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41.
Biomass Burning in Southern Africa: Individual Particle Characterization of Atmospheric Aerosols and Savanna Fire Samples 总被引:2,自引:0,他引:2
Xiande Liu Piet Van Espen Freddy Adams Jan Cafmeyer Willy Maenhaut 《Journal of Atmospheric Chemistry》2000,36(2):135-155
Ambient atmospheric aerosols and savanna fireparticulate emission samples from southern Africa werecharacterised in terms of particle classes and theirnumber abundance by electron probe X-ray microanalysis(EPXMA). About ten particle classes were identifiedfor each sample. The major classes werealuminosilicates and sea salts for ambient coarse(2–10 m equivalent aerodynamic diameter (EAD))samples, and K-S and S-only particles for ambient fine(<2 m EAD) samples. The K-S particles are oneof the major products of biomass burning. The EPXMAresults were found to be consistent with the resultsfrom bulk analyses on a sample by sample basis. Forsavanna fire fine samples, quantitative EPXMA revealedthat many particles had a composition of simple saltssuch as KCl. Some particles had a deviatingcomposition in the sense that more ionic species wereinvolved in sustaining the balance between cations andanions, and they were composite or mixed salts.Because of extensive processing during the atmospherictransport, the composition of the K-S particles in theambient samples was different from K2SO4,and such particles were enriched with S. The finepyrogenic KCl particles and the fine sea-saltparticles were much depleted in chlorine. 相似文献
42.
采用马弗炉将样品与NaOH混合进行熔融煅烧,热去离子水提取、离心、稀释后过OnGuard Ⅱ H柱和过滤膜进行前处理,抑制型电导离子色谱法检测,测定了Ta2O5和Nb2O5的氟离子、氯离子和硫酸根离子。该方法对三种被测阴离子的检测限(s/N=3)在0.15~0.70μg/g(以固体样品实际浓度计)或0.136~0.623μg/L(以溶液浓度计),标准曲线线性范围均在两个数量级以上,方法的精密度(RSD,n=7)小于5.46%,回收率为88%~106%,具有灵敏度高、选择性好、重现性佳、对环境友好等特点,用于实际样品的检测,结果令人满意。 相似文献
43.
成都经济区农业生态系统土壤镉通量研究 总被引:5,自引:2,他引:5
以四川成都经济区农业生态系统中的重金属Cd为对象,对其在土壤中的输入输出通量进行初步探索。综合各方面的因素,确定以大气干湿沉降、灌溉水、化肥为输入途径和农作物为输出途径进行研究。经过计算,经济区大气干湿沉降通量平均值为17.76g/hm2·a,灌溉水和化肥通量明显较低,三者对土壤Cd污染的贡献率分别为86%、10%和4%。对于6个不同的地区,三者比例略有差别,大气干湿沉降所占比例最高达94%,最低也达到了77%。Cd通过农作物收割输出的量相对较小。土壤Cd年净增量主要受大气干湿沉降的制约,因此大气环境质量应是重点监控的对象。以耕作土体为研究介质,经估算,当前的Cd年平均通量可引起土壤Cd的质量分数升高0.006mg/kg。 相似文献
44.
45.
讨论了在现时泥沙、水体、鱼类、藻类的含镉状态下洞庭湖的输入输出通量;并以其为例,在简要介绍马尔可夫链数学方法的基础上,建立了湖泊生态系统中镉迁移转化的马尔可夫链数学模型,初步评价了当洞庭湖不断有镉加入、系统到达状态稳定时各种介质中的镉总量及镉的迁移转化趋势。 相似文献
46.
Estimation of groundwater recharge using the chloride mass-balance method, Pingtung Plain, Taiwan 总被引:4,自引:0,他引:4
Due to rapid economic growth in the Pingtung Plain of Taiwan, the use of groundwater resources has changed dramatically.
Over-pumping of the groundwater reservoir, which lowers hydraulic heads in the aquifers, is not only affecting the coastal
area negatively but has serious consequences for agriculture throughout the plain. In order to determine the safe yield of
the aquifer underlying the plain, a reliable estimate of groundwater recharge is desirable. In the present study, for the
first time, the chloride mass-balance method is adopted to estimate groundwater recharge in the plain. Four sites in the central
part were chosen to facilitate the estimations using the ion-chromatograph and Thiessen polygon-weighting methods. Based on
the measured and calculated results, in all sites, including the mountain and river boundaries, recharge to the groundwater
is probably 15% of the annual rainfall, excluding recharge from additional irrigation water. This information can improve
the accuracy of future groundwater-simulation and management models in the plain.
Received, April 1996 Revised, March 1997, November 1997 Accepted, March 1998 相似文献
47.
The application of a modified version of dynamic TOPMODEL for two subcatchments at Plynlimon, Wales is described. Conservative chemical mixing within mobile and immobile stores has been added to the hydrological model in an attempt to simulate observed stream chloride concentrations. The model was not fully able to simulate the observed behaviour, in particular the short‐ to medium‐term dynamics. One of the primary problems highlighted by the study was the representation of dry deposition and cloud‐droplet‐deposited chloride, which formed a significant part of the long‐term chloride mass budget. Equifinality of parameter sets inhibited the ability to determine the effective catchment mixing volumes and coefficients or the most likely partition between occult mass inputs and chloride mass inputs determined by catchment immobile‐store antecedent conditions. Some success was achieved, in as much as some aspects of the dynamic behaviour of the signal were satisfactorily simulated, although spectral analysis showed that the model could not fully reproduce the 1/f power spectra of observed stream chloride concentrations with its implications of a wide distribution of residence times for water in the catchment. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
48.
Chloride is a major anion in soil water and its concentration rises essentially as a function of evapotranspiration. Compared to herbaceous vegetation, high transpiration rates are measured for isolated trees, shelterbelts or hedgerows. This article deals with the influence of a tree hedge on the soil and groundwater Cl? concentrations and the possibility of using Cl? as an indicator of transpiration and water movements near the tree rows. Cl? concentrations were measured over 1 year at different depths in the unsaturated zone and in the groundwater along a transect intersecting a bottomland oak hedge. We observed a strong spatial heterogeneity of Cl? concentrations, with very high values up to 2 g l?1 in the unsaturated zone and 1·2 g l?1 in the upper part of the groundwater. This contrasts with the low and homogeneous concentrations (60–70 mg l?1) in the deeper part of the groundwater. Cl? accumulation in the unsaturated zone at the end of the vegetation season allows us to identify the active root zone extension of trees. In winter, upslope of the tree row, downwards leaching partly renews the soil solution in the root zone, while the slow water movement under the trees or farther downslope results in Cl? accumulation and leads to a salinization of the soil and groundwater. This salinization is of the same order as experimental conditions produce negative effects on oak seedlings. The measurement of Cl? concentrations in the unsaturated zone under tree rows at the end of the vegetation season would indicate whether certain topographic, pedological or climatic conditions are likely to favour a strong salinization of the soil, as observed in the present study. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
49.
Lei Yanju Zhang Wenbing Xu Wei Zhang Yanjiao Zhou Huihui Mai Kangsen 《中国海洋大学学报(英文版)》2015,14(3):511-521
The aim of this study was to compare the effects of waterborne copper(Cu) and cadmium(Cd) on survival, anti-oxidative response, lipid peroxidation and metal accumulation in abalone Haliotis discus hannai. Experimental animals(initial weight: 7.49 g ± 0.01 g) were exposed to graded concentrations of waterborne Cu(0.02, 0.04, 0.06, 0.08 mg L-1) or Cd(0.025, 0.05, 0.25, 0.5mg L-1) for 28 days, respectively. Activities of the anti-oxidative enzymes(catalase, CAT; superoxide dismutase, SOD; glutathione peroxidases, GPx; glutathione S-transferase, GST), contents of the reduced glutathione(GSH) and malondiadehyde(MDA) in the hepatopancreas, and metal accumulation in hepatopancreas and muscles were analyzed after 0, 1, 3, 6, 10, 15, 21, 28 days of metal exposure, respectively. Results showed that 0.04 mg L-1, 0.06 mg L-1 and 0.08 mg L-1 Cu caused 100% death of abalone on the 21 st, 10 th and 6th day, respectively. However, no dead abalone was found during the 28-day waterborne Cd exposure at all experimental concentrations. Generally, activities of SOD and GST in hepatopancreas under all Cu concentrations followed a decrease trend as the exposure time prolonged. However, these activities were firstly increased and then decreased to the control level and increased again during Cd exposure. Activities of CAT in all Cu exposure treatments were higher than those in the control. These activities were firstly increased and then decreased to the control level and increased again during Cd exposure. Contents of MDA in hepatopancreas in all Cu treatments significantly increased first and then decreased to the control level. However, the MDA contents in hepatopancreas were not significantly changed during the 28-day Cd exposure. The metals accumulation in both hepatopancreas and muscles of abalone significantly increased with the increase of waterborne metals concentration and exposure time. These results indicated that H. discus hannai has a positive anti-oxidative defense against Cu or Cd. In conclusion, anti-oxidative mechanism in abalone to resist waterborne Cu did not follow the same pattern as that for waterborne Cd. 相似文献
50.