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101.
Disequilibrium for Ca during growth of pelitic garnet 总被引:14,自引:1,他引:14
Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error. 相似文献
102.
103.
悬浮液进样—石墨炉原子吸收测定钒钛磁铁矿中痕量镓 总被引:5,自引:0,他引:5
研究了悬浮液进样_石墨炉原子吸收测定钒钛磁铁矿中痕量镓的分析方法。以Ni(Ⅱ)作为基体改进剂时,可直接用镓标准溶液进行校准。样品粒度<38μm、悬浮液中试样质量浓度在01~80g/L、含镓质量浓度不超过100μg/L时呈良好线性关系,检出限为24μg/L镓。用所拟方法测定了含镓量在16~42μg/g的标准矿样,结果与标准值相符,6次平行测定的相对标准偏差不超过9%,满足痕量分析的要求。 相似文献
104.
榴辉岩中铁铝榴石的测定方法研究 总被引:3,自引:1,他引:3
对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Fe均以Fe^2+为主,其质量分数在83-94,并将Fe^2+这特征性成分用于某地榴辉岩中铁铝榴石的间接测定,获得结果与焙烧磁化-磁选法一致且精度好,较磁化法简便,快速。 相似文献
105.
遥感技术获取的可见光、红外及微波信息,可以对化工企业及化学矿山环境污染(水、粉尘、大气、废渣污染等)及环境地质灾害(滑坡、泥石流、地面塌陷等)进行实时动态监测,并可获得较高的社会经济效益,达到地面环保及常规环境地质工作难以达到的效果。特别是对重点大中型化工企业及化学矿山建立环境遥感信息动态监测系统,可以为国家决策部门及时准确地提供环境治理和改造的依据。 相似文献
106.
论湖南柿竹园多金属矿床成岩成矿的化学模式─—与毛景文先生等商榷 总被引:2,自引:0,他引:2
从湖南柿竹园多金属矿床成岩成矿的事实出发,用化学基本定律对其矽卡岩的形成,蚀变及成岩成矿的化学反应方程式进行研讨,建立了比较符合矿床实际与地球化学理论的化学模式。认为地球科学与化学是在相互交叉,相互渗透,相互促进中共同发展的。 相似文献
107.
108.
Georg Kaufmann 《Geophysical Journal International》1997,131(2):281-292
In this paper the effect of a delayed onset of glaciation in the Barents Sea on glacial isostatic adjustment is investigated. The model calculations solve the sea-level equation governing the total mass redistributions associated with the last glaciation cycle on a spherically symmetric, linear, Maxwell viscoelastic earth for two different scenarios for the growth phase of the Barents Sea ice sheet. In the first ice model a linear growing history is used for the Barents Sea ice sheet, which closely relates its development to the build-up of other major Late Pleistocene ice sheets. In the second ice model the accumulation of the Barents Sea ice sheet is restricted to the last 6 ka prior to the last glacial maximum.
The calculations predict relative sea levels, present-day radial velocities, and gravity anomalies for the area formerly covered by the Weichselian ice sheet. The results show that observed relative sea levels in the Barents Sea are appropriate for distinguishing between the different glaciation histories. In particular, present-day observables such as the free-air gravity anomaly over the Barents Sea, and the present-day radial velocities are sensitive to changes in the glaciation history on this scale.
A palaeobathymetry derived from relative sea-level predictions before the last glacial maximum based on the second ice model essentially agrees with a palaeobathymetry derived by Lambeck (1995). The additional emerged areas provide centres for the build-up of an ice sheet and thus support the theory of Hald, Danielsen & Lorentzen (1990) and Mangerud et al. (1992) that the Barents Sea was an essentially marine environment shortly before the last glacial maximum. 相似文献
The calculations predict relative sea levels, present-day radial velocities, and gravity anomalies for the area formerly covered by the Weichselian ice sheet. The results show that observed relative sea levels in the Barents Sea are appropriate for distinguishing between the different glaciation histories. In particular, present-day observables such as the free-air gravity anomaly over the Barents Sea, and the present-day radial velocities are sensitive to changes in the glaciation history on this scale.
A palaeobathymetry derived from relative sea-level predictions before the last glacial maximum based on the second ice model essentially agrees with a palaeobathymetry derived by Lambeck (1995). The additional emerged areas provide centres for the build-up of an ice sheet and thus support the theory of Hald, Danielsen & Lorentzen (1990) and Mangerud et al. (1992) that the Barents Sea was an essentially marine environment shortly before the last glacial maximum. 相似文献
109.
Periodicity of magnetic intensities in magnetic anomaly profiles: the Cenozoic of the South Atlantic
Spectral analyses of several published magnetic anomaly profiles from Candé & Kent (1992a) were undertaken prior to analysing, in the same way, raw magnetic anomaly data from similar parts of the South Atlantic. It was found that similar and distinct medium and short wavelengths were present in both the published and raw data. When these are converted into the time domain using the average rate of spreading for each profile, these periodicities appear similar, possibly identical, to those expected from the long-term eccentricity orbital parameters (Fischer, DeBoer & Premoli Silva 1990). While such correlations are not necessarily causative, they suggest that magnetohydro-dynamical processes near the core-mantle boundary may be affected by gravitational changes due to planetary orbital perturbations. 相似文献
110.