Estimating the contribution of the authigenic mineral component to the long-term reactive silica accumulation on the western shelf of the Mississippi River Delta     

Massimo Presti  Panagiotis Michalopoulos 《Continental Shelf Research》2008

Previous studies have shown how biogenic silica particles undergo conversion to aluminosilicate phases in large tropical deltaic systems, thus affecting the world ocean budget of major seawater cations. This study tackles the important question of the silica budget in the coastal zone of the Mississippi River Delta, providing evidence for the role of biogenic silica diagenesis in this subtropical system from direct examination of individual diatom particles, sediment leachates and pore-water composition. The estimated reactive silica stored in the study area (5990 km²) is based on operational leaches that account for altered biogenic silica particles and other authigenic aluminosilicate phases in addition to fresh biogenic silica. Early diagenesis of silica in the delta front occurs mainly where more siliceous material is deposited. An inner-shelf area, where hypoxic conditions are found, significantly contributes to the formation of authigenic products of Si alteration. Data suggest that the limiting factor of silica alteration processes is the availability of detrital phases such as Al and Fe. The estimated total reactive silica accumulation in the study area is 1.45×10¹⁰ mol Si year⁻¹, representing ∼2.2% of the long-term bulk sediment accumulation. On the basis of a conservative appraisal, the authigenic mineral components account for ∼40% of the long-term reactive silica storage. This study shows that non-tropical deltaic systems are significantly more important sinks of silica than previously thought and that, where conditions are favourable, a consistent portion of reactive silica not leaving the shelf is stored within the delta in the form of authigenic components.  相似文献   

Paleolimnological evidence of the response of the central Canadian treeline zone to radiative forcing and hemispheric patterns of temperature change over the past 2000 years     

Glen M. MacDonald  David F. Porinchu  Nicolas Rolland  Konstantine V. Kremenetsky  Darrell S. Kaufman 《Journal of Paleolimnology》2009,41(1):129-141

Instrumental climate records from the central Canadian treeline zone display a pattern of variation similar to general Northern Hemisphere temperature trends. To examine whether this general correspondence extends back beyond the instrumental record, we obtained a sediment core from Lake S41, a small lake in the Northwest Territories of Canada at 63°43.11′ N, 109°19.07′ W. A radiocarbon-based chronology was developed for the core. The sediments were analyzed for organic-matter content by loss-on-ignition (LOI), biogenic-silica content (BSi), and chironomid community composition to reconstruct July air temperature and summer water temperature. The paleolimnological records were compared with records of atmospheric CO₂ concentration, solar variability, and hemispheric temperature variations over the past 2000 years. The results of the analyses suggest that widely-documented long-term variations in Northern Hemisphere temperature associated with radiative forcing, namely the cooling following the medieval period during the Little Ice Age (LIA), and twentieth century warming, are represented in the central Canadian treeline zone. There is also evidence of a brief episode of warming during the eighteenth century. As evidenced by LOI and BSi, the twentieth century warming is typified by increased lake productivity relative to the LIA. Depending upon the measure, the increased productivity of the twentieth century nearly equals or exceeds that of any other period in the past 2000 years. In contrast, the rate of chironomid head capsule accumulation decreased and remained low during the twentieth century. Although the chironomid-inferred temperature reconstructions indicate cooling during the LIA, they present no evidence of greatly increased temperatures during the twentieth century. Warming during the twentieth century might have enhanced lake stratification, and the response of the chironomid fauna to warming was attenuated by decreased oxygen and lower temperatures in the hypolimnion of the more stratification-prone lake.

Glen M. MacDonaldEmail:

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北冰洋西部楚科奇海盆晚第四纪生源沉积物及其古海洋学意义   总被引：3，自引：0，他引：3       下载免费PDF全文

王汝建  肖文申 《极地研究》2009,21(4):255-264

通过北冰洋西部楚科奇海盆M03孔晚第四纪以来生源沉积物,有孔虫丰度和冰筏碎屑(Ice．Rafted Detritus,IRD)的综合研究表明,海洋氧同位素(Marine Isotope Stage,MIS)7期以来,碳酸钙(CaCO )含量和浮游有孔虫丰度在间冰期的增加和冰期的降低,分别指示大西洋水输入的加强和减弱。而有机碳(TOC)和生源蛋白石(Biogenic Opa1)含量的变化可能主要与输入到海底的TOC降解和Opal溶解作用与底层水中的溶解氧有关。间冰期低的TOC和Opal含量可能反映楚
科奇海盆海冰覆盖减少,营养盐供给多,表层生产力增加,通气作用好,底层水富氧,降解和溶解作用增强,保存在沉积物中的TOC和Opal减少;而冰期相对高的TOC和Opal含量可能反映楚科奇海盆海冰覆盖时间较长,营养盐供给少,表层生产力较低,通气作用差,底层水少氧,降解和溶解作用减弱,保存在沉积物中的TOC和Opal增多。  相似文献   

柴达木盆地三湖地区第四系沉积相与生物气成藏   总被引：30，自引：3，他引：27       下载免费PDF全文

党玉琪  张道伟  徐子远  侯泽生 《古地理学报》2004,6(1):110-118

柴达木盆地三湖地区第四系蕴藏着巨大的生物气资源,目前已探明加控制天然气储量接近3×1011m3。更新世时期,柴达木盆地的湖相沉积主要分布在三湖(吉乃尔湖、涩聂湖和达布逊湖)地区,自山前至盆地中心依次发育了冲积扇、河流三角洲和湖相沉积,其中湖相沉积分布最为广泛。早更新世湖相沉积开始形成,中更新世湖相沉积扩张并且达到鼎盛,晚更新世湖相沉积开始萎缩并形成盐湖沉积。中、早更新世冰川的出现和青藏高原的崛起使柴达木盆地的古气候变得干旱寒冷,沉积水体温度较低,盐度较高。本区第四纪独特的沉积环境是形成大型生物气藏最重要的地质条件。高盐度的水体环境减缓了有机质的降解速度,长期的低温条件抑制了甲烷菌的活动,避免了沉积有机质在沉积浅埋阶段的过量消耗,推迟了生物产气的高峰期。而三湖地区巨厚的第四系暗色泥岩和频繁发育的砂岩提供了充足的气源条件和构成了良好的生储盖组合。  相似文献   

SiO₂ precipitation in olivine: ATEM investigation of two dunites annealed at 300 MPa in hydrous conditions     

Paul Raterron  Prame Chopra  Jean-Claude Doukhan 《Earth and Planetary Science Letters》2000,180(3-4):415-423

Two natural dunites were annealed at pressure P=300 MPa, temperature T=1373, 1473 and 1573 K, and fO₂ within the stability field of olivine. The starting materials contained small amounts of hydroxyls in the form of minor phases of hydrated minerals, which released an aqueous phase during the experiments. A detailed analytical transmission electron microscopy (ATEM) investigation of these materials revealed that small quantities of two types of silica-rich glass formed during heat treatment. The first type of glass, found at triple junctions as rare partially crystallized glass pockets, results from melting dehydration reactions involving the hydrous phases. The second type of glass is found as pure silica precipitates (0.1–0.5 μm in size, for a total of a few 0.1 vol%) within the olivine grains of specimens heated to ≥1473 K. From considerations of the kinetics of the precipitation at 1473 K, we interpret this silica precipitation as resulting from the condensation of olivine metallic vacancies promoted by increasing fluid fugacities during the runs. Our observations, thus, demonstrate that metastable silica can precipitate in olivine from dunites experiencing rapid changes in their thermodynamical environment.  相似文献   

云南保山盆地第三系成烃地球化学特征及其评价   总被引：3，自引：0，他引：3  

宋振亚  贝丰 《矿物岩石》1999,19(3):23-29

本文系统地研究了保山盆地保参１井第三系成烃地球化学特征,并对其油气显示,天然气成因及古地温进行了探讨,研究结果表明,盆地第三系虽然具有一定规模的形成烃源岩的物质基础,但其有机质成熟度表现偏低,羊邑组（Ｎ２ｙ）属于未成熟带,南林组（Ｎ１ｎ）属于低成熟带,成熟的烃源岩展布规模有限,生物成因天然气及未成熟,低成熟油是保山盆地主要的油气资源。  相似文献   

Silica diagenesis in Eocene shallow-water platform carbonates, southern Pyrenees   总被引：1，自引：0，他引：1  

Jordi Giménez-Montsant  Francesc Calvet  & Maurice E. Tucker 《Sedimentology》1999,46(6):969-984

Spectacularly developed lower Eocene chert in the Corones platform carbonates of the Spanish Pyrenees is concentrated within a restricted, brackish-water, laminated ostracod-rich facies, which also contains abundant sponge spicules. The chert occurs as nodular, bedded and mottled varieties, and four petrographic types of quartz are developed: microquartz; length-fast (LF) chalcedony; megaquartz; and microspheres. δ¹⁸O values of chert range from 29·6‰ to 30·9‰ (SMOW), which correspond to a broad isotope rank common for biogenic and diagenetic replacement cherts. Calcian dolomite crystals with high Fe and Na are disseminated within the microquartz and LF-chalcedony, but are absent from the megaquartz and host carbonate. The chert is closely associated with desiccation cracks and with interstratal dewatering structures. Load casts are silicified, and laminae rich in sponge spicules are convoluted. Early cracks related to dewatering are filled by microquartz and quartz cements. Ostracod shells within chert are locally fractured; those in the host carbonate are commonly flattened. Late fractures are filled by LF-chalcedony and megaquartz. There is much evidence for the dissolution of sponge spicules and their calcitization in the carbonate host rock. Silica for the Corones cherts was derived from sponges during early diagenesis and shallow burial. Early mechanical compaction and sediment dewatering played a major role in sponge spicule dissolution, migration of silica-rich fluids and the consequent precipitation of chert. Quartz cements continued to be precipitated into the burial environment.  相似文献   

8000-year history of palaeoproductivity in a large boreal lake     

Arto Itkonen  Virpi Marttila  Jarno Meriläinen  Veli-Pekka Salonen 《Journal of Paleolimnology》1999,21(3):271-294

An 8000-year record of palaeoproductivity, based on the chemical and chironomid stratigraphies from Lake Päijänne, S. Finland, was assessed with respect to known morphometric, climatic and anthropogenic events. A gradual trend of dystrophication and an associated decrease in aquatic production was detected during the Holocene, with the following exceptions: (1) high diatom and chironomid production around 8000-6000 cal yr BP, (2) eutrophication around 2000 cal yr BP, and (3) an anthropogenic signal during the last few decades.The changes in chironomid assemblages, before the past few decades, have mainly been shifts in concentration, but not in species composition. Variation in chironomid production was mainly explained by the accumulations of biogenic silicon, carbon and organic matter. Nutrient availability seems to be important in controlling biogenic silicon, which we use to infer past diatom production. The high production ca. 8000-6000 cal yr BP and the fluctuation in chironomid influx after ca. 2000 cal yr BP, however, were probably caused by the proposed warm/dry and cold/wet conditions during these times, respectively. These results highlight the sensitivity of boreal shield lake ecosystems to climatic forcing. In contrast, the pronounced change in the morphometry of the basin around 7000 cal yr BP had little effect on the trophic state of the lake. The human-induced trophic change during the past few decades has affected the Lake Päijänne ecosystem to an extent never experienced before during the last 8000-years.  相似文献   

A Comprehensive Review on Microalgae-Based Biorefinery as Two-Way Source of Wastewater Treatment and Bioresource Recovery     

Sumira Malik  Shristi Kishore  Jutishna Bora  Vishal Chaudhary  Anjali Kumari  Preeti Kumari  Lamha Kumar  Abhaya Bhardwaj 《洁净——土壤、空气、水》2023,51(3):2200044

In the past few years, microalgae have gained huge recognition from the scientific community due to their potential applications in the production of a broad array of bio-based products varying from biofuels to nanoparticles. Due to their elevated growth rate, high tolerance to various types of abiotic stresses, and complex metabolic capacity, microalgae can be used as promising tools for the attainment of a circular bioeconomy. Moreover, they can simply utilize nutrients from wastewater for biorefinery purposes, resulting in resource recovery coupled with wastewater treatment. However, due to their sub-optimal yields and high production costs, microalgae-based bio-products have not yet been commercialized. This review provides insights into the employment of microalgae as an efficient bioresource for the treatment of wastewater with simultaneous enactment as a biorefinery to produce biofuels, biochar, bioplastic, fertilizers, and other high-value bioproducts. Furthermore, the application of microalgal nanoparticles in wastewater treatment and prospects for genetic modification of microalgae for enhanced biorefinery capabilities have also been briefly highlighted.  相似文献   

2022年极端干旱下洞庭湖区水体营养状态变化及改善对策     

王丹阳  韩锦诚  黎睿  汤显强 《湖泊科学》2023,35(6):1970-1978

2022年夏季长江流域遭受极端干旱,在此背景下,围绕长江荆江河段(松滋-城陵矶),东、西、南洞庭湖,松滋河、虎渡河、藕池河三口水系,湘江、资水、沅江、澧水四水尾间河段,以及环洞庭湖主要垸区,开展了原位监测和采样工作,测定了湖泊、河道、沟渠、池塘等各类水体中氮、磷、碳等生源要素和叶绿素a浓度,以及浮游植物种类和丰度。结果显示,东、西、南洞庭湖中,总氮、总磷、溶解态有机碳和叶绿素a浓度均值分别为0.57 mg/L、0.45 mg/L、38 mg/L和5.38μg/L,氮、磷分别以溶解态和颗粒态为主;浮游植物共检出6门37种,以硅藻和绿藻为主,藻类生物量约1.337 mg/L。就综合营养状态指数而言,洞庭湖处于中营养状态,并不显著高于长江和三口四水。极端干旱导致荆江-洞庭湖的水文连通削弱,洞庭湖来自三口的生源要素通量减少,来自四水和湖内自源生产的比重增加;洞庭湖垸区与外部自然河湖的阻隔限制垸内水体自由流动,导致生源要素累积,造成富营养化。2022年极端干旱气象条件下,洞庭湖总磷、叶绿素a、浮游植物数量相比历史阶段数据处于高位,但总氮浓度低于历史水平。恢复水文连通,改善江湖关系,削减内源污染释...  相似文献