The Dissolution Experiment of Polyhalite at Different Temperature and Pressure     

ZHAO Xianyin  AN Lianying  LI Chunge  CHENG Li 《《地质学报》英文版》2014,88(Z1):412-413

正Polyhalite(K2SO4·Mg SO4·2Ca SO4·2H2O)is one of the insoluble potassium mineral which is widely distributed in sulfate-type potassium-bearing deposit,and the theoretical concentration of K2SO4 is 28%.It can be directly used as a  相似文献   

Thermal simulation experiments of saturated hydrocarbons with calcium sulfate and element sulfur: Implications on origin of H<Subscript>2</Subscript>S   总被引：1，自引：0，他引：1  

CHEN TengShui    HE Qin  LU Hong  PENG PingAn & LIU JinZhong State Key Laboratory of Organic Geochemistry  Guangzhou Institute of Geochemistry  Chinese Academy of Sciences  Guangzhou  China  Department of Geology  Northwest University  Xi’an 《中国科学D辑(英文版)》2009,52(10):1550-1558

Temperature-programmed simulation experiments of saturated hydrocarbons with calcium sulfate and element sulfur were compared in this study. Based on the variation analysis of the yields and evolvement features of gaseous hydrocarbon (C1-C5) and inorganic gaseous CO2, H2 and H2S, the reaction mechanisms were analyzed and discussed. In the calcium sulfate-saturated hydrocarbon system, H2S was produced by a small quantity, which indicates this reaction belongs to the low-degreed thermal sulfate reduction (TSR...  相似文献   

Weathering of phosphorus-bearing mineral powder and calcium phosphate by Aspergillus niger     

Shuangshuang Qiu  Bin Lian 《中国地球化学学报》2012,31(4):390-397

The weathering of phosphorus-bearing mineral powder(PBMP) and calcium phosphate(CP) by Aspergillus niger was compared,and the mechanism involved was analyzed for the comprehensive utilization of PBMP.The concentration of water-soluble phosphorus(WSP),Mg2+,and Ca2+at different culture times,microstructures of particles,and mineral compositions was examined by ultraviolet-visible spectrometer(UV),atomic absorption spectrometry(AAS),scanning electron microscopy(SEM),and X-ray diffraction(XRD).Results showed that the change in the concentrations of WSP,Mg2+,and Ca2+were related to the growth of A.niger and the different mineral compositions.Compared with CP,PBMP was weathered harder by fungi.Traces of the weathered mineral were found through SEM.CP not only showed traces of erosion damage but also appeared as a rhombohedron-like substance.The XRD test indicated that the weathering minerals can form water calcium oxalate.Further analysis revealed that the mechanism of PBMP and CP weathering by A.niger was the collaborative result of mycelium biomechanical effects and the acid-soluble role of acidic metabolites.The phosphorus dissolution rate of PBMP after 20 d was 46.83%,whereas that of CP after 12 d was 91.01%.The findings of this study are significant to the effective use of waste PBMP and to the exploitation of low-grade phosphate rock resources.  相似文献   

鹿角杯形珊瑚骨骼构造和显微结构的研究          下载免费PDF全文

叶承  黄晖  张成龙 《热带海洋学报》2013,(2)

石珊瑚骨骼对重建古海洋古气候环境,评估珊瑚礁对未来气候变化、海洋酸化的响应和反馈,辨识现存造礁石珊瑚种属及其演化途径有着十分重要的作用和意义。为了更好地认知造礁石珊瑚骨骼特征,在三亚海域采集了常见的造礁石珊瑚——鹿角杯形珊瑚Pocillopora damicornis,通过扫描电镜(结合EDS能谱仪)、红外分光显微镜分析其碳酸钙骨骼结构和成分的特征,结果表明鹿角杯形珊瑚骨骼主要成分为文石,少数骨骼样品的空腔中发育有极少量方解石矿物。虽然鹿角杯形珊瑚骨骼宏观架构和中观架构在群体间和单体间存在诸多差异,但不同形态的骨骼样品具有基本相同的发育模式和基础结构单元。同时,发现鹿角杯形珊瑚骨骼内部空腔存在有次生文石沉积发育现象,同时常伴生着水镁石矿物的发育,而且这与骨骼中的钻孔穴居动物有很大关联。  相似文献   

甲状腺乳头状癌中砂粒体矿物学研究   总被引：5，自引：0，他引：5  

赵文雯  王长秋  鲁安怀  张波  柳剑英  梅放 《岩石矿物学杂志》2009,28(6):623-628

砂粒体矿化对诊断甲状腺乳头状癌具有高度的特异性,对其矿物成分及形成机理的分析有望对研究肿瘤的发生发展过程提供辅助信息.本文以甲状腺乳头状癌中的同心层状砂粒体矿化作为研究对象,采用偏光显微镜、环境扫描电镜及其能谱、傅立叶变换红外光谱、电子探针和高分辨透射电子显微镜,对原位和分离处理样品的表面形貌、结构和矿物成分进行了观察测试.研究结果表明,甲状腺乳头状癌中砂粒体是由纳米尺寸的粒状、短柱状碳羟磷灰石及一些无定形低Ca/P(原子分数,下同)的磷酸钙矿物混合组成,砂粒体的同心层状构造具有微胶粒成因的特征,是结构和成分不同的直接反映,砂粒体中Ca、P及 Ca/P的分布具有从外向内逐渐升高的趋势.  相似文献   

吉林通化地区煤系高岭岩合成4沸石研究     

李春茂  李洪文  楚湘涛 《吉林地质》2009,28(2):123-125

以吉林通化地区煤系高岭岩为原料,采用水热法合成了4沸石,讨论了煅烧温度、用碱量、晶化时间和温度等对生成产物的影响。实验表明：合成4沸石的适宜条件为：煅烧温度650-850℃,用碱量Na2O/SiO2=2.80,晶化时间2 h,晶化温度80℃,胶化时间2 h,老化时间10 h,在此条件下合成的4沸石,其钙离子交换量为233.51 mg.CaCO3/g。  相似文献   

Glacial atmospheric CO₂ decline in association with decrease of marine sedimentary phosphorus     

Weng Huanxin  Zhang Xingmao  Wu Nengyou  Wang Ying  Chen Lihong  Zhong Hexian  Qin Yachao 《中国科学D辑(英文版)》2006,49(3):322-330

The environmental and biogeochemical information extracted from the sediments collected from the northern shelf of the South China Sea shows that terrigenous inputs of phosphorus into the sea remained relatively constant, and the variation of phosphorus contents at different depths was caused by climatic and environmental changes. The findings also suggest that the vertical variation of phosphorus content was opposite to those of calcium carbonate and cadmium, and the functional correlation between CO₂ and PO ₄ ³⁻ in seawater was given by calculating the chemical equilibrium, indicating that the accumulation of marine sedimentary phosphorus may have something to do with the variation of atmospheric CO₂. The decreased phosphorus accumulation as well as the correspondingly-increased calcium carbonate content might be one of key factors causing glacial atmospheric CO₂ decline.  相似文献   

The analysis and forecast for fouling in water pipelines in Daqing oilfield     

Xiaoyan LIU Qianya ZHU Jinlai FENG Gang QI Baosen ZHANG Yingli LI Jingxin SUN 《中国地球化学学报》2006,25(B08):161-161

In order to maintain the reservoir pressure and improve oil recovery efficiency, water flood recovery is used commonly in the middle and last periods of oilfield exploitation. At the same time, in order to avoid environmental pollution, the oilfield sewage should be reinjected. During that manufacture, variations in the conditions of pressure, temperature and unstability and incompatibility of thermodynamics make scale formation in water flood assize, casing, bottom of the wells, surface equipments and gathering lines. Taking the Daqing oil field for example, in which the surface gathering lines the scale forming is comparatively serious. In order to improve crude oil processing effect to warm up wet oil, this measure results in scale formation constant in pipelines and equipments, so inner diameter becomes less, leading to back pressure ascent in pipelines, the loss of efficiency of processing equipment, these all have a strong impact on normal activities in oilfield, increase the frequency of maintenance repairs and replacements for pipelines and equipments, and reduce the completion benefit. So forecasting the scaling tendency of surface gathering pipelines, and judging the degree of the scaling tendency or possibility, preventing and controlling scaling effectively is not a negligible research topic in petroleum production technology and oil-gas-water treatment technology. This paper introduces the fouling process, fouling mechanism and the influence factors of the scale, mainly analyses the formation mechanism of calcium carbonate and calcium sulfate, and some factors, such as temperature, pressure, salinity and some thermodynamics conditions. All these factors lead to changes in ionic equilibrium condition, so they will influence the fouling. This paper analyses the main kinds of scale in the gathered transportation water pipeline in the forth plant in the Daqing Oilfield, adopts the method of saturation exponent and energetic solubility to forecast the trend of fouling, reduces the calcium carbonate showing scaling tendency, calcium sulfate having the possibility of scaling.  相似文献   

二水硫酸钙结晶动力学研究   总被引：1，自引：0，他引：1  

周利民  金解云 《华东地质学院学报》2004,27(4):378-380

主要研究了过饱和溶液中CaSO4 ·2H2 O晶体成核及生长现象 ,同时对垢的形成机理进行了探讨。实验表明 ,成核延迟时间随溶液过饱和度增大而减小 ;CaSO4 ·2H2 O晶体生长属于表面反应控制 ,且与粒径相关 ,当温度为 3 0℃ ,粒径为2 8～ 67μm ,Ca2 + 浓度为 0 .0 3 5mol/L时 ,晶体生长速度在 0 .5× 10 - 8～ 5 .8× 10 - 8m/s之间  相似文献   

草酸钙生物矿化膜的形成机理和化学仿制－－一种新型石质文物表面防护材料的开发研究   总被引：4，自引：0，他引：4  

张秉坚  尹海燕  沈忠悦  卢唤明 《矿物学报》2001,21(3):319-322

已经发现一些年代久远的含钙岩石表面有一层天然生成的矿化膜，矿化膜保护下的石刻文字可以历经上千年的风雨而保持完好。本工作探讨了这种膜的组成和来源。膜的样品用FTIR、PLM、EDAX、SEM和TEM进行了分析。检测发现天然矿化膜的主要成分为草酸钙，许多证据表明这是一种生物矿化膜。本文讨论了膜的形成机理。为了开发新型石质文物表面防护材料，我们在实验室中用化学仿制的方法在含钙岩石上生成了这种保护膜，同时研究了膜的生成条件与保护效果之间的关系。  相似文献