The Production of Methanol by Flowering Plants and the Global Cycle of Methanol   总被引：10，自引：0，他引：10  

I. E. Galbally  W. Kirstine 《Journal of Atmospheric Chemistry》2002,43(3):195-229

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.  相似文献   

百色盆地那读组短期基准面旋回层序分析   总被引：14，自引：3，他引：14  

彭军  郑荣才  陈景山  蔡勋育  韦景春 《沉积学报》2002,20(2):203-209

以高分辨率层序地层学理论和技术方法为指导，运用短期基准面旋回界面的识别标志将百色盆地那读组短期基准面旋回层序划分为向上“变深”的非对称型（A 型）、向上变浅的非对称型（B 型）、向上变深复变浅的对称型（C型）等三种基本结构类型，再根据可容纳空间大小和上下两个半旋回的厚度进一步划分为七个亚类型:即低可容纳空间向上“变深”的对称型（A₁型），高可容纳空间向上“变深”的非对称型（A₂型），低可容纳空间向上变浅的非对称型（B₁型），高可容纳空间向上变浅的非对称型（B₂型），完全-近完全对称型（C₁型），以上升半旋回为主的不完全对称型（C₂型），以下降半旋回为主的不完全对称型（C₃型）。文中详细讨论了每个基本类型和亚类型的沉积背景、叠加样式、岩性组成和沉积动力学过程，并指出有利储集砂体在每种类型中的发育部位。在此基础上，总结了短期基准面旋回层序的变化规律和分布模式，指出从陆地向湖盆，短期基准面旋回层序类型具有从A₁型!A₂型!C₂型!C₁型!C₃型!B₁型!B₂型的变化规律，并简述了短期基准面旋回层序在油气勘探开发中的研究意义。  相似文献   

原油在储层介质中的加水裂解生气模拟实验   总被引：5，自引：2，他引：5  

冯子辉  侯读杰等 《沉积学报》2002,20(3):505-509

采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。  相似文献   

冰芯记录中末次间冰期-冰期旋回气候突变事件的研究进展   总被引：9，自引：2，他引：9  

王有清  姚檀栋 《冰川冻土》2002,24(5):550-558

冰芯记录中的气候变化是古气候研究中的重要组成部分. 极地、中低纬度和热带地区的冰芯记录表明, 在冰期间冰期旋回大尺度气候变化背景下, 全球经历了一系列数百年至千年时间尺度的快速气候突变事件, 诸如末次间冰期的干冷事件、末次冰期的DansgaardOeschger事件、 Heinrich事件和Younger Dryas事件等, 虽然这些穿插在冰阶中的暖湿气候事件、间冰阶中的干冷气候事件的成因、机制和影响范围还存在明显的不确定性. 主要介绍不同区域冰芯记录中末次间冰期冰期旋回这些气候突变事件发生的时间、过程和机制等的研究进展.  相似文献   

深切怀念我们的导师-李连捷院士          下载免费PDF全文

石元春  林培 《第四纪研究》2002,22(1):47-56

李连捷院士是杰出的土壤地理学家、我国土壤学的创始人之一，也是土壤地质学派的创史人。他有关土壤发生的地学基础背景的正确而鲜明的学术思想引导着土壤地理和土壤资源的研究、土地资源开发和研究生培养工作。他一方面不断学习国际上在这方面的学术发展动向及前沿；另一方面紧密结合中国发展的生产实际。他在20世纪50-60年代以综合考察，70年代以后以扎根基点的形式发展土壤科学、培养研究生。他一生刚正不阿、高风亮节，实为一代宗师。  相似文献   

鄂尔多斯盆地上古生界高分辨率层序地层分析   总被引：35，自引：1，他引：35  

郑荣才  文华国  梁西文 《矿物岩石》2002,22(4):66-74

按基准面旋回原理，将鄂尔多斯盆地上古生界本溪组（C2b)、太原组（P1t）、山西组(P1s)和下石盒子组（P1xs)划分为3个超长期、8个长期、19个中期和62个短期旋回层序：较为详细地介绍了各级别层序的结构类型、叠加样式和沉积演化序列；建立以长期旋回层序为年代地层框架，中期旋回层序为等时地层对比单元的层序的地层格架；并讨论高分辨率层序地层与天然气藏的关系。  相似文献   

Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes   总被引：7，自引：0，他引：7  

M. Satish-Kumar  H. Wada  M. Santosh 《Journal of Metamorphic Geology》2002,20(3):335-350

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.  相似文献   

Analyzing CO2 emissions mitigation by technology improvement in Central and Eastern Europe     

Diana Ürge-Vorsatz  Adam Szeszler 《GeoJournal》2002,57(3):211-226

As a legacy of the centrally planned economy, the economies in transition of Central and Eastern Europe (CEE) have a unique potential to reduce their greenhouse gas emissions through the improvement in their high energy intensities. Since much of this `low-hanging fruit' in energy-efficiency improvements can be highly cost-effective, many developed countries facing difficulties in meeting their greenhouse gas (GHG) emission targets domestically are eager to find such opportunities in the CEE region. Therefore, studies analysing the potentials and costs of carbon dioxide reduction through technology improvement in the region have come into the limelight. While there are a few excellent studies in the region aimed at analysing climate change abatement potentials, they all embark on different assumptions, methodologies and boundary conditions. It is hence difficult, if not impossible, to compare and analyse the results of these studies across different authors, countries or time horizons. Consequently, the purpose of this paper is to place four leading studies on GHG mitigation through technology improvement from the CEE region into an internationally comparable framework. Four studies were selected from three countries, Poland, Hungary and Estonia, which are all the results of major national and international efforts to assess costs and potentials of GHG reduction. The paper places their assumptions, methods and final results into a framework which enables policy-makers and project designers to compare these across geographical and technological boundaries. Since other studies from around the globe have been analysed in this framework in the literature, this paper provides a vehicle for the findings of these four studies to be compared to others worldwide. In addition, the paper highlights a few areas where similar studies to be completed in the future in the region may be enhanced by incorporating features used in GHG mitigation research in other parts of the world. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

云南腾冲地块北部空树河组一个菱铁矿结核中的C、O同位素变化特征     

金小赤 《地球学报》2002,23(1):37-41

空树河组是滇西腾冲地块北部的石碳－二叠纪冈瓦纳相沉积。菱铁矿结核见于该组顶部的黑色泥岩中。将一个结核通过中心切开，在切面上由中心向边缘用牙钻等间隔提取10个样品。同位素测试结果显示，δ^13C自中心向边缘逐渐由－8．09％减为－16．12％，最外一个样例外（－15．39‰），而δ^18O自中心向边缘逐渐由－10．64‰增加为0‰左右。δ^13C的变化情况表明，菱铁矿结核可能形成于硫酸盐还原带。在解释δ^18o的变化情况时，推测在结核开始生长时可能有δ^18O亏损的大气降水掺入，随着埋藏深度的逐渐加大，孔隙水的O同位素逐渐趋近正常海水的值（0‰）。  相似文献   

Study on Paleoenvironment since Late Glacial Eooch in Lanzhou Area, China     

Yang Guifang  Yin Hongfu  Li ChangAn 《中国地质大学学报(英文版)》2002,13(1)

The Hongzuisi Section in Lanzhou area is used to infer the paleoclimate since the late glacial epoch. Through combined analysis of organic carbon isotope and CaCO3 content, paleoenvironment evolution of Hongzuisi Section since the late glacial epoch is discussed. There were changes in both drymoist and warm-cold. Especially the climate changes can be compared with synchronous sections of other areas, which provides useful information for our future forecast.  相似文献