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161.
Water samples taken at 19 locations in the Mawheraiti River catchment at weekly intervals during 1979–80 were analysed for sodium, magnesium, potassium, calcium, phosphate, nitrate, and ammonium ion concentrations and for electrical conductivity. Seasonal discharge effects were apparent, and lithology and land management practice also influenced solute concentrations. Solute concentrations were generally very low; nitrate and soluble phosphate were rarely greater than 0.05 mg.L‐1 and ammonium was rarely greater than 0.01 mg.L‐1. The 4 major cations (Na, Mg, K, and Ca) usually summed to less than 6 mg.L‐1 much of which was supplied by precipitation. Forest management (clearfelling and slash‐burning) caused significant increases in solute concentrations, but concentrations declined rapidly during succeeding months and approached pretreatment levels after 2–3 years. The higher concentrations associated with forest management in small experimental catchments were rapidly diluted downstream; together with the low natural solute concentrations this suggests that harmful downstream effects of management practices are unlikely under low flow conditions. 相似文献
162.
163.
A. M. Díaz J. P. Díaz F. J. Expósito P. A. Hernández-Leal D. Savoie X. Querol 《Journal of Atmospheric Chemistry》2006,53(1):63-90
The dynamics and the aerosol chemistry of the air masses reaching the free troposphere of the subtropical Northeast Atlantic region during the period 1995–98 have been studied. Seven days backward trajectories were calculated daily with HYSPLIT-4 model for Izaña Global Atmospheric Watch (GAW) Observatory (28.3°N 16.5°W, 2367 m a.s.l.). These back-trajectories were classified by means of a k-means clustering strategy. The daily air masses have been coded using 16 variables to detect the aerosol load of each one of them. Four clusters were found: Cluster 1, representative of Atlantic oceanic middle troposphere air masses, (OMT), has an average frequency of occurrence of 50.6%. Cluster 2, which includes air masses originated in the African continent (AfD), has been recorded in a 19.8% of time. Cluster 3 represents a mixture at least of two of the next sources: Europe, Africa and Ocean, (EAM), with a frequency of 12.7%. Finally, Cluster 4 includes air masses with a high load of maritime aerosols, (MaA), and it has been detected in a 16.9%. An analysis of four aerosol components: NO3 ?, NH4 +, non-sea-salt-SO4 2?, and mineral dust and its relation with the origin and transport of the air masses have been done. The highest quantities of mineral dust and nss-SO4 2? are linked with African air masses with a mean value of 86.5 and 1.9 μg/m3 respectively. Whereas the highest levels of NO3 ?, 1.0 μg/m3, and NH4 +, 0.4 μg/m3, were obtained for AfD and EAM. The lowest levels were associated with OMT and MaA air masses types: 12.7, 0.6, 0.2, and 0.5 μg/m3 for dust, NO3 ?, NH4 +, and nss-SO4 2? in average for the four studied years. However, it is remarkable that the values of the median for dust are 2.2 and 3.5 μg/m3 in clusters MaA and OMT respectively. Using non-parametric statistical tests the distributions of concentrations in each cluster by year have been compared in order to detect similarities. The results show that the aerosol loads of OMT and MaA air masses are quite similar and the same occurs for AfD and EAM air masses. However, the correlation analysis between the levels of anions and ammonium evidenced important differences among the air mass types. In AfD air masses is clear a low correlation between levels of nss-SO4 2? and NH4 + (r 2 = 0.08) suggesting that the sulfate speciation was dominated by sulfate species others than ammonium sulfate, such as calcium sulfate. CaSO4 ?2H2O (gypsum) is mainly present in the coarse mode, where the radiative effects of sulfate are less important that in the accumulative mode. For OMT air masses is noticeable an important increasing on the correlation between the levels of anions and those of NH4 + for the two last years of the study period (1997–1998, r 2 = 0.61 –0.85%) with respect to the first ones (1995–1996, r 2 = 0.25–0.49%), coinciding with the second strongest ENSO (El Niño Southern Oscillation) event recorded. This behavior indicates a change in the speciation of the aerosol component. 相似文献
164.
Sources and transport of nitrate constrained by the isotopic technique in a karst catchment: an example from Southwest China 总被引:4,自引:0,他引:4 下载免费PDF全文
The concentration and isotopic composition of nitrate were analyzed to improve an understanding of nitrate sources and transformation processes in a typical karstic agricultural field in the Houzhai catchment, Guizhou Province, Southwest China. The results revealed that no distinct spatial pattern of content and isotopic composition of nitrate exists in this karst catchment. Nitrate in surface stream (SFS) had slightly lighter isotopic composition and lower concentration compared with nitrate in subterranean stream (STS) during the dry season. Concentrations of SFS nitrate increased to concentrations similar to those of STS during the wet season. The isotopic values indicated that nitrate were mainly impacted by manure sources during the dry season and influenced by a mix of chemical fertilizer and manure during the wet season. The denitrification rates were roughly estimated based on the isotopic compositions of nitrate after considering volatilization and ignoring assimilation. The calculated result showed that approximately one fifth of nitrate load was removed by denitrification in the catchment. Annual nitrate flux from the outlets accounted for 14.2% of applied total fertilizers used in the catchment, approximately 85% of total transported flux from the catchment in the wet season. Furthermore, chemical weathering processes were enhanced by using nitrogen fertilizer because liberated protons and enhanced HCO3? flux were produced through by nitrification. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
165.
A method has been developed for determination of15N isotope ratio in nitrate nitrogen, which is a major analytical step in tracer experiments for studies of nitrate metabolism
in the marine environment. The method is based on diazotization of nitrite with sulfanilic acid following reduction of nitrate
to nitrite by a cadmium-copper column. The diazonium compound is then subject to the azo coupling reaction with 2-naphthol,
and the azo dye formed is extracted by a solid phase extraction column. The dye eluted from the column is collected, and total
nitrogen and15N content of the dye are determined by mass spectrometry. Sulfanilic acid can also remove preexisting nitrite by heating the
sample under acidic conditions before passing through the cadmium-copper reduction column. The average recovery of nitrate
nitrogen was 86%. A procedure for reducing the background nitrogen that derives from the analytical operations has been developed;
background nitrogen was limited to about 0.25 μg-atomN. The variation in the background nitrogen levels reflects the range of error in15N determination of nitrate nitrogen by this method. Application of the present method to a15NO3
− isotope dilution experiment for determination of nitrification rate in sea water is demonstrated. 相似文献
166.
S. A. Penkett K. C. Clemitshaw N. H. Savage R. A. Burgess L. M. Cardenas L. J. Carpenter G. G. McFadyen J. N. Cape 《Journal of Atmospheric Chemistry》1999,33(2):111-128
Detailed studies have been made of the behaviour of gases and radicals involved in the production of oxidants at the Weybourne Atmospheric Observatory in both summertime and wintertime conditions. In June 1995 the range of meteorological conditions experienced varied such that ozone destruction was observed in clean northerly air flows reaching Weybourne down the North Sea from the Arctic, and ozone production was observed in varying degrees in air with different loadings of nitrogen oxides and other precursors. The transition point for ozone destruction to ozone production occurred at a nitric oxide concentration of the order of 50 pptv. Plumes of polluted air from various urban areas in the U.K. were experienced in the June campaign at Weybourne. Quantitative studies of ozone production in a plume from the Birmingham conurbation on 18 June 1995 showed that the measurement of ozone production agreed well with calculated production rates from the product of the nitric oxide and peroxy radical concentrations (r2=0.9). In wintertime conditions (October–November 1994) evidence was also found for oxidant production, defined as the sum of O3+NO2. At this time of year the peroxy radical concentrations (RO2) were much lower than observed in the summertime and the nitric oxide (NO) was much higher. There was still sufficient RO2 during the day, however, for a slow accumulation of oxidant. Confirmatory evidence for this comes from the diurnal co-variance of (O3+NO2) with PAN, an excellent tracer of tropospheric photochemistry. The same type of covariance occurs in summer between PAN and ozone. The results obtained in these series of measurements are pertinent to understanding the measures necessary to control production of regional photochemical air pollution, and to the production of ozone throughout the northern hemisphere in winter. 相似文献
167.
W. Jaeschke T. Salkowski J. P. Dierssen J. T. Trümbach U. Krischke A. Günther 《Journal of Atmospheric Chemistry》1999,34(3):291-319
During two measuring campaigns in early spring 1994 and 1995 (March/April) and one campaign in summer 1994, measurements of ozone, PAN, sulfur dioxide, nitric acid, and particulate nitrate, sulfate, and ammonium (only 1995) were recorded in the Arctic. Observations were made by aircraft at various sites in the eastern and western Arctic. Ozone concentrations showed a steady increase with altitude both in spring and summer. During five flights in springtime, low ozone events (LOEs) could be observed near the surface and up to altitudes of 2000 m. SO2 background concentrations, ranging from detection limit (0.5 nmol/m3) to 5 nmol/m3, were observed during both spring and summer. Distinct maxima up to 55 nmol/m3 in lower altitudes were only obtained in springtime. Concentrations of the organic nitrate PAN were within a similar range as those of the inorganic nitrate HNO3 during spring campaigns. In contrast, concentrations of particulate nitrate were one half an order of magnitude lower. HNO3 concentrations increased significantly with altitude. Evidently, HNO3 was intruded from the stratosphere into the troposphere. Sulfate concentrations ranged between 5 and 30 nmol/m3; ammonium concentrations were obtained within a range from 10 to 50 nmol/m3. 相似文献
168.
169.
Saline playas in north-western Nevada, U.S.A., remnants of pluvial periods of the Pleistocene, represent a tremendous source of unconsolidated sediments available for aeolian transport. This study investigated the transport of aqueous-soluble solutes in dust from July 1994 through June 1996 along a transect from a barren salt-encrusted playa surface (elevation=1224 m), to a former pluvial lake beach (elevation=1228 m), to a dune-mantled upland (elevation=1248 m). The content of aqueous-soluble solutes in aeolian dust showed a significant (p≤0·05) interaction with dust trap location (playa, beach, dune) and time of collection. Dust collectors on the playa surface generally contained significantly more aqueous-soluble solutes and had greater total flux of solutes than either the beach or the dune locations. The solute content of aeolian dust was usually higher, in some cases several orders of magnitude, than that in the surface 5 cm of soil. Recent changes in playa hydrology may explain this result. Pulses of nitrate-rich dust, synchronous with spring emergence, and other nutrient additions via aeolian dust may have stimulated invasion of dune-mantled uplands by the weedSalsola paulsenii (barb-wire Russian thistle). 相似文献
170.
温度、光照强度及硝酸盐对拟柱孢藻(Cylindrospermopsis raciborskii N8)生长的影响 总被引:4,自引:3,他引:1
以从南亚热带水库中分离的拟柱孢藻(Cylindrospermopsis raciborskii N8)为材料,研究了不同温度(12、16、20、24、28、32℃)、光照强度(6.6、12.4、21.5、30.7、62.9、106.4μmol/(m2·s))和硝态氮浓度(0.5、1、2、4、8、16、32、64、128 mg/L)下拟柱孢藻的生长特性.结果表明:在实验设置的温度范围(16~32℃)内拟柱孢藻能够正常生长;最适温度范围为24~28℃,在28℃条件下,具有最大比生长速率,为0.189 d-1;当温度为12℃时,拟柱孢藻叶绿素a浓度一直降低,显著低于其他温度组(16~32℃).在6.6~106.4μmol/(m2·s)光照强度范围内,拟柱孢藻均呈指数增长趋势,最适光照强度为30.7μmol/(m2·s),其比生长速率达到最大值,为0.156 d-1;高光照强度(62.9~106.4μmol/(m2·s))下拟柱孢藻的比生长速率显著大于低光照强度(6.6~12.4μmol/(m2·s))处理组.拟柱孢藻开始指数增长的最低硝态氮浓度为4 mg/L;硝态氮浓度为8 mg/L时,拟柱孢藻达到最大比生长速率(0.155 d-1);当硝态氮浓度高于16 mg/L时比生长速率增加不显著.高硝态氮浓度组(16~128 mg/L)拟柱孢藻的叶绿素a浓度和比生长速率显著高于低硝态氮浓度组(0.5~2 mg/L).研究结果说明拟柱孢藻对温度、光照和氮源均有较宽的生态位,有利于在较大空间尺度上进行扩散. 相似文献