations using scanning electron microscopy equipped with a cryotransfer system indicate that authigenic dolomite precipitates within the exopolymeric substances constituting the microbial mats. In current models, microbial dolomite precipitation is linked to an active microbial activity that sustains high pH and alkalinity and decreased sulphate concentrations in pore waters. Such models can be applied to the sabkha environment to explain dolomite formation within microbial mats present at the surface of the intertidal zone. By contrast, these models cannot be applied to the supratidal zone, where abundant dolomite is present within buried mats that no longer show signs of intensive microbial activity. As no abiotic mechanism is known to form dolomite at Earth surface conditions, two different hypotheses can reconcile this result. In a first scenario, all of the dolomite present in the supratidal zone formed in the past, when the mats were active at the surface. In a second scenario, dolomite formation continues within the buried and inactive mats. In order to explain dolomite formation in the absence of active microbial metabolisms, a revised microbial model is proposed in which the mineral‐template properties of exopolymeric substances play a crucial role.  相似文献   

Structural characterization of aquatic humic substances – The need for a multiple method approach     

Gudrun?Abbt-BraunEmail author  Ulrich?Lankes  Fritz?H.?Frimmel 《Aquatic Sciences - Research Across Boundaries》2004,66(2):151-170

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Abundance and functions of natural organic matter species in soil and water     

Lars?J.?TranvikEmail author  Patrick?A.?W.?van Hees  Ulla?S.?Lundstr?m 《Aquatic Sciences - Research Across Boundaries》2004,66(2):149-150

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Physico-chemical and biological sediment properties determining erosion resistance of contaminated riverine sediments – Temporal and vertical pattern at the Lauffen reservoir/River Neckar, Germany     

Sabine Ulrike Gerbersdorf  Thomas Jancke  Bernhard Westrich 《Limnologica》2005,35(3):132-144

In order to contribute to a reliable, easy-to-handle and economically viable erosion risk assessment of contaminated riverine sites, the present study aims to implement master-variables best characterising the sediment stability. Thus, a wide range of sediment properties was related to the critical shear stress for mass erosion, determined in the SETEG (Stroemungskanal zur Ermittlung der tiefenabhaengigen Erosionsstabilitaet von Gewaessersedimenten) pressurised channel, with special emphasis on vertical and temporal gradients in the Lauffen reservoir on the River Neckar. Over the course of 1 year, positive impacts of some macrofauna species and benthic diatoms on the sediment stability were detected for the sediment surface (0.5 cm). However, a high seasonal variability of biological parameters caused varying relations with erosion resistance in the upper sediment layers as shown for the colloidal carbohydrates. Considering only deeper sediment layers (5–35 cm), a more general pattern could be revealed with correlations between the critical shear stress and single sediment properties such as depth, grain size, total organic carbon (TOC), cation exchange coefficient (CEC), carbohydrates and proteins. Firstly, the influence of physico-chemical and biological properties on erosion resistance became evident, even over depths at 0–35 cm. Secondly, inter-particle forces are most important for erosion resistance. These are enhanced in fine-grained sediment layers, offering high binding capacities but also strengthened by polymeric substances permeating the void space and coating particles. These covariance patterns of sedimentological and biological parameters are addressed by multivariate statistical tests (principal component analysis), resulting in a higher magnitude of the correlation coefficient between critical shear stress and the master-variables in main component II (polymeric substances, grain size, TOC, CEC; R=0.77) compared to single correlations.  相似文献