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41.
为探析长江口沉积物-水界面砷的迁移转化机制,本文分析了2019年夏季长江口4个站位上覆水和间隙水中总As浓度及形态的剖面变化特征,耦合氧化还原敏感元素(Fe、Mn和S)的剖面变化剖析了沉积物-水界面砷循环的Fe-Mn-S控制机制,同时结合砷相关功能基因探讨了沉积物-水界面砷迁移转化的微生物调控过程,估算了沉积物-水界面总As的扩散通量。结果表明,除A7-4站位外,长江口其他3个站位间隙水总As以As3+为主要存在形态,且总As浓度均在上覆水中为最低值(0.748~1.57 μg·L-1),而在间隙水中随着深度增加而逐渐增加并在6~9 cm深度达到峰值(7.14~26.9 μg·L-1)。间隙水总As及As3+浓度的剖面变化趋势与溶解态Fe2+、Mn2+相似,其均在中间层出现高值,说明沉积物Fe/Mn还原带砷的释放可能是随固相Fe(Ⅲ)或Mn(Ⅳ)的还原而转移到间隙水中的。氧化层和Fe/Mn还原带过渡区间隙水砷浓度与砷异化还原菌功能基因arrA和arsC丰度存在对应关系(除A1-3站外),说明砷异化还原菌将溶解As5+或固相As5+还原为溶解As3+可能是该过渡层砷迁移转化的另一重要过程。硫酸盐还原带的间隙水总As和As3+浓度降低,但由于间隙水的低S2-浓度不利于砷硫化物生成,因此深层间隙水砷可能与铁硫矿物结合而被移除。底层环境氧化还原条件是影响沉积物-水界面砷迁移转化的重要因素,随底层水DO浓度的降低,砷迁移转化更倾向于微生物还原控制。长江口沉积物-水界面总As的扩散通量为1.18×10-7~2.07×10-7 μmol·cm-2·s-1,均表现为沉积物间隙水中总As向上覆水释放,即沉积物是研究区域水体总As的来源之一。 相似文献
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M. M. Farinha Z. Šlejkovec J. T. van Elteren H. Th. Wolterbeek M. C. Freitas 《Journal of Atmospheric Chemistry》2004,49(1-3):343-353
A three-step sequential extraction procedure with Milli-Q, CaCl2 and H3PO4 was applied for extraction of arsenic species in lichen transplants and airborne particulate matter (fine and coarse fractions). The samples used in this work were collected in 1994–1995 near coal-fired power plants. Both transplant lichens and airborne particulate matter were submitted to the same environment simultaneously. Arsenic species identification and quantification was performed by HPLC–UV–HG–AFS. Inorganic forms of arsenic (arsenite and arsenate) were present in significant amounts in most of the samples. Only in lichens also organic forms of arsenic (monomethyl arsonic acid and dimethyl arsinic acid) were identified which may indicate biotransformation of inorganic arsenic. 相似文献
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Sediments from shallow aquifers in Bengal Delta, India have been found to contain arsenic. Rivers of Ganga-Brahmaputra system, responsible for depositing these sediments in the delta, have created a store of arsenic. Geomorphological domains with different depositional styles regulate the pattern of distribution of zones with widely different content of groundwater arsenic. The high arsenic zones occur as narrow sinuous strips confined to channel deposits. A few iron-bearing clastic minerals and two post-depositional secondary products are arsenic carriers. Secondary siderite concretions have grown on the surface of the clastic carriers in variable intensity. The quantity of arsenic in all clastic carriers is in excess of what is generally expected. Excess arsenic is contributed by the element adsorbed on the concretion grown on the surface of the carriers, which adds up to the arsenic in the structure of the minerals. Variable abundance of concretions is responsible for the variable quantity of arsenic in the carriers and the sediment samples. Fe2+ for the growth of siderite concretions is obtained from the iron-bearing clastic carriers. The reaction involves reduction of trivalent iron to bivalent and the required electron is obtained by transformation of As3+ to As5+. It is suggested that oxidation of As3+ to As5+ is microbially mediated. In the Safe zone arsenic is retained in the carriers and groundwater arsenic is maintained below 0.05 mg/l. In the Unsafe zone sorbed arsenic is released from the carriers in the water through desorption and dissolution of concretion, thereby elevating the groundwater arsenic level to above 0.05 mg/l. 相似文献
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C. Chagué D. Edwards J. Ruszczyk P. Gadd A. Zawadzki G. Jacobsen 《Australian Journal of Earth Sciences》2019,66(5):657-670
Late Holocene environmental changes were examined in Dee Why Lagoon, New South Wales, based on the sedimentological, geochemical and geochronological analysis of six cores collected from the fluvial delta and lagoon basin. The lagoon formed about 7300–7200?cal yr BP, following the post-glacial marine transgression and establishment of a sand barrier. Infilling of the lagoon occurred at a rate of 0.09–0.15?mm/yr until about 3300–3200?cal yr BP, when the barrier closed, resulting in mostly freshwater conditions, as evidenced by a change from pyrite-rich units to sediment containing little sulfur and a lack of foraminifera. Sedimentation rates increased to 0.23 then 0.43?mm/yr until about 100?years ago. Post-European land clearance led to an increase in sedimentation rates to 1.0–1.3?mm/yr on the fluvial delta, which are lower than those from other wave-dominated estuaries in New South Wales as well as those estimated by previous studies in Dee Why Lagoon. Our study shows that the fluvial delta started forming much earlier than originally thought, based on results of radiometric dating, and confirmed using sedimentological and geochemical data, as well as a critical examination of historic aerial photographs. Human impact has resulted in an increase in heavy metal (Cu, Pb, Zn) and metalloid (As) concentrations in the recent sediment, most likely attributed to stormwater discharge. Pb and As concentrations are above the ANZECC high sediment quality guideline values at the site closest to the stormwater outlet, with As-based pesticides one of the possible sources. Using the mean enrichment quotient, which is based on normalised Cu, Pb and Zn concentrations over their normalised background concentrations, we show that the surface sediments in Dee Why Lagoon are severely enriched, reflecting the recent anthropogenic impact that has also led to an increase in sedimentation rates. 相似文献
48.
砒砂岩区地貌形态三维分形特征量化及空间变异 总被引:3,自引:0,他引:3
针对现有地貌形态三维分形模型结构存在的不足,构建一个新的地貌形态三维分形维数测算模型。基于该模型对砒砂岩区274个小流域的地貌形态三维分形维数进行计算并分析其空间变异规律。研究表明:① 基于该模型计算的分形维数能更准确地反映地貌形态复杂度信息;② 砒砂岩区小流域地貌形态三维分形维数介于1.683 6~1.948 6之间;③ 地貌形态三维分形维数整体上覆土砒砂岩区(均值为1.765 9)<裸露砒砂岩强度侵蚀区(均值为1.785 4)和剧烈侵蚀区(均值为1.774 8)<覆沙砒砂岩区(均值为1.796 6)。由于地表覆盖物、砒砂岩裸露程度和土壤侵蚀机理的差异而形成的不同地貌特征是该区地貌形态分形特征空间变异的主要原因。 相似文献
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Comparison of vegetation and stream sediment geochemical patterns in northeastern New South Wales 总被引:1,自引:0,他引:1
D. R. Cohen C. M. Silva-Santisteban N. F. Rutherford D. L. Garnett H. M. Waldron 《Journal of Geochemical Exploration》1999,66(3):383
This study compares the geochemical response of stream sediments and adjacent vegetation samples, with variations in drainage catchment lithology and the occurrence of mineralisation, within a 14,000-km2 block of the northeastern region of New South Wales, Australia. The area contains a range of lithologies within a Devonian–Permian accretionary complex and Mesozoic sedimentary basin, as well as a wide range of mineral deposits. Sampling was designed to confine each sub-catchment to a single lithological group (mafic and ultramafic rocks, acid intrusives, volcanics, metasedimentary and sedimentary rocks or alluvium). Leaves of over 20 genera, dominated by (Allo-)Casuarina, Eucalyptus, Acacia, Callistemon and Melaleuca, and the <250-μm fraction of the stream sediments were analysed by INAA. The uptake of most trace elements varied between genera, with Callistemon displaying the highest median As and La contents and Eucalyptus the highest Co contents. The stream sediment and vegetation geochemistry reflect both hydromorphic and mechanical dispersion within sub-catchments, with regional patterns dominant over local influences. The vegetation appears to be influenced to a greater extent by hydromorphic dispersion, as indicated by differences in the ratio of leaf to sediment Cr concentrations in sub-catchments draining serpentinites and basalts. Although most known mineral deposits in the region produced anomalies in at least one medium, there was little correlation between the trace element concentrations of the vegetation and stream sediments on a site-by-site basis. A number of Au targets were only detected on the basis of the biogeochemistry and others were only reflected in the stream sediment geochemistry. In general, vegetation displayed more extensive dispersion trains away from mineralisation than did the stream sediments. Differences in the response of the two sampling media suggest their joint use in exploration or environmental surveys to maximise the probability of detecting mineralisation. 相似文献
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选取广西北部湾地区表层土壤中As元素为研究对象,采集了7 327个土壤样品,400个岩石样品,分析As、K2O、Na2O、CaO、MgO、SiO2、Al2O3、TFe2O3、Mn、Ti、pH和有机碳(SOC)等指标,探讨了土壤成土母岩、成土作用、土壤组成、pH和有机质等对表层土壤As元素的影响。结果表明:As元素平均质量分数为7.96×10-6,为中国土壤背景值0.80倍;风化作用对于As元素的次生富集起到极为重要的作用,明显强于成土母岩As元素背景的影响。Pearson相关分析和主成分分析表明:在土壤组成和土壤性质等因素中,含Al矿物(Al2O3)、含Fe矿物(TFe2O3)、含Si矿物(SiO2)和SOC,对土壤As的富集起到主导作用;pH 和含 Ca矿物(CaO)的作用较弱;而含K矿物(K2O)、含Na矿物(Na2O)和含Mg矿物(MgO)对As的次生富集作用可以忽略不计。 相似文献