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21.
铍矿是中国重要的战略性新兴产业矿产资源,其中以花岗伟晶岩型最为重要.南岭是中国重要的稀有金属、钨、锡多金属成矿带,以往发现的铍矿主要以矽卡岩型、云英岩型为主,花岗伟晶岩型铍矿较少.通过详细的野外和室内岩矿鉴定工作,笔者在南岭成矿带中亚带花岗伟晶岩中发现了粗晶状绿柱石,并确定其具有一定的规模,弥补了南岭地区铍矿类型单一的...  相似文献   
22.
Short‐lived fallout isotopes, such as beryllium‐7 (7Be), are increasingly used as erosion and sediment tracers in watersheds. 7Be is produced in the atmosphere and delivered to the Earth's surface primarily in precipitation. However, relatively little has been published about the variation in 7Be wet deposition caused by storm type and vegetation cover. Our analysis of precipitation, throughfall, and sediments in two forested, headwater catchments in the mid‐Atlantic USA indicates significant variation in isotope deposition with storm type and storm height. Individual summer convective thunderstorms were associated with 7Be activity concentrations up to 5.0 Bq l?1 in precipitation and 4.7 Bq l?1 in throughfall, while single‐event wet depositional fluxes reached 168 Bq m?2 in precipitation and 103 Bq m?2 in throughfall. Storms originating from the continental USA were associated with lower 7Be activity concentrations and single‐event wet depositional fluxes for precipitation (0.7–1.2 Bq l?1 and 15.8–65.0 Bq m?2) and throughfall (0.1–0.3 Bq l?1 and 13.5–98.9 Bq m?2). Tropical systems had relatively low activity concentrations, 0.2–0.5 Bq l?1 in precipitation and 0.2–1.0 Bq l?1 in throughfall, but relatively high single‐event depositional fluxes due to large rainfall volumes, 32.8–67.6 Bq m?2 in precipitation and 25.7–134 Bq m?2 in throughfall. The largest sources of 7Be depositional variation were attributed to storm characteristics including precipitation amount and maximum storm height. 7Be activity associated with fluvial suspended sediments also exhibited the highest concentration and variability in summer (175–1450 Bq kg?1). We conclude the dominant source of variation on event‐level 7Be deposition is storm type. Our results illustrate the complex relationships between 7Be deposition in precipitation and throughfall and demonstrate event‐scale relationships between the 7Be in precipitation and on suspended sediment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
23.
本文在EDTA和甘露醇存在下以Sn为共沉淀剂,沉淀富集痕量Be,分离大量Fe、Al和Ti等干扰元素。痕量Be测的定采用草酸存在下铍试剂Ⅲ(隐色)三阶导数光度法。显色体系灵敏度高,检出限为1ng Be/ml,且允许共存离子量较大。方法经GSD系列标样和硅酸盐岩石试样中痕量Be测定验证,其结果与推荐值(或原结果)相符。方法精密度好,对于含Be0.0091%硅酸盐岩石测定其RSD(n=6)为1.66%。  相似文献   
24.
在pH值为5.8的六次甲基四胺缓冲液的存在下,用EDTA和酒石酸钠掩蔽,铍与新型显色剂:偶氮氯膦-MK形成稳定络合物。最大吸收波长于620nm处。表观摩尔吸收常数为2.32×104L·mol-1·cm-1。铍含量在0~5μg/25mL内服从比耳定律。该方法用于水样中铍含量的测定,得到较好效果。  相似文献   
25.
Here we combine 10Be depth profile techniques applied to late glacial ice‐contact marine and lacustrine deltas, as well as boulder exposure dating of associated features in the Scoresby Sound region, east Greenland, to determine both the surface age and the magnitude of cosmogenic nuclide inheritance. Boulder ages from an ice‐contact delta in northern Scoresby Sund show scatter typical of polar regions and yield an average age of 12.8 ± 0.5 ka – about 2 ka older than both our average profile surface age of 10.9 ± 0.7 ka from three depth profiles and a radiocarbon‐based estimate. On the other hand, boulder exposure ages from a set of moraines in southern Scoresby Sund show excellent internal consistency for polar regions and yield an average age of 11.6 ± 0.2 ka. The profile surface age from a corresponding ice‐contact delta is 8.1 ± 0.9 ka, while a second delta yields an age of 10.0 ± 0.4 ka. Measured 10Be inheritance concentrations from all depth profiles are internally consistent and are between 10% and 20% of the surface concentrations, suggesting a regional cosmogenic inheritance signal for the Scoresby Sound landscape. Based on the profile inheritance concentrations, we explore the first‐order catchment‐averaged bedrock erosion under the Greenland ice sheet, yielding estimates of total erosion during the last glacial cycle of the order of 2–30 m. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
26.
Cosmogenic 7Be is a natural tracer of short‐term hydrological processes, but its distribution in upland fluvial environments over different temporal and spatial scales has not been well described. We measured 7Be in 450 sediment samples collected from perennial channels draining the middle of the Connecticut River Basin, an environment that is predominantly well‐sorted sand. By sampling tributaries that have natural and managed fluctuations in discharge, we find that the 7Be activity in thalweg sediments is not necessarily limited by the supply of new or fine‐grained sediment, but is controlled seasonally by atmospheric flux variations and the magnitude and frequency of bed mobilizing events. In late winter, 7Be concentrations in transitional bedload are lowest, typically 1 to 3 Bq kg?1 as 7Be is lost from watersheds via radioactive decay in the snowpack. In mid‐summer, however, 7Be concentrations are at least twice as high because of increased convective storm activity which delivers high 7Be fluxes directly to the fluvial system. A mixed layer of sediment at least 8 cm thick is maintained for months in channels during persistent low rainfall and flow conditions, indicating that stationary sediments can be recharged with 7Be. However, bed mobilizing rain on snowmelt events in late Spring can ‘reset’ 7Be amounts and concentrations in the channel as previously buried ‘old’ sediment with low 7Be is mixed into the thalweg. We conclude that given proper temporal and spatial sampling, 7Be is a valuable tracer of seasonal‐timescale mass transport and exchange in coarse‐grained fluvial systems. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
27.
选用市场上常见的紫红色、橙色、粉色、绿色、黑色处理珍珠,粉橙色、金黄色铍扩散蓝宝石,充胶翡翠作为研究对象,通过设计耐久性实验,对样品颜色的稳定性进行了研究。结果显示,充胶翡翠和铍扩散蓝宝石在日晒、盐雾及人工汗液中均表现出了良好的颜色稳定性;处理珍珠在盐雾环境中表现出了较好的稳定性,在模拟日光照射试验中褪色明显,而经过人工汗液腐蚀,其颜色表现出了较差的稳定性。对样品颜色稳定性的研究,可以为优化处理宝石的市场准入提供一定的依据。  相似文献   
28.
通过在川西九龙三岔河地区开展综合地质调查工作,发现该区桥棚子花岗岩体与三叠系围岩接触带及其附近具有较好的铍矿化,初步圈定了4条铍矿体,主要沿岩体接触带呈NNW向延伸,BeO品位最高可达0.698%,初步预测BeO资源量可达大型规模,矿石矿物主要为绿柱石,围岩蚀变以电气石化为主。花岗岩体顶部是含铍伟晶岩的重要成矿部位,野外可采用遥感先行的技术手段查找异常,再对遥感异常开展大比例尺追索,进一步采用工程手段进行验证。结果表明,九龙地区具有明显锂、铍异常,且与地质体套合度高。研究区外围东部发现稀有金属矿化显著的打枪沟锂铍矿床,南部乌拉溪地区追索到大量含锂辉石矿化伟晶岩转石,表明该区具有良好的稀有金属成矿条件及找矿潜力。  相似文献   
29.
铬天青R分光光度法测定铝土矿中的铍   总被引:1,自引:1,他引:0  
刘文春 《岩矿测试》2010,29(3):328-330
建立了用铬天青R分光光度法测定铝土矿中铍的方法。700℃下用氢氧化钠碱熔法分解铝土矿,以8-羟基喹啉、酒石酸、EDTA作为掩蔽剂,在pH 9~10的氨水-氯化铵介质中,铍与铬天青R、溴化十六烷基三甲基胺(CTMAB)生成三元红色络合物,在波长552 nm处有最大吸收。方法的特征浓度为0.031μg/(mL.1%),摩尔吸光系数ε=1.25×105,标准偏差为0.000 7μg/mL,回收率为97.6%,铍量在0~0.06μg/mL内符合比耳定律。方法简便,准确度好,灵敏度高,结果令人满意。  相似文献   
30.
珠江三角洲地区浅层地下水铍的分布及成因探讨   总被引:1,自引:0,他引:1       下载免费PDF全文
通过对珠江三角洲地区900余组浅层地下水样中铍及铝、pH值等元素的分析,研究了珠江三角洲浅层地下水中铍的分布特征,探讨了铍的主要影响因素及其成因。结果表明,珠江三角洲地区浅层地下水中铍的含量介于0~40.3μg.L-1,普遍低于0.5μg.L-1,平均值0.66μg.L-1。超标点仅零散分布于广州、深圳、东莞、佛山和惠州地区,超标率2.24%。地下水铍污染呈局部点状分布特征。pH值和铝是影响该区地下水中铍分布的最主要因素。偏酸及高铝含量的地下水及土壤环境为铍的迁移提供了有利条件。岩石风化及天然土壤的形成是地下水中铍的来源之一,人类活动造成的污染对地下水铍超标有重要贡献。  相似文献   
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