Chemical composition of upper crust in eastern China   总被引：4，自引：0，他引：4  

Mingcai Yan  Qinghua Chi  Tiexin Gu  Chunshu Wang 《中国科学D辑(英文版)》1997,40(5):530-539

In an area of 3.3×10⁶ km² within eastern China, 28 253 rock samples were collected systematically and combined into 2718 composite samples which were analyzed by 15 reliable methods using national preliminary certified reference materials (CRMs) for data quality monitoring. The average chemical compositions of the exposed crust, the sedimentary cover and the exposed basement as well as the upper crust for 76 chemical elements in eastern China are given. A key basic geology projcct supported by Ministry of Geology and Mineral Resources of China.  相似文献   

地质样品中微量金银的在线分离富集方法     

齐菊锐  苏克  邹海峰  鲍长利  姜桂兰  齐清凤 《吉林大学学报(地球科学版)》1997,(4)

提出用ＶＳ－Ⅱ型强碱性阴离子交换纤维定量富集、硫脲解脱，流动注射在线分离富集—火焰原子吸收光谱法测定地质样品中痕量金银的分析方法。该方法检出限低，金为１．４μｇ／ｍＬ，银为０．３５μｇ／ｍＬ，相对标准偏差均小于２％，采样频率为１２０次／ｈ，用于地质样品中痕量金银的直接测定，结果令人满意。  相似文献   

原油族组分成气的化学动力学模型及其标定   总被引：27，自引：2，他引：27       下载免费PDF全文

卢双舫  付晓泰 《地质学报》1997,71(4):367-373

利用等温密封热解实验技术及恒速升温热解实验与PY—GC分析技术的结合,本文分别建立并标定了原油中各族组分,即饱和烃、芳烃、非烃和沥青质成气的化学动力学模型。结果表明,原油中不同族组分成气的过程均可用平行一级反应描述,但不同组分在平均活化能及活化能分布上有明显的差异。各族组分在地史过程中成气的过程可由各自的化学动力学模型来描述。这将使原油成气过程的定量、动态描述成为可能。  相似文献   

EXPERIMENTAL STUDY ON EFFECTS OF HUMIDITY AND CHEMICAL COMPOSITION UPON IMAGINARY PART OF REFRACTIVE INDEX OF AEROSOL PARTICLES^*          下载免费PDF全文

LI Zihu  DONG Zhen  YANG Jun  HUANG Shihong 《Acta Meteorologica Sinica》2004,18(4):517-526

Experimental study is made of the relationship between the imaginary part of refractive index (IRI) of atmospheric aerosol particles and relative humidity,and between IRI and chemical element through the assay of chemical constituents of the particles.Evidence suggests that atmospheric humidity and aerosols' chemical ingredients have great effects on the IRI's and they should thus be considered in the research of the radiation properties of the particles in the atmosphere.  相似文献   

GRADIENT DISTRIBUTION OF ACID RAIN IN THE SCENIC RESORT OF THE BAIYUN MOUNTAIN IN GUANGZHOU     

黄健  李福娇  江奕光  李琼 《热带气象学报(英文版)》2004,10(1):95-105

1 INTRODUCTION Sitting in the central part of the Pearl River Delta, Guangzhou is one of the cities in China that are most polluted by acid rain. Broad attention has been brought to the problem. Since the early 1980s, a series of observation and studies h…  相似文献   

An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems     

Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.  相似文献   

Influence of water level fluctuation on the spatial dynamic of the water chemistry at Lake Fertõ/Neusiedler See     

Mria Dinka  Edit goston-Szab  rpd Berczik  Gyula Kutrucz 《Limnologica》2004,34(1-2):48

Lake Fertõ/Neusiedler See is a steppe lake situated on the Hungarian-Austrian border with a surface area of 309 km². It is an extremely shallow lake with regulated outflow. 54% of the whole lake and 85% of the Hungarian part (75 km²) is covered by reed. There are numerous reedless areas (inner ponds) of variable size within the reed belt, which is enmeshed with canals connecting the inner ponds with the open water areas. Fundamental differences were recorded in the water chemistry of the three water type areas, open water, canals and inner ponds. The degree of these differences is basically determined by the distance from the open water areas and the water level of the actual years. An extremely high, an average and an extremely low water level year was examined, in order to present the spatial and temporal differences in the water chemistry of the investigated water bodies. Differences due to the water level fluctuation between years in the three different water types are discussed on the basis of electrical conductivity, cation, and anion concentration changes of the water. Our results support the concept of high instability of Lake Fertõ and describe habitats with remarkable temporal and spatial variability. The high influence of water level on habitat conditions at different sites of the lake recommend a carefull water level regulation strategy.  相似文献   

Evidence for freeze–thaw events and their implications for rock weathering in northern Canada     

Kevin Hall 《地球表面变化过程与地形》2004,29(1):43-57

Discussions regarding weathering in cold environments generally centre on mechanical processes and on the freeze–thaw mechanism in particular. Despite the almost ubiquitous assumption of freeze–thaw weathering, unequivocal proof of interstitial rock water actually freezing and thawing is singularly lacking. Equally, many studies have used the crossing of 0 °C, or values close to that, as the basis for determining the number of ‘freeze–thaw events’. In order to assess the weathering regime at a site in northern Canada, temperatures were collected at the surface, 1 cm and 3 cm depth for sets of paving bricks, with exposures both vertical and at 45°, orientated to the four cardinal directions. Temperature data were collected at 1 min intervals for 1 year. These data provide unequivocal proof for the occurrence of the freezing and thawing of water on and within the rock (freeze–thaw events). The freeze event is evidenced by the exotherm associated with the release of latent heat as the water actually freezes. This is thought to be the ?rst record of such events from a ?eld situation. More signi?cantly, it was found that the temperature at which freezing occurred varied signi?cantly through the year and that on occasion the 1 cm depth froze prior to the rock surface. The change in freeze temperature is thought to be due to the chemical weathering of the material (coupled with on‐going salt inputs via the melting of snowfall), which, it is shown, could occur throughout the winter despite air temperatures down to ?30 °C. This ?nding regarding chemical weathering is also considered to be highly signi?cant. A number of thermal stress events were also recorded, suggesting that rock weathering in cold regions is a synergistic combination of various chemical and mechanical weathering mechanisms. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

化学腐蚀下砂岩三轴细观损伤机理及损伤变量分析   总被引：10，自引：4，他引：10  

陈四利  冯夏庭  周辉 《岩土力学》2004,25(9):1363-1367

利用CT识别技术对化学腐蚀下的砂岩进行了三轴加载全过程的即时扫描试验，得到了在不同级荷载作用下砂岩的压密、微裂纹萌生、扩展和破裂的CT图像和CT数，分析了砂岩损伤演化的细观机理。同时，建立了一个基于化学腐蚀影响和CT数的损伤变量模型。  相似文献   

岩层移动动态过程的离散单元法分析   总被引：2，自引：0，他引：2  

张建全  于友江 《水文地质工程地质》2004,31(2):9-13

采动覆岩动态发展过程受地质、采矿条件诸多因素的影响,是一个十分复杂的时空过程。通过离散单元法数值模拟,揭示了综放开采条件下采场上覆岩层动态发展规律,特别是覆岩离层缝隙的分布规律、发展形态、空间位置以及与地质采矿条件的关系,揭示了工作面推进过程中,采场上覆岩层中重新分布的应力大小、方向及其发展变化规律,该应力的存在和变化规律是确定井下开采方法、支护方式的依据。  相似文献