上扬子地台区晚古生代海相碳酸盐岩的碳,锶同位素研究   总被引：79，自引：4，他引：79       下载免费PDF全文

黄思静 《地质学报》1997,71(1):45-53

未经蚀变的海相碳酸盐岩的碳，锶同位素组成代表了原始海水的同位素组成，在确定样品末经显著蚀变的基础上，本文测定了上扬子地区晚古生代７条剖面２３８个海相碳酸盐岩样品的碳、锶同位素组成，分布了它们的测试结果和演化曲线，为其他相关研究提供了可利用的基础参照数据。  相似文献   

洋岛,海山碳酸盐岩的沉积特征及其古地理意义   总被引：7，自引：1，他引：7  

张海清  孙晓猛 《地质科技情报》1997,16(1):29-33

高出水面的洋岛和潜伏水下的海山普遍存在于现代地球表面的各大洋中，地质历史中存在的古洋岛和古海山也逐渐为人们所认识。笔者从地形特征，沉积学特征，成岩作用和生物学特征几个方面对洋岛，海山进行了分析，洋岛，海山通常具有洋岛型火山岩基底和碳酸盐盖层的双层式地层结构，具有低分异度，探讨了古洋岛，古海山的鉴别对于再造古海洋，古地理格局的现实意义。  相似文献   

河北小营盘石英—碳酸盐型金矿成矿地质特征     

邱小平  潘淼 《黄金地质》1997,3(4):29-35

小营盘金矿赋存在稳定的缓倾斜石英脉中，但单纯的白色石英脉仅有微弱矿化，只有经过Ｓ懊断层剪切拉张破裂和叠加铁白云石化及硫化物蚀变的石英脉才能成为矿体，金矿体的顶底面常被铁白云石蚀变岩和糜棱岩所包裹，而且部分蚀变岩的金含量也达到工业品位，石英脉与蚀变岩作用构成矿体。因此，早期金成矿作用的时代大致与铁白云蚀变同期，含金铁白云石蚀变岩的δ＾１３Ｃ值平均为－４．１３‰，Ｐｂ－Ｐｂ等时线年龄为２７１１±２３８  相似文献   

Biomarkers in the Molar Tooth （MT）-Bearing Limestones in the Jilin-Liaoning Area of China   总被引：2，自引：1，他引：2  

旷红伟  李艳霞  曾艳涛  孟祥化  葛铭 《中国地球化学学报》2004,23(4):334-341

The origin of Molar Tooth (MT) carbonates has been argued for more than 100 years, which are a kind of Proterozoic carbonates especially composed of microsparite with ptygmatically folded and sheet-like structures. Biomarkers detected in the microcalcsparite from the Wanlong and Xingmincun formations in the Jilin-Liaoning area showed there are abundant normal alkanes, isoprenoids, hopanes, steranes, alkylmethylcyclohexanes, and alkyleyclohexanes, indicating a diversity of biological source: long-chain isoprenoids, the major components of chlorophyll, such as C19, C20, a kind of major biomarkers synthesized early by isoprenoid monomers; hopanes a type of characteristic biomarkers from prokaryote, such as archaebacteria and cyanobacteria; sterane a biomarker for eukaryote; and two kinds of alkanes with C17, C18 as the main peaks representing aquatic bacteria and with C23, C24 as the main peaks representing fungi, respectively. Biomarker analysis showed that MT is the result of bacterial and algal activities, which is a kind of organisms between aerobic and anaerobic bacteria, reproducing well in normal or slightly saline sea water under weak oxidation-reduction conditions, resulting in rapid deposition of calcite as microsparite clue to some mechanisms.  相似文献   

鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究   总被引：15，自引：0，他引：15  

刘德汉  付金华  郑聪斌  肖贤明  米敬奎 《地质学报》2004,78(4):542-550

用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%～ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰～ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰～ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因  相似文献   

碳酸盐岩储层缝洞发育带预测:以塔河油田为例     

王世星  管路平  朱海龙 《应用地球物理》2004,1(1)

塔河油田碳酸盐岩为古岩溶喀斯特化与受后期构造叠置改造的孔、洞、缝等组成的非均质储层,储层具有规模不同、空间形态不规则、充填性质各异的复杂组合特征以此为对象通过分解地震波场不同特征信号,开发了一系列针对不同储层目标的叠前叠后地震预测技术,不同特征地震预测结果经综合叠置验证分析,实现了残丘体上叠置的孔、洞、缝及古地貌的精细刻画及表征,展示了缝洞空间纵横交错的叠置关系,提高了复杂储层空间展布规律的认识及精确定位。  相似文献   

山东胜利油田车镇地区下古生界碳酸盐岩潜山储集层特征   总被引：1，自引：3，他引：1  

宋来明  彭仕宓  李国蓉  贾达吉 《现代地质》2004,18(2):263-268

碳酸盐岩潜山储层研究一直是油气地质研究领域的一个难点。以大量的岩心、薄片观察为基础 ,对研究区的岩石学特征进行描述 ,进而提出研究区 5种主要的储渗空间类型 :溶蚀孔隙型、溶蚀孔洞型、大型洞穴、风化裂隙型以及构造裂隙型储渗空间。通过研究认为 ,这 5种储渗空间构成了研究区的 5类储层 :风化裂隙型储层、构造裂隙型储层、裂隙孔洞型储层、溶蚀孔洞型储层以及洞穴型储层 ,其中以风化裂隙型储层、裂隙—孔洞型储层以及溶蚀孔洞型储层为主。结合钻井、录井、测井、试井资料 ,对 5类储层的特征进行总结 ,从而进一步对潜山储层发育作出评价 ,将研究区储层发育带分为 3类 ,提出车镇地区下古潜山储层主要沿北东—南西方向呈条带状规律展布的观点。  相似文献   

成像测井技术在碳酸盐岩水平井中的应用   总被引：4，自引：1，他引：4  

郑玉玲  赵冬梅  胡国山  李冬梅 《新疆地质》2004,22(3):319-322

塔里木盆地北部地区碳酸盐岩油藏储层，非均质性较强，只依靠常规测井判断碳酸盐岩裂缝、溶孔、溶洞很困难．利用地层微电阻率扫描成像(FMI)，对碳酸盐岩水平井储层进行定性分析、定量解释，并能准确识别出碳酸盐岩目的层裂缝的性质、大小、开度、溶蚀孔洞原生孔隙、次生孔隙的发育情况等．同时并利用测试、酸压资料验证了使用成像测井判断裂缝的有效性．  相似文献   

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials   总被引：6，自引：1，他引：6  

Jean Carignan  Damien Cardinal  Anton Eisenhauer  Albert Galy  Mark Rehkamper  Frank Wombacher  Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   

High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献