胶州湾表层海水碳酸盐体系的季节变化     

邓雪  胡玉斌  刘春颖  杨桂朋  陆小兰  张洪海 《海洋与湖沼》2016,47(1):234-244

根据2007年8月(夏季),11月(秋季),2008年1月(冬季)和2010年4月(春季)在胶州湾海域测得的p H、溶解无机碳(DIC)、总碱度(Alk),以及通过以上参数计算得到的二氧化碳分压(p CO2)的数据,结合现场的化学、水文、生物等参数,探讨和分析了该海域的二氧化碳各参数的分布特征、季节变化和影响因素。结果表明:胶州湾p H、DIC、Alk和p CO2的年变化范围分别为:7.77—8.30,1949.2—2201.8μmol/kg,2033.9—2382.5μmol/kg和89.9—745.3μatm,均呈现明显的时空变化。温度是影响胶州湾碳酸盐体系的主要影响因素之一,同时陆地径流和降水会降低海水碳酸盐体系中各参数的含量,但是人类活动和生物活动也会在一定程度上增加DIC、Alk和p CO2的含量。  相似文献   

Origin of abundant moonmilk deposits in a subsurface granitic environment     

《Sedimentology》2018,65(5):1482-1503

Subsurface granitic environments are scarce and poorly investigated. A multi‐disciplinary approach was used to characterize the abundant moonmilk deposits and associated microbial communities coating the granite walls of the 16th Century Paranhos spring water tunnel in Porto city (north‐west Portugal). It is possible that this study is the first record of moonmilk in an urban subsurface granitic environment. The morphology and texture, mineralogical composition, stable isotope composition and microbial diversity of moonmilk deposits have been studied to infer the processes of moonmilk formation. These whitish secondary mineral deposits are composed of very fine needle‐fibre calcite crystals with different morphologies and density. Calcified filaments of fungal hyphae or bacteria were distinguished by field emission scanning electron microscopy. Stable isotope analysis revealed a meteoric origin of the needle‐fibre calcite, with an important contribution of atmospheric CO ₂, soil respiration and from weathering of Ca‐bearing minerals. The DNA ‐based analyses revealed the presence of micro‐organisms related to urban contamination, including Actinobacteria, mainly represented by Pseudonocardia hispaniensis , Thaumarchaeota and Ascomycota, dominated by Cladosporium . This microbial composition is consistent with groundwater pollution and contamination sources of the overlying urban area, including garages, petrol stations and wastewater pipeline leakage, showing that the Paranhos tunnel is greatly perturbed by anthropogenic activities. Whether the identified micro‐organisms are involved in the formation of the needle‐fibre calcite or not is difficult to demonstrate, but this study evidenced both abiotic and biogenic genesis for the calcite moonmilk in this subsurface granitic environment.  相似文献   

川北地区寒武系筇竹寺组钙质结核裂缝充填物特征及指示意义   总被引：1，自引：0，他引：1  

冯明友  郑江  刘田  刘小洪  张家强  梅文华  孙霓源  龙涛 《地质论评》2018,64(3):711-722

川北地区寒武系筇竹寺组钙质结核泥页岩中早成岩期钙质结核较发育,结核裂缝中见多期次矿物充填。为揭示钙质结核裂缝形成机理,本次结合岩石学特征及地球化学特征等开展系统研究。川北筇竹寺组钙质结核裂缝中见三~四期矿物充填。第一期微晶方解石表面较脏,阴极发光暗淡,δ13C_(PDB)、δ18O_(PDB)平均值分别为-4.26‰及-7.69‰;第二期为细—中晶粒状方解石充填,阴极发光为橘黄色,流体包裹体均一温度为平均值为86.4℃,δ13C_(PDB)、δ18O_(PDB)平均值分别为-3.15‰及-7.41‰;第三期为粗晶方解石充填阴极发光暗淡,流体包裹体均一温度平均值为96.6℃,δ~(13)C_(_(PDB))、δ~(18)O_(_(PDB))平均值分别为-1.73‰及-10.28‰;第四期为重晶石充填。结合区域构造史—热演化史分析表明,钙质结核裂缝中四期充填物分别指示早期脱水、烃源岩早成熟期生烃、加里东构造运动抬升释压及深埋藏期硫酸盐热还原作用事件。  相似文献   

Paleogene stratigraphy of Kutch,India: an update about progress in foraminiferal biostratigraphy     

Pratul Kumar Saraswati  Sonal Khanolkar  Santanu Banerjee 《Geodinamica Acta》2018,30(1):100-118

The Paleogene sections of Kutch are the reference for the regional chronostratigraphic units of India. The ages of these dominantly shallow marine carbonates are mainly based on larger benthic foraminifera (LBF). The taxonomic revisions of the LBF and the progressively refined shallow benthic zonations (SBZ) have necessitated the present study on updating the stratigraphy of the area. The sedimentation in Kutch commenced with the deposition of volcaniclastics in terrestrial environments in the Paleocene. The marine transgression in SBZ 5/6 deposited finer clastics and carbonates, designated as Naredi Formation, in early Eocene. There is no evidence of marine Paleocene in Kutch. A major hiatus spanning SBZ 12 to SBZ 16 was followed by the development of a carbonate platform and deposition of Harudi Formation – Fulra Limestone during the Bartonian, SBZ 17. The hiatus corresponds to a widespread stratigraphic break in Pakistan and India to Australia, referred as the ‘Lutetian Gap.’ The Maniyara Fort Formation is assigned to SBZ 22 B and SBZ 23, and its age is revised to Chattian. Climate played a major role in building up of the Paleogene stratigraphic succession of Kutch, the carbonates formed during the warming intervals and the stratigraphic gaps were in the intervening cooling periods.  相似文献   

Larger Foraminiferal Biostratigraphy and Facies Analysis of the Oligocene–Miocene Asmari Formation in the Western Fars Sub-basin, Zagros Mountains, Iran     

Tahereh HABIBI  Telm BOVER-ARNAL 《《地质学报》英文版》2018,92(6):2079-2097

The Oligocene–Miocene carbonate record of the Zagros Mountains, known as the Asmari Formation, constitutes an important hydrocarbon reservoir in southern Iran. This marine carbonate succession, which developed under tropical conditions, is explored in terms of larger foraminiferal biostratigraphy, facies analysis and sequence stratigraphy in a new section at Papoon cropping out in the western Fars sub-basin, in the south-east of the Zagros belt. Facies analysis shows evidence of re-working and transport of skeletal components throughout the depositional system, interpreted here as a carbonate ramp. The foraminifera-based biozones identified include the Globigerina–Turborotalia cerroazulensis–Hantkenina Zone and Nummulites vascus–Nummulites fichteli Zone, both of Rupelian age, the Archaias asmaricus–Archaias hensoni–Miogypsinoides complanatus Zone of Chattian age and the ‘Indeterminate’ Zone of Aquitanian age. The vertical sedimentary evolution of the formation exhibits a progressive shallowing of the facies belts and thus the succession is interpreted as a high-rank low-order regressive systems tract. This long-lasting Rupelian–Aquitanian regressive event is in accordance with accepted global long-term eustatic curves. Accordingly, long-term eustatic trends would have been a factor controlling accommodation during the deposition of the Asmari Formation studied in the western Fars sub-basin.  相似文献   

Sinian-Cambrian Tectonic Framework in the Tarim Basin and its Influences on the Paleogeography of the Early CambrianEI北大核心CSCD     

Yan W.  Wu G.  Zhang Y.  Yang G.  Lou H.  Wang X. 《大地构造与成矿学》2018,(3):455-466

Due to strong remodification and sparse trace remnants, tectonic restoration is critical for the reconstructing of the paleography and basin-prototype in the multiple-cycles superimposed basin, which is also fundamental for the hydrocarbon exploration of the deep marine carbonate in the Tarim Basin. This study presents the tectonic framework of the transition phase from the Sinian to the Cambrian Period and its constrains on the paleography of the Cambrian in the Tarim Basin based on comprehensive analysis of new geochronology data, seismic data and regional tectonic data. The results showed that (1) there is a large regional unconformity between the Cambrian and Precambrian, suggesting a discontinuous deposition from the Sinian to the Cambrian that is contrary to the major view; (2) a broad flattened paleotopography formed before Cambrian Period, which is favorable for the wide epicontinental sea environment and a gentle homoclinal ramp platform development in the early Cambrian, and the residual basement low relief uplifts that influence the microfacies differentiation in the carbonate platform; (3) the Cambrian carbonate platform has been involved much into the marginal orogenic belts, and the proto-platform is probably of 200 km out of the present basin in S-N direction; (4) there is a weak extensional setting in the Cambrian-Early Ordovician rather than a strong rifting setting with a large aulacogen into the platform, in which a inter-platform shallow depression and stable ramp platform developed in the Cambrian; (5) there is not troughs, but rather low relief uplifts developed in the Early Cambrian in the southwestern Tarim Basin, and lack of large uplifts along the carbonate platform margins; (6) it is showed a broad architecture of platform-wide slope-ocean basin from the inner Tarim plate to its margin in the Cambrian Period. Considering the basin prototype, the restoration of the tectono-paleography in the early Cambrian in the Tarim Basin is distinct from those of the previously proposed. We propose that a gentle pattern with “two platforms and one inter-depression” in E-W striking other than multiple small platform constrained in the basin, and further subdivision of the western platform with inner platform low uplift and sag in N-S striking, which is possibly inherited from the basement architecture. On the outer of the united platform, there is probably broad gentle slope for transition to ocean basin. We therefore argue that tectonic restoration is crucial for reconstruction of the paleogeography and basin prototype, especially for basins experienced multiphase of tectonic cycles. © 2018, Science Press. All right reserved.  相似文献   

碳酸盐岩风化过程中高场强元素的地球化学行为研究——来自碳酸盐岩淋溶实验的证据   总被引：1，自引：0，他引：1  

冯志刚  刘炫志  韩世礼  马强 《中国岩溶》2018,37(3):315-329

选择黔中地区的一条白云岩原位风化剖面（平坝剖面）作为研究对象,通过对岩-土界面之下的岩粉层（砂状碳酸盐岩）动态淋溶过程中高场强元素（HFSE）地球化学行为的研究,并结合其在风化壳剖面的分布特征,获得了以下主要认识:（1）碳酸盐岩风化过程中,HFSE间存在明显的分馏,而且元素分馏主要出现在岩-土界面作用过程中,即碳酸盐岩溶蚀形成残积土阶段;元素的地球化学惰性由强到弱的顺序依次为Zr>Hf>Nb>Sc>Th>Ta>Ti>Y,其中,Zr是最稳定的元素,Hf仅次于Zr,Nb和Sc也相对较为惰性,而Th、Ta、Ti、Y呈现出明显的活性;（2）对于碳酸盐岩风化剖面的质量平衡计算,Zr是理想的参比元素（即惰性元素）;（3）由基岩酸不溶物至风化壳剖面,元素对Nb-Ta、Zr-Hf显示出较好的协变性,没有明显分馏,因此,在利用这类元素对岩溶区风化壳的物源进行示踪时,碳酸盐岩作为潜在母岩,宜采用其酸不溶物作为参比对象;（4）碳酸盐岩风化过程中,虽然Sc也是一个较为稳定的HFSE,但在风化母岩中分布不均匀,不宜用于岩溶区风化壳的物源示踪。   相似文献   

东营凹陷沙河街组碳酸盐胶结物成因机制     

孟伟  隋风贵  郝雪峰  张守鹏  秦峰  伍松柏 《地质论评》2021,67(Z1):67z1107-67z1108

正碳酸盐矿物是砂岩储层中主要的成岩产物之一。碳酸盐胶结物较为活跃,其溶蚀及沉淀广泛发育于砂岩储层内。碳酸盐的溶蚀及沉淀是砂岩储层改造的重要成因之一。明确碳酸盐胶结物的成因机制对预测深部储层具有重要的意义。本次研究,采用铸体薄片及扫描电镜观察,明确碳酸盐胶结物的产状。对不同产状碳酸盐胶结物的分布、  相似文献   

碳酸盐岩铸体薄片面孔自动提取研究     

杜相仪  董少群  曾联波  何娟  孙福亭 《地质论评》2021,67(6):1910-1920

岩石孔隙是储层储集油气的重要场所,通过铸体薄片进行岩石孔隙结构分析对储层质量评价具有重要意义。碳酸盐岩孔隙结构较为复杂,铸体薄片图像中存在大量噪声和干扰因素,致使常规方法面孔提取效果不佳,因此本文引入一种多阈值铸体薄片面孔自动提取方法（ctsPore方法）进行孔隙区域提取和面孔率估计,方法综合利用HSV色彩空间中不同参数提取孔隙区域。本文针对碳酸盐岩储层的特点确定了一套ctsPore阈值参数,以解决溶蚀孔与噪声易混淆的问题。实验以伊拉克A油田中新统 Asmari组A段碳酸盐储层为例对所使用算法进行了效果检验。算法精度和效率分析实验表明,基于ctsPore方法的碳酸盐岩铸体薄片面孔提取误差小于0.24%。全井段铸体薄片分析结果表明,A段储层面孔率范围主要分布在6%~8%,储层较为致密,从上到下A1~A3小层的储层平均面孔率分别为6. 9%、11.7%、5.4%,与储层物性、沉积微相和岩性等纵向分布规律较为吻合。  相似文献   

钙同位素地球化学研究新进展及其在碳酸岩-共生硅酸盐研究中的应用     

向蜜  龚迎莉  刘涛  田世洪 《地质学报》2021,95(12):3937-3960

作为"非传统稳定同位素"家族成员,钙同位素正受到国际地学界日益广泛的关注.钙是主要的造岩元素,也是生物必需的元素.钙在地球各圈层广泛分布,研究钙同位素的地球化学行为将有助于提高我们对各种生物过程和地质过程的认识.钙同位素测定主要采用热电离质谱仪(TIMS)和多接收电感耦合等离子体质谱仪(MC-ICP-MS),分别表示为δ44/40 Ca和δ44/42Ca.目前自然界可观测到的δ44/40Ca变化范围为-2.0‰～6.75‰,约8.7‰.本文系统介绍了近年来钙同位素分析中样品溶解、化学分离、质谱测定以及高温地质过程中的钙同位素分馏及其地质应用等方面的研究成果,尤其对钙同位素在碳酸岩-共生硅酸盐岩研究中的意义、钙同位素组成以及取得的主要认识作了较为全面的介绍.阐述了放射成因40 Ca、部分熔融作用/分离结晶作用、地壳同化作用、古俯冲碳酸盐循环、热液蚀变作用、岩浆起源深度等对碳酸岩、硅酸盐岩的钙同位素组成造成的影响.最后,通过系统对比碳酸岩-共生硅酸盐岩的锂、镁、钙同位素研究成果,认为应该开展多元同位素体系的联合示踪.由于不同同位素体系存在相似性和差异性,而多元同位索体系相结合能有效地加强优势互补,将是同位素地球化学研究发展的一种必然趋势.  相似文献