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61.
金在表生条件下溶解,迁移和沉淀的探讨 总被引:2,自引:0,他引:2
金矿物在表生条件下溶解为离子金.离子金与表生络合剂结合成金络离子团迁移.在物化条件改变时,由于有机炭、粘土矿物及带异性电荷胶体吸附,使金络离子团分解成原子金沉淀. 相似文献
62.
离子色谱—双电导法同时测定水样中多种阴离子的研究 总被引:2,自引:0,他引:2
本文在Dionex2020i离子色谱仪上,选用0.61×10~(-3)mol/L NaHCO_3-1.61×10~(-3)mol/LNa_2CO_3水溶液作淋洗液,在HPIC-AS4A阴离子分离柱上分离痕量F~-、NO_2~-、Br~-和较高浓度的Cl~-、NO_3~-、SO_4~(2-);选用2.0×10~(-3)mol/L TBAOH-6%CH_3CN水溶液作淋洗液,在MPIC-NS1分离柱上分离痕量F~-、Br~-和较高浓度的Cl~-,然后用串联双电导检测器的不同输出范围分别同时定量测定。本法特别适用于相邻两种离子浓度相差较大,前面高含量的离子对后面痕量离子测定有干扰的样品。用本文拟定的HPIC方法测定除铬后的地下水样中多种阴离子的结果与文献值吻合。 相似文献
63.
人工合成硅灰石的发光性质与发光机理的初步研究 总被引:2,自引:0,他引:2
在254nm紫外光照激发条件下,对人工合成掺入不同激活离子的低温TC型和高温型假硅灰石的发光性质进行了实验测定,从微观原子能量谱项讨论了在全的硅灰石基质中Eu^3+和Gd^3+的发光机理,分析了Bi^3+对Eu^3+与Pb^2+对Mn^2+的敏化发光条件,初步探讨了掺放Eu^3+的高温型假硅灰石发光强度减弱的原因。 相似文献
64.
65.
线性规划在徐州地下水资源开发中的应用 总被引:1,自引:0,他引:1
本文从地下水系统的观点出发,对徐州地区中寒武统—中奥陶统碳酸盐岩地下水系统进行了分析。并应用线性规划的原理和方法对徐州市西郊四个水源地地下水进行了水文地质计算。在规定水位允许降深的约束条件下,求得至2000年,该区地下水最大开采量为14万米~3/天及各水源地相应取水量的最佳分配。文中采用特定条件图解法计算多边界、多主井抽水干扰影响的方法,具有通用意义。 相似文献
66.
Jean Servant Robert Delmas Jacques Rancher Marcel Rodriguez 《Journal of Atmospheric Chemistry》1984,1(4):391-401
A partial balance of mineral N is given for the basins of two coastal rivers in a forest zone in the Ivory Coast. The dry and wet depositions on the basin surfaces is given for particulate matter (NO3
–, NH4
+). The quantity of mineral N washed away in the rivers is evaluated. The losses from leaching of the soils by rainwater are about 0.33 to 1.0% of the atmospheric depositions for NH4
+–N and 2.2 to 5.8% for NO3
––N. The yearly atmospheric input of N compounds to the ecosystem, about 1.4 g N m–2 y–1, is at least 14% of mineral N formed in the soils and is therefore quite significant. 相似文献
67.
利用国产的光刻胶和国产离子刻蚀机在蒸镀的铝基衬底上进行刻蚀全息光栅,在国内是一项较新的技术。本文介绍和论述了该试验工作的工艺过程、参数计算和测试方法,得出了试验结果和参数计算值基本吻合的结论,并指出了进一步改善质量的方向。 相似文献
68.
Products and mechanisms for the gas-phase reactions of NO3 radicals with CH2=CHCl, CH2=CCl2, CHCl=CCl2,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO3 was generated by the thermal dissociation of N2O5. Experiments with15NO3 and CD2CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO2. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH2=CCl2 and CHCl=CCl2 are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO3 addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10–16 cm3 molecule–1 s–1 for CH2=CHCl, CH2=CCl2, CHCl=CCl2 andcis-CHCl=CHCl, respectively. 相似文献
69.
Balloon-borne observations of electrical conductivity in the troposphere and stratosphere were performed using conductivity sondes at Garmisch-Partenkirchen, West Germany, from June to November, 1980, after the Mt St Helens eruption. A significant decrease of atmospheric ions in the altitudes from the troposphere to lower stratosphere has been detected until several months after the eruption in comparison with the observational results obtained before the eruption. Simulteneous ruby lidar observation a month after the eruption indicates an increased amount of aerosol at nearly the same altitude as that of conductivity decrease. Several months after the eruption it appears that aerosols detected by lidar and those effective in reducing ion concentration have different profiles. 相似文献
70.
We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for
the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The
study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in
porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within
pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to
the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g.,
typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials.
In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters
in the range 1.4–70 μm does not affect the deliquescence humidity of the salt. 相似文献