太平洋多金属结核及沉积物标准物质研制   总被引：8，自引：0，他引：8  

王毅民  李家熙  高玉淑  宋浩威  罗代洪  王晓红  陈维岳  滕云业  周世光 《地球学报》1998,19(3):298-307

太平洋多金属结核及深海沉积物标准物质,ＧＳＰＮ－２,３和ＧＳＭＳ－２,３,４个样品已研制完成。ＧＳＰＮ－２,３和ＧＳＭＳ－２采自太平洋ＣＣ区,ＧＳＭＳ－３采自中太平洋海盆（ＣＰ区）。原样被加工成－２００目（７４μｍ）的均匀粉未,其均匀性采用高精度的Ｘ射线荧光光谱法检测。样品的特性值采用国内外多实验室协同分析的方式定值,有包括台湾大学在内的１４个国内实验室和１８个国外实验室参加了合作分析。测试组分分别达７９和８１个,定值组分６３个。全组分的百分总和分别为：９９．７％,９９．５％,９９．８％和９９．７％。这４个标准物质已于１９９７年被国家技术监督局批准为国家一级标准物质,序号分别为ＧＢＷ０７２９５,ＧＢＷ０７２９６,ＧＢＷ０７３１５和ＧＢＷ０７３１。  相似文献   

Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)   总被引：2，自引：0，他引：2  

Mingcai Yan  Chunshu Wang  Tiexin Gu  Qinghua Chi  Zhong Zhang 《Geostandards and Geoanalytical Research》1998,22(2):235-246

Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.  相似文献   

环境水土对重要建筑材料的腐蚀作用     

梅祖明 《上海国土资源》1998,(4):53-57

从建筑材料和水土中活跃成分的化学性质出发,讨论环境水土成分对重要建筑材料的腐蚀的机理及其评价的有关问题。  相似文献   

Using archaeological data and sediment parameters to review the formation of the Gravettian layers at Krems-Wachtberg     

Marc Händel  Roswitha Thomas  Tobias Sprafke  Philipp Schulte  Michael Brandl  Ulrich Simon  Thomas Einwögerer 《第四纪科学杂志》2021,36(8):1397-1413

  相似文献   

Isotopic tracing of ore-forming source materials for Dexing porphyry copper deposit of Jiangxi, China     

References： 《东北亚地学研究》2008,11(1):25-31

Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C, Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ^13 CpDB values of siderite were close to the δ^13 CpDB value of original magma; δ^30Si values of the samples at the ore-forming stage were close to the δ^30 Si value range of magma, δ^30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials.  相似文献   

Prediction of uniaxial compression PFC3D model micro‐properties using artificial neural networks     

A. S. Tawadrous  D. DeGagné  M. Pierce  D. Mas Ivars 《国际地质力学数值与分析法杂志》2009,33(18):1953-1962

Artificial neural networks are used to predict the micro‐properties of particle flow code in three dimensions (PFC3D) models needed to reproduce macro‐properties of cylindrical rock samples in uniaxial compression tests. Data for the training and verification of the networks were obtained by running a large number of PFC3D models and observing the resulting macro‐properties. Four artificial networks based on two different architectures were used. The networks used different numbers of input parameters to predict the micro‐properties. Multi‐layer perceptron networks using Young's modulus, Poisson's ratio, uniaxial compressive strength, model particle resolution and the maximum‐to‐minimum particle ratio showed excellent performance in both training and verification. Adding one more variable—namely, minimum particle radius—showed degrading performance. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Grain size composition and transport of sedimentary organic carbon in the Changjiang River (Yangtze River) Estuary and Hangzhou Bay and their adjacent waters     

ZHANG Weiyan  JIN Haiyan  YAO Xuying  JI Zhongqiang  ZHANG Xiaoyu  YU Xiaoguo  ZHANG Fuyuan  GAO Aigen 《海洋学报(英文版)》2015,34(10):46-56

Surface sediments from the Changjiang River(Yangtze River) Estuary,Hangzhou Bay,and their adjacent waters were analyzed for their grain size distribution,organic carbon(OC) concentration,and stable carbon isotope composition(δ13C).Based on this analysis,about 36 surface sediment samples were selected from various environments and separated into sand(0.250 mm,0.125–0.250 mm,0.063–0.125 mm) and silt(0.025–0.063 mm)fractions by wet-sieving fractionation methods,and further into silt-(0.004–0.025 mm) and clay-sized(0.004mm) fractions by centrifugal fractionation.Sediments of six grain size categories were analyzed for their OC andδ13C contents to explore the grain size composition and transport paths of sedimentary OC in the study area.From fine to coarse fractions,the OC content was 1.18%,0.51%,0.46%,0.42%,0.99%,and 0.48%,respectively,while theδ13C was –21.64‰,–22.03‰,–22.52‰,–22.46‰,–22.36‰,and –22.28‰,respectively.In each size category,the OC contribution was 42.96%,26.06%,9.82%,5.75%,7.09%,and 8.33%,respectively.The OC content in clay and fine silt fractions(0.025 mm) was about 69.02%.High OC concentrations were mainly found in offshore modern sediments in the northeast of the Changjiang River Estuary,in modern sediments in the lower estuary of the Changjiang River and Hangzhou Bay,and in Cyclonic Eddy modern sediments to the southwest of the Cheju Island.Integrating the distribution of terrestrial OC content of each grain size category with the δ13C of the bulk sediment indicated that the terrestrial organic material in the Changjiang River Estuary was transported seaward and dispersed to the Cyclonic Eddy modern sediments to the southwest of the Cheju Island via two pathways:one was a result of the Changjiang River Diluted Water(CDW) northeastward extending branch driven by the North Jiangsu Coastal Current and the Yellow Sea Coastal Current,while the other one was the result of the CDW southward extending branch driven by the Taiwan Warm Current.  相似文献   

Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method     

LI Jin  TANG Suohan  ZHU Xiangkun  MA Jianxiong  ZHAO Xinmiao 《《地质学报》英文版》2022,96(2):517-524

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.  相似文献   

Plastic debris as nesting material in a Kittiwake-(Rissa tridactyla)-colony at the Jammerbugt, Northwest Denmark     

Hartwig E  Clemens T  Heckroth M 《Marine pollution bulletin》2007,54(5):595-597

This paper continues the investigations of Clemens and Hartwig from 1992 on the proportion of garbage used as nesting material in the Kittiwake colony at Bulbjerg in the Jammerbugt in Northwest Denmark. Whereas in the year 1992 plastic garbage items were included in 39.3% of 466 Kittiwake nests in the Bulbjerg colony, in 2005 57.2% of 311 nests contained plastic debris. Although it has been forbidden to dispose of plastic garbage into the marine environment since the implementation of the MARPOL 73/78-Agreement/Annex V (Regulation for the Prevention of Pollution by Ship Waste) of 1989 and especially since the declaration of the North Sea as a MARPOL-Special Area for garbage in 1991, the pollution of the oceans and the North Sea is still an ubiquitous problem, particularly with regard to plastic waste. Plastic waste is presumably not used preferentially for nest-building, but in the context of available nesting material in the waters surrounding the breeding colony. Therefore the share of garbage parts in nests of certain species of birds is an indicator of the amount of waste in the natural environment in the vicinity of their breeding site.  相似文献   

中国地源热泵技术应用及进展   总被引：1，自引：0，他引：1       下载免费PDF全文

孙友宏  仲崇梅  王庆华 《探矿工程》2010,37(10):30-34

地源热泵技术在中国应用时间不长,但推广应用速度非常快,几乎以每年20%以上的速度增长,尤其在上海世博场馆中大面积推广,取得了很好的节能效果。随着该技术的推广应用和深入研究,我国已掌握了地源热泵的全套技术,并在浅层地热能勘查评价规范、钻孔热反应测试技术、高效地下热交换井以及太阳能与地源热泵技术的联合应用等方面都取得了一些新进展,这些成果的取得将为实现我国2050年的节能减排目标提供技术保障。  相似文献