天津地区表土中蒽和芘的频率分布特征     

段永红  李本纲  陶澍  王学军  徐福留  曹军  刘文新 《地理研究》2005,24(4):559-564

用频率分析、逐步聚类和最小二乘拟合等方法研究了天津地区表土中蒽和芘含量的频率分布特征。结果表明,两者都呈双峰分布,其中蒽的双峰特征尤为典型。可以用双高斯密度函数很好地拟合经对数变换的实际观测数据,证明天津地区蒽和芘都包括两个相对独立的对数正态分布总体。根据拟合频率密度函数求得的蒽的两个子总体几何均值分别为2.73±2.17ng/g和26.52±1.55ng/g,芘则为11.05±2.11ng/g和82.52±3.24ng/g。芘的两个总体在空间上的分异比蒽更明显,其高值总体主要集中在城区、近郊区和开发区,而蒽的高值总体仅有局部聚集的一般趋势。芘与芘/苯并[a]芘之比的空间分布特征十分相似,表明两个芘含量总体并存的原因与排放源特征有关。  相似文献   

Benzo[a]pyrene modulates the biotransformation,DNA damage and cortisol level of red sea bream challenged with lipopolysaccharide     

Jun Bo  Singaram Gopalakrishnan  Fang-Yi Chen  Ke-Jian Wang 《Marine pollution bulletin》2014

In animals, biotransformation and the immune system interact with each other, however, knowledge of the toxic mechanism of benzo[a]pyrene (BaP) on these two systems is not well known. The present study investigated the toxic effects of BaP on the biotransformation system, cortisol level and DNA integrity of red sea bream (Pagrus major). The results showed that cortisol level was induced under the challenge of lipopolysaccharide (LPS). Short-term exposure (96 h) of BaP at environmental concentration significantly increased the cortisol level, hepatic EROD activity and CYP1A1 mRNA expression. When P. major was exposed to BaP for 14 d followed by LPS challenge this increased the cortisol level, EROD activity and hepatic DNA damage except CYP1A1 mRNA expression. Combined with our previous data, which showed that BaP exposure can modulate the immunologic response in P. major challenged with LPS, a hypothetical adverse outcome pathway of BaP on fish was suggested.  相似文献   

引发四川盆地东部暴雨的西南低涡结构特征研究   总被引：1，自引：0，他引：1  

江玉华  杜钦  赵大军  何跃  李江 《高原气象》2012,31(6):1562-1573

利用1951-2008年四川盆地(27°-32°N,105°-110°E)54个地面气象观测站网监测的日雨量资料,分析了四川盆地东部暴雨发生的气候特征。结果表明,四川盆地东部暴雨(或伴有雷雨大风、冰雹大风等)多发生在6-9月,川东北和渝东北是单站暴雨的高发区,重庆西部是大范围暴雨的多发区;引发四川盆地东部(宜宾、南充和重庆西部)暴雨的主要天气系统是西南低涡。对2007-2010年6次西南低涡暴雨过程进行了合成分析,分析表明,西南低涡热力结构特征具有200hPa存在明显增暖现象,对流层中低层则由暖转冷;西南低涡初期大气对流性不稳定明显;西南低涡动力结构特征具有200hPa西风急流在36°N附近,500hPa低槽东移,槽前正涡度加强,从对流层底垂直伸展到300hPa以上,正涡度中心随高度向西倾斜,850～500hPa平均正涡度大值区与低涡中心对应,对流层中低层北风大值区与南风大值区在低涡中心附近形成强水平风切变,同时低涡中心附近的垂直风切变也较明显。促使西南低涡发展的水汽主要来自南海,低空急流由南向北输送水汽,将对流层低层到大气边界层内的水汽输送到低涡中心附近。西南低涡发生、发展过程中在红外卫星云图上具有MCC等中-α尺度特征,发展强盛的西南低涡在多普勒天气雷达回波上有"列车效应"和中气旋特征。  相似文献   

EIGEN-CG01C用于GPS高程转换的精度分析   总被引：7，自引：0，他引：7  

张兴福  沈云中  楼立志 《大地测量与地球动力学》2005,25(4):74-78

介绍了综合CHAMP、GRACE卫星数据和地面重力数据得到的最新重力场模型EIGEN-CG01C,利用GPS水准数据探讨了该模型用于GPS高程转换的精度问题,并同EGM96模型进行了比较。统计结果表明:在我国西部某区域(2000km×2000km)的范围内、点间距100km的情况下,该模型用于GPS高程转换的精度约0.7m;在我国中、东部的3个小区域算例中,该模型的精度分别约0.13m、0.05m和0.06m,均优于EGM96模型的精度。  相似文献   

Synthesis of Calix[4]arene‐grafted Magnetite Nanoparticles and Evaluation of Their Arsenate as Well as Dichromate Removal Efficiency     

Serkan Sayin  Fatih Ozcan  Mustafa Yilmaz  Ali Tor  Shahabuddin Memon  Yunus Cengeloglu 《洁净——土壤、空气、水》2010,38(7):639-648

In this study, 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene ( 3 ) has been prepared by the treatment of calix[4]arene with a secondary amine (4‐benzylpiperidine) and formaldehyde by means of Mannich reaction. The prepared Mannich base ( 3 ) has been grafted onto [3‐(2,3‐epoxypropoxy)‐propyl]‐trimethoxysilane‐modified Fe₃O₄ magnetite nanoparticles (EPPTMS‐MN) in order to obtain 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy calix[4]arene‐grafted EPPTMS‐MN (BP‐calix[4]arene‐grafted Fe₃O₄). All new compounds were characterized by a combination of FTIR and ¹H‐NMR analyses. The morphology of the magnetic nanoparticles was examined by transmission electron microscopy. Moreover, the studies regarding the removal of arsenate and dichromate ions from the aqueous solutions were also carried out by using 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene in liquid–liquid extraction and BP‐calix[4]arene‐grafted Fe₃O₄ ( 4 ) in solid–liquid extraction experiments. The extraction results indicated that 3 is protonated at proton‐switchable binding sites in acidic conditions. Hence, facilitating binding of arsenate and dichromate is resulted from both electrostatic interactions and hydrogen bonding. To understand the selectivity of 3 , the retention of dichromate anions in the presence of Cl⁻, NO, and SO anions at pH 1.5 was also examined.  相似文献   

一个被曲解和讹传了60年的第四纪地层名称--J.Thorp 1936年的Lunan Series (路南红色土)     

张守信 《第四纪研究》2004,24(3):355-358

文章指出LunanSeries(红色土)系J.Thorp1936年创名,名称取自云南省的路南县,地质时代是第四纪。杨钟健1939年对此曾做过正确而详细的介绍,并认为其地质年代属更新世晚期或全新世。自1943年至今,所有已发表涉及杨钟健论文中关于所谓“路南组”(或路南群,路南层)的介绍或记述均被曲解和属讹传  相似文献   

近六年中山站春季臭氧低值的观测结果分析   总被引：4，自引：0，他引：4       下载免费PDF全文

郑向东  陆龙骅  周秀骥 《极地研究》1999,11(4):265-274

根据中山站 Brewer臭氧光谱仪的观测结果 ,对中山站地区近六年春季臭氧低值的特征进行研究 ,并与 TOMS卫星观测结果进行了对比分析。分析表明中山站春季臭氧值的逐日变化与极地涡旋动力过程有密切联系。Brewer和 TOMS观测结果总体上接近 ,但 TOMS要略高于地基观测结果 6～ 1 0 DU。在春季臭氧低值期间 ,UV- B测值要高于夏至时的 UV- B测值 ,30 0～30 5nm波段的 UV- B辐射强度比 32 0～ 32 5nm波段更易受春季臭氧低值的影响  相似文献   

西南极菲尔德斯海峡断层GPS卫星地壳形变监测网的重建和数据分析   总被引：2，自引：0，他引：2       下载免费PDF全文

鄂栋臣  张小红  陈春明  王清华 《极地研究》1999,(4)

为了有效地监测南极菲尔德斯海峡断层的地壳运动 ,利用 GPS定位技术 ,将原有的二维平面形变监测网改造成三维空间形变监测网 ,并对 GPS数据采集和数据处理方法作了综述和分析 ,获得了水平方向优于 3mm,高程方向优于 6mm的监测精度。建立 GPS空间三维监测网在南极环境中研究地壳动态形变完全可行的  相似文献   

液相色谱法测定城市自来水中的苯并(a)芘   总被引：5，自引：0，他引：5       下载免费PDF全文

曲仪 《气象与环境学报》2006,22(6):43-45

针对目前测定生活饮用水中的苯并(a)芘(简称Bap),采用的是国家标准《生活饮用水标准检验法》GB5750-85中的纸层析—荧光分光光度法,其准确度、精密度很难令人满意,提出了使用高效液相色谱法来定量检测城市自来水中的Bap。实验结果表明:该方法快速、准确,具有优异的重现性,线性范围为4.0～30.0 ng/L,线性系数为0.9999。日内(5 h)、日间(5 d)精密度均小于4.0%(n=5),Bap的回收率为89.0%～93.4%。由于Bap见光极容易分解,影响测定结果,因此采样后应尽快分析。  相似文献   

EROD activities of liver in Mugil so-iuy exposed to benzo (a)pyrene, pyrene and their mixture     

Wang Chonggang  Chen Jixin  Yu Ang  Zheng Weiyun 《海洋学报(英文版)》2003,22(2):213-220

Abstract-The effects on hepatic EROD (7-ethoxyresorufin O-deethylase) in Mugil so-iuy exposedto benzo(a)pyrene (BaP), pyrene and their mixtures of equal concentration were investigated, at con-centrations of 0.1, 1.0, 5.0, 10.0, 50.0 μg/dm~3, in experimental condition. Time-effects and dose-response of the biochemical indexs were observed. The results showed that the hepatic EROD activitieswere induced by the exposure of BaP, pyrene and their mixtures at high concentration. Dose-responseconnections were that the hepatic EROD activities were elevated with increasing concentration of the pol-lutants. The combined effect of BaP and pyrene at 1:1 concentration ratio on hepatic EROD activity wasantagonism.  相似文献