Trace metals in suspended particulate matter and in sediment trap material from a permanently anoxic fjord — Framvaren, South Norway     

Jens M. Skei  Douglas H. Loring  Reijo T. T. Rantala 《Aquatic Geochemistry》1996,2(2):131-147

Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.  相似文献   

An integrable case of a rotational motion analogous to that of Lagrange and Poisson for a gyrostat in a Newtonian force field     

J. A. Cavas  A. Vigueras 《Celestial Mechanics and Dynamical Astronomy》1994,60(3):317-330

The scope of the present paper is to provide analytic solutions to the problem of the attitude evolution of a symmetric gyrostat about a fixed point in a central Newtonian force field when the potential function isV ⁽²⁾.We assume that the center of mass and the gyrostatic moment are on the axis of symmetry and that the initial conditions are the following: (t ₀)=₀, (t ₀)=₀, (t ₀)=(t ₀)=₀, ₁(t ₀)=0, ₂(t ₀)=0 and ₃(t ₀)= ₃ ⁰ .The problem is integrated when the third component of the total angular momentum is different from zero (B ₁ 0). There now appear equilibrium solutions that did not exist in the caseB ₁=0, which can be determined in function of the value ofl ₃ ^r (the third component of the gyrostatic momentum).The possible types of solutions (elliptic, trigonometric, stationary) depend upon the nature of the roots of the functiong(u). The solutions for Euler angles are given in terms of functions of the timet. If we cancel the third component of the gyrostatic momentum (l ₃ ^r =0), the obtained solutions are valid for rigid bodies.  相似文献   

Mid-infrared imaging of ultracompact H II regions     

T. L. Hayward  J. W. Miles  J. R. Houck  T. K. Timberlake 《Experimental Astronomy》1994,3(1-4):159-160

We discuss preliminary results of an 11.7 m imaging survey of ultracompact H II regions from the Wood and Churchwell radio survey. We find that that the morphologies of ionized gas and warm dust are often significantly different, indicating that an H II region classification scheme should be based on more than radio data.  相似文献   

江西省安福地区地热水化学特征研究     

余廷溪  刘凯  孙军亮  王路瑶  王书训 《地球学报》2024,45(1):99-111

为研究江西安福地区水文地球化学特征及控制因素, 本文采集了15组样品, 采用水化学、同位素分析等方法进行研究。结果表明: 研究区地热水以Na-HCO3型水为主, 地下水以HCO3-Na·Ca型为主, 地表水由西南向东北从HCO3-Na·Ca向HCO3-Ca型水演化。水化学组分演化过程主要受岩石风化作用控制, 地层封闭性较差, 水中的Na+、HCO– 3、Sr2+来源于硅酸岩风化溶解。由稳定同位素特征可知, 研究区地热水补给来源为大气降水。研究区热储温度为49.8~101.4 ℃, 地热水循环深度为1 502.6~1 513.6 m。热水在沿断裂带上升过程中与浅层冷水发生混合, 其混合比例为76.1%~87.5%。研究成果为安福地区水循环演化提供依据, 有利于地热资源的合理开采与保护。  相似文献   

Geochemistry of recent hydrothermal systems of Mendeleev Volcano （Kuril Islands） and surrounding waters     

Oleg Chudaev Valentina Chudaeva Kenji Sugimori Akihito Kuno Motoyuki Matsuo 《中国地球化学学报》2006,25(B08):211-211

On the Kuril Islands there are 85 volcanoes, 39 of which are active. Hot springs and mud pots are wide spread in this area and have significant inputs on the chemical composition of the surrounding surface waters and environment. We present results of trace elements as well as data on H, O, S, and He isotope ratios for hydrothermal systems of the Mendeleev Volcano （Kunashir Island） and surrounding surface waters. Water and gas samples were taken from springs and holes as well as creeks and the Lesnaya River. Among the thermal water types, three main groups can be distinguished. The first group includes the waters, in which SO4^- ion predominant. The water temperature on the surface reaches 97℃, and TDS varies from a few g/L to 7 g/L. These waters are acid to superacid with pH values ranging 0.6 to 2.3. The second group is sodium-chloride waters. A maximum TDS is 14.2 g/L. The waters are neutral or alkaline; pH varies from 6.9 to 8.2. The third group is the sodium-chloride-sulfate-bicarbonate water. The Stolbovskie springs, located in the periphery of the Mendeleev Volcano are representative of this type. The pH of these waters is close to neutral. TDS is 1.9 g/L. They are rather the derivatives of sodium-chloride waters arisen from dilution of them by subsurface waters. The Kuslyi Creek and Lesnaya River are located near the Mendeleev Volcano. The most acid springs discharge into the Kislyi Creek as a result pH of this creek being 2.5, and contents of most elements rather high. For example, the contents of dissolved solids of Si, Fe, Al, Mn, Zn, in waters of the Kislaya Creek are 22.1, 8.1, 6.2, 1.29, and 0.28 mg/L, and correspondently. The water of the Lesnaya River, （Before the Kislyi Creek, pH is about 8 with TDS 102 mg/L, but after the Kuslyi Creek, pH decreases and the concentrations of chemical elements increase. Debit of the Kislayi Creek in summer season is about 370 L/sec. It means that every day only this small creek inputs in the Lesnay River about 706 kg of Si;  相似文献   

Comparative Seismic Risk Studies for German Earthquake Regions on the Basis of the European Macroseismic Scale EMS-98     

Jochen Schwarz  Mathias Raschke  Holger Maiwald 《Natural Hazards》2006,38(1-2):259-282

Within the framework of recent research projects, basic tools for GIS-based seismic risk assessment technologies were developed and applied to the building stock and regional particularities of German earthquake regions. Two study areas are investigated, being comparable by the level of seismic hazard and the hazard-consistent scenario events (related to mean return periods of 475, 2475 and 10000 years). Significant differences exist with respect to the number of inhabitants, the grade and extent of urbanisation, the quality and quantity of building inventory: the case study of Schmölln in Eastern Thuringia seems to be representative for the majority of smaller towns in Germany, the case study of Cologne (Köln) stands for larger cities. Due to the similarities of hazard and scenario intensities, the considerable differences do not only require proper decisions concerning the appropriate methods and acceptable efforts, they enable conclusions about future research strategies and needs for disaster reduction management. Not least important, results can sharpen the focus of public interest. Seismic risk maps are prepared for different scenario intensities recognising the scatter and uncertainties of site-dependent ground motion and also of the applied vulnerability functions. The paper illustrates the impact of model assumptions and the step-wise refinements of input variables like site conditions, building stock or vulnerability functions on the distribution of expected building damage within the study areas. Furthermore, and in contrast to common research strategies, results support the conclusion that in the case of stronger earthquakes the damage will be of higher concentration within smaller cities like Schmölln due to the site-amplification potential and/or the increased vulnerability of the building stock. The extent of damage will be pronounced by the large number of masonry buildings for which lower vulnerability classes have to be assigned. Due to the effect of deep sedimentary layers and the composition of building types, the urban centre of Cologne will be less affected by an earthquake of comparable intensity.  相似文献   

Managing sustainable farmed landscape through 'alternative' food networks: a case study from Italy   总被引：1，自引：0，他引：1  

LEWIS HOLLOWAY  ROSIE COX†  LAURA VENN‡  MOYA KNEAFSEY‡  ELIZABETH DOWLER§  HELENA TUOMAINEN§ 《The Geographical journal》2006,172(3):219-229

This paper focuses on a case study of an 'alternative' food network based in the Abruzzo National Park, Italy, to explore how ideas of sustainable farmland management can be expressed through broader understandings of developing networks of care concerned with local economies and societies, high-quality specialist food products, particular 'traditional' farming practices and livestock breeds, as well as the ecology of a farmed landscape. The scheme allows customers, internationally as well as in Italy, to 'adopt' a milking sheep on a large mountain farm. In return, adopters are sent food products from the farm. The adoption scheme is inter-twined with an agri-tourism project which provides accommodation, runs a restaurant and engages in educational activities. The scheme is the result of the individual initiative of its founder, and is associated with a strongly expressed ethical position concerning the value of sustaining valued local rural landscapes and lifestyles, and the importance of 'reconnecting' urban dwellers with rural areas, farming and 'quality' food production. Yet the localness of the scheme is sustained through wider national and international networks: volunteer and paid workers are drawn from several European countries, funding has been acquired from the EU LEADER programme, and internet and transport technologies are essential in connecting with and supplying an international customer base. The broader economy of care instanced in this case study draws attention to a need to develop strategies for sustainable farmland management constructed around wider programmes of social, economic and cultural, as well as environmental, concern.  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Hydrogeochemistry of the Simav geothermal field, western Anatolia, Turkey     

Ünsal Gemici  Gültekin Tarcan 《Journal of Volcanology and Geothermal Research》2002,116(3-4)

Thermal waters hosted by Menderes metamorphic rocks emerge along fault lineaments in the Simav geothermal area. Thermal springs and drilled wells are located in the Eynal, Çitgöl and Na a locations, which are part of the Simav geothermal field. Studies were carried out to obtain the main chemical and physical characteristics of thermal waters. These waters are used for heating of residences and greenhouses and for balneological purposes. Bottom temperatures of the drilled wells reach 163°C with total dissolved solids around 2225 mg/kg. Surface temperatures of thermal springs vary between 51°C and 90°C. All the thermal waters belong to Na–HCO₃–SO₄ facies. The cold groundwaters are Ca–Mg–HCO₃ type. Dissolution of host rock and ion-exchange reactions in the reservoir of the geothermal system shift the Ca–Mg–HCO₃ type cold groundwaters to the Na–HCO₃–SO₄ type thermal waters. Thermal waters are oversaturated at discharge temperatures for aragonite, calcite, quartz, chalcedony, magnesite and dolomite minerals giving rise to a carbonate-rich scale. Gypsum and anhydrite minerals are undersaturated with all of the thermal waters. Boiling during ascent of the thermal fluids produces steam and liquid waters resulting in an increase of the concentrations of the constituents in discharge waters. Steam fraction, y, of the thermal waters of which temperatures are above 100°C is between 0.075 and 0.119. Reservoir pH is much lower than pH measured in the liquid phase separated at atmospheric conditions, since the latter experienced heavy loss of acid gases, mainly CO₂. Assessment of the various empirical chemical geothermometers and geochemical modelling suggest that reservoir temperatures vary between 175°C and 200°C.  相似文献   

城市用地与人口的异速增长和相关经验研究   总被引：16，自引：5，他引：16  

梁进社  王旻 《地理科学》2002,22(6):649-654

由于城市土地利用变化涉及的因素多，使获取动态研究研究所需的资料十分困难，所以，用少数几个主要因素定量地表达其变化就显得十分重要。从前人的成果，即以人口表示的城市位序-规模法则和建成区面积表示的位序-规模法则出发，绽绎出城市的用地规模和人口数量呈异速增长。这意味着，如果把整个城市看成是一个生命有机体，那么作为反映城市特征的城市用地规模和城市人口这两个重要变量，就是城市这个有机体的两个器官，他们的增长率是成比例的。还通过这个关系建立了城市建成区面积与市场人口和经济发展水平的数学模式。对我国部分城市的经验研究在一定程度上分别证明了这两经验关系。  相似文献