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121.
At the inside corner between the South Mid‐Atlantic Ridge (SMAR) and the Cardno fracture zone, the 14°S hydrothermal field, with its abundant silica‐rich sulfides, was identified as a volcanic massif, which provided the first opportunity to study inside corner‐related hydrothermal mineralization. S, Pb, and O isotopes were measured in hydrothermal sulfide samples from the two sites (volcanic top and slope sites) in the 14°S field. The homogeneous Pb isotope values (207Pb/204Pb = 15.466 ? 15.472; 206Pb/204Pb = 18.242 ? 18.252) and the δ34S values (top site, +6.3 to +6.85‰; slope site, +2.37 to +3.36‰) suggest that the source of metals and most of the sulfur is the upper crust, whereas some sulfur is sourced from downward‐penetrating seawater, especially in the top site. The calculated oxygen isotope equilibration temperatures from quartz and seawater are between 94 and 144°C for the top site and between 179 and 196°C for the slope site. These isotopic proxies, together with geological background survey data, have an important implication: Discrepancies between the sites may result from variations in crust permeability, which also affect the mixing level between downward‐penetrating seawater and upward hydrothermal end‐member fluids and determine the various mineralization types.  相似文献   
122.
During a cruise aboard the R/V Hakuho-maru in the northwestern North Pacific in the summer of 1998 the particle number concentrations and the major ionic components of size fractionated aerosols were measured to investigate the aerosol produced by marine biological activity. Continuous low concentrations of nitrate (<1.8 nmol m−3), similar to the marine air background level, were found over the northwestern North Pacific (40–45°N) and the Sea of Okhotsk (44–45°N). Over the Sea of Okhotsk, a high concentration of chlorophyll-a (5.4 mg m−3) in seawater was observed, and atmospheric concentrations of non sea-salt (nss-) sulfate (44 nmol m−3), methane sulfonic acid (MSA) (1.8 nmol m−3) and particle number in the size range of 0.1 < D < 0.5 μm (199 cm−3) were found to be 9, 7, and 2 times, respectively, higher than those in the background marine air. The increase in particle number concentrations mainly in the size range of 0.2 < D < 0.3 μm was likely caused by the increase of biogenic sulfate over the high productive region of the Sea of Okhotsk. In humid air conditions (R.H. > 96%), the increased biogenic sulfate that condensed the large amount of water vapor would not have sufficient solute mass to activate as cloud condensation nuclei (CNN) and would remain as aerosol particles in the marine air with frequent sea-fogs over the high productive region. Biogenic sulfate originating from dimethyl sulfide (DMS) would gradually grow into the CCN size and continuously supply a great number of CCN to the marine air in the northwestern North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
123.
山东半岛硅热流值与区域地质条件的关系   总被引:3,自引:1,他引:3  
据地下水中SiO2含量计算山东半岛硅热流值。以此为基础初步探讨本区的地热场特征及其与区域地质条件的关系。指出:1.山东半岛平均热流值与全球平均热流值接近,但比一般古老地块略高。2.划分出三个地热异常区,在大地构造上,两较高热异常区分别对应于胶北和文登隆起;较低热异常区与胶莱盆地相应。3.地热场总特征及其区域热异常的形态主要与近地表的地层岩性、构造形态和断裂发育程度等地质条件有关,而与中生代的岩浆活动无关,但第四纪岩浆活动对胶北隆起局部(蓬莱一带)热异常有重要作用  相似文献   
124.
孢囊是甲藻生活史中特殊的休眠阶段,被认为是赤潮发生的种源。于2018年4月采集了福建福宁湾海域表层沉积物,对沉积物中甲藻孢囊的分布规律进行了研究,重点揭示有毒有害甲藻孢囊的分布;同时测定了沉积物中生源要素含量,以揭示孢囊分布与生源要素的关系。共鉴定甲藻孢囊25种,其中别什藻(Biecheleria tirezensis)孢囊占据优势。孢囊的种类多样性指数(H'')偏低,为2.06~2.34;均匀度指数(J)为0.71~0.81。孢囊密度介于178.6~386.3 cysts/g (以干重计,下同),平均为286.0cysts/g。孢囊密度高值区位于水深较深、沉积物颗粒较细的长表岛外海域,而低值区则位于长表岛至海尾角的近岸海域。值得注意的是,研究分析鉴定出9种有毒有害甲藻的孢囊,包括麻痹性贝类毒素(paralytic shellfish poisoning,PSP)原因种奥氏亚历山大藻(Alexandrium ostenfeldii)和链状/塔玛亚历山大藻(Alexandrium catenella/tamarense)孢囊复合体、goniodomine A原因种平野亚历山大藻(Alexandrium hiranoi)、虾夷扇贝毒素(yessotoxin,YTX)原因种具刺膝沟藻(Gonyaulax spinifera)和网状原角藻(Protoceratium reticulatum)、产生鱼毒素的哈曼褐多沟藻(Pheopolykrikos hartmannii)以及赤潮藻类Barrufeta bravensis、锥状斯氏藻(Scrippsiella acuminata)和垂裂莱万藻(Levanderina fissa),其中Barrufeta bravensisGonyaulax spiniferaScrippsiella acuminata的孢囊分布广泛且密度较高,需引起关注。  相似文献   
125.
126.
Global change models predict effects of climate change on hydrological regimes at the continental scale in Europe. The aim of this study was to gain a better understanding of the possible effect of changing external forcing conditions on the functioning of estuarine ecosystems. In densely populated areas, anthropogenic nutrient enrichment and consequent alteration of nutrient biogeochemical cycles have already had a big impact on these ecosystems. The average yearly discharge of the upper Schelde estuary increased nearly threefold over the period 1996–2000, from 28 m3 s−1 in 1996 to 73 m3 s−1 in 2000. The continuously rising discharge conditions over the five-year period were used as a reference situation for possible future effects of climate on ecological functioning through increase of discharge. At high discharges, nutrient (NH4+, NO3, dissolved silica and PO43−) concentrations in the tidal fresh- and brackish water showed a decrease of up to 50% while total discharged nutrient loadings increased up to 100%. Opposite effects of increasing discharge on NH4+, NO3 and dissolved silica concentrations in summer and winter, resulted in the flattening out of seasonal cycles for these nutrients. Under high discharge conditions, silica uptake by diatom communities was lowered. Dissolved silica loadings to the coastal area increased concurrently with total silica loadings upstream. Salt intrusion to the marine parts of the estuary decreased. This resulted in a downstream shift of the salinity gradient, with lower salinity observed near the mouth. As a result, TDIN, NO3 and dissolved silica concentrations doubled at the mouth of the estuary.  相似文献   
127.
1 IntroductionFor several reasons, the Arctic Ocean and itsmarginal seas are key areas for understanding ocean-ic circulation and global climate system ( Clark,1982; Hansen et al., 1983; Walsh et al., 1996;Overpeck et al., 1997). First, the Arctic Ocean i…  相似文献   
128.
The pore water concentrations of dissolved silica in sediment cores from the continental slope offshore from Cape Hatteras, North Carolina, varied from 150 to almost 700 μ,M with depth in the top 40 cm of sediment. Sediment cores from 630 to 2010 m depth had very similar profiles of dissolved silica in their pore waters, even though these cores came from regions greatly different in slope, topography, sedimentation rate, and abundance of benthic macrofauna. Cores from 474 to 525 m were more variable, both with respect to pore water dissolved silica profiles, and with respect to sediment texture. Experiments indicate that both the rate of dissolution of silica and the saturation concentration decrease as sediment depth below the sediment-seawater interface increases. These data are consistent with depletion of a reactive silica phase in surface sediment, which may be radiolarian tests, or the alteration of biogenic silica to a less reactive form over time. Experimental results suggest that the pore water dissolved silica concentration in sediments below the top few centimeters may be higher than the sediments could now achieve. The flux of dissolved silica out of these sediments is estimated to be 15 μmoles cm−2 yr−1.  相似文献   
129.
Speleothems of silica are far rarer than those of calcite but occur in a range of types including stalactites, stalagmites and flowstones. This study has found a wider range and far greater number of silica speleothems on the quartz sandstones of the Sydney region than the small number of previous accounts had suggested. Speleothems on the Sydney region sandstones are composed of multiple layers of amorphous opal‐A and cryptocrystalline chalcedony. Silica slowly dissolved from detrital and diagenetic quartz and kaolinite clays of the host arenites is redeposited as opal‐A at the sandstone surface when groundwater evaporates. This amorphous silica converts over time by Ostwald‐type paragenesis to the cryptocrystalline form, but the expected intermediate opal‐CT phase has not been detected. The crystallisation of chalcedony at earth‐surface temperatures is generally believed to take an extremely long time and its presence makes these speleothems very significant, especially as it is reported in only a small number of silica speleothems elsewhere. Furthermore, a similar paragenetic silica‐‘ripening’ mechanism may also be involved in the low‐temperature earth‐surface formation of other crystalline silica deposits such as silcrete duricrusts and pedogenic quartz. Additional closely coupled laboratory and field investigations into the processes that control silica paragenesis under earth‐surface conditions are sorely needed.  相似文献   
130.
Concentrations of biogenic silica(BSi) in the southern Yellow Sea were determined during four cruises(spring:April–May 2014; autumn: November 2014; summer: August–September 2015; winter: January 2016). Samples of BSi were measured using the double extraction method. Seasonal and spatial variations of BSi and the potential correlation between chlorophyll a(Chl a) content and BSi in four seasons were measured in this study. Significant spatial variability was observed in seawater BSi concentrations. The average concentration of BSi was highest in winter and lowest in spring. Furthermore, the relationships between concentrations of BSi and hydrological parameters were also discussed. There was a significant positive correlation between Chl a and BSi. The concentrations of BSi showed significant relationships with temperature and the concentrations of silicates, total inorganic nitrogen and total inorganic phosphorus, indicating that distribution of BSi was affected by temperature and nutrient level.  相似文献   
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