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101.
俯冲带中的水在壳幔演化和物质交换中起重要作用。本文就俯冲带中水的物理化学性质、溶液中的离子缔合、混溶、主量元素与微量元素组成等方面进行了阐述。重点剖析:1)超临界态下温度压力条件的改变导致水微观结构与性质的变化,扩散系数、粘度等性质随之改变,进而对水岩反应产生影响;2)富水流体中离子缔合影响着金属配合物数量,很大程度制约流体中矿物的溶解行为;3)低Cl流体中微量元素配分模式与岛弧玄武岩类似,意味着富水贫氯碱性硅酸盐成分的流体在地幔楔元素运移中起关键作用。并展望了俯冲带中流体化学性质研究的新手段。 相似文献
102.
103.
Iron and manganese redox cycling in the sediment — water interface region in the Kalix River estuary was investigated by using sediment trap data, pore-water and solid-phase sediment data. Nondetrital phases (presumably reactive Fe and Mn oxides) form substantial fractions of the total settling flux of Fe and Mn (51% of Fetotal and 84% of Mntotal). A steady-state box model reveals that nondetrital Fe and Mn differ considerably in reactivity during post-depositional redox cycling in the sediment. The production rate of dissolved Mn (1.6 mmol m–2 d–1) exceeded the depositional flux of nondetrital Mn (0.27 mmol m–2 d–1) by a factor of about 6. In contrast, the production rate of upwardly diffusing pore-water Fe (0.77 mmol m–2 d–1) amounted to only 22% of the depositional flux of nondetrital Fe (3.5 mmol m–2 d–1). Upwardly diffusing pore-water Fe and Mn are effectively oxidized and trapped in the oxic surface layer of the sediment, resulting in negligible benthic effluxes of Fe and Mn. Consequently, the concentrations of nondetrital Fe and Mn in permanently deposited, anoxic sediment are similar to those in the settling material. Reactive Fe oxides appear to form a substantial fraction of this buried, non-detrital Fe. The in-situ oxidation rates of Fe and Mn are tentatively estimated to be 0.51 and 0.16–1.7 mol cm–3 d–1, respectively. 相似文献
104.
Brent B. Wolfe Thomas W. D. Edwards Ramon Aravena Glen M. MacDonald 《Journal of Paleolimnology》1996,15(2):171-181
Analysis of 18Ocellulose, 13Corganic matter, and 13Ccellulose at about 100 year intervals from organic matter deposited in Toronto Lake, Northwest Territories, Canada, revealed an 8000-year history of rapid, post-glacial hydrologic change at the treeline zone. Several mid-Holocene phases of enriched 13Corg and 13Ccell, caused by elevated lake productivity, declining [CO2(aq)], and closed basin conditions, were abruptly terminated by intervals of open hydrology recorded by sharply depleted 18Ocell. Two of these events, at 5000 and 4500 BP, are correlated with increased total organic content and Picea mariana pollen concentration, which indicate that high levels of productivity were also accompanied by northern treeline advances. A third treeline advance at about 2500 BP is also marked by an apparent outflow event from Toronto Lake, but this was not associated with 13Corg/cell enrichment in the sediment record because rapid and substantial lake water renewal probably prevented productivity-driven enrichment of the dissolved inorganic carbon and replenished the CO2(aq) supply to thriving phytoplankton. However, high sediment organic content during this period suggests increased productivity. Increases in the inflow:evaporation ratio at about 6500 and 3500 BP were also sufficient to cause Toronto Lake to overflow but the prevailing climate during these periods apparently did not favour appreciable northward treeline migration or changes in lake productivity.This is the 14th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers 相似文献
105.
Sustainable food systems face trade-offs between demands of low environmental pressures per unit area and requirements of increasing production. Organic farming has lower yields than conventional agriculture and requires the introduction of nitrogen (N) fixing legumes in crop rotations. Here we perform an integrated assessment of the feasibility of future food systems in terms of land and N availability and the potential for reducing greenhouse gas (GHG) emissions. Results show that switching to 100% organic farming without additional measures results in N deficiency. Dietary change towards a reduced share of animal products can aggravate N limitations, which can be overcome through the implementation of a combination of agroecological, circular economy and decarbonization strategies. These measures help to recycle and transfer N from grassland. A vegan diet from fully decarbonized conventional production performs similarly as the optimized organic scenario. Sustainable food systems hence require measures beyond the agricultural sector. 相似文献
106.
Victor?W.?TruesdaleEmail author Jim?E.?Greenwood Andrew?Rendell 《Aquatic Geochemistry》2005,11(3):319-343
This paper investigates the kinetics of biogenic silica dissolution in seawater, through batch dissolution, where the reaction
is observed as the increase in dissolved silicic acid concentration with time. It utilises new data from dissolution of the
marine diatom Cyclotella cryptica, and the freshwater diatom C. meneghiniana, as well as literature results. The sum of exponentials form:
, is hypothesised as the most general rate equation, with the single exponential form occurring in a minority of cases. The
consistency of this behaviour with a near-exponential decay of surface area with time, an appropriate mathematical integration,
and surface heterogeneity, is discussed. (Serious errors in some existing integrations are identified.) The rate of dissolution
at constant surface area is shown to decrease non-linearly as the ambient concentration of silicic acid increases. A fractional
order with respect to silicic acid in the back reaction, close to 0.5, leads to a mechanism in which an intermediate is formed
from the surface and an, as yet, unidentified molecule, probably water. Good preliminary fits are found between the model
and literature results found using entirely different methods. A parallel treatment of hydrogen ion dependency is suggested.
The likely distortion of full reaction curves from exponential behaviour imposed by the back reaction, is considered in detail. 相似文献
107.
潮滩生态系统中生源要素氮的生物地球化学过程研究综述 总被引:2,自引:1,他引:1
海岸带潮滩生源要素生物地球化学循环过程是国际地圈生物圈计划(IGBP)、海岸带陆海交互作用(LOICZ)研究的重要内容,也是全球变化区域响应研究中的重要组成部分。在过去的10~20年之间,潮滩生源要素氮的生物地球化学循环研究得到了长足的发展。基于此,较为全面、系统地总结和分析了有关潮滩氮营养盐的来源、潮滩氮素的物理、化学和生物迁移转化过程及氮素地球化学循环过程中底栖生物效应等一系列研究成果,并提出了今后潮滩生源要素氮的生物地球化学循环研究重点和发展趋向。 相似文献
108.
Javier Romero Gérard Pergent Christine Pergent-Martini Miguel-Angel Mateo Cécile Regnier 《Marine Ecology》1992,13(1):69-83
Abstract. The ecosystem associated to the Mediterranean seagrass Posidonia oceanica shows a clear distinction in two subcompartments regarding turnover time: aboveground and belowground. Aboveground parts (leaves) are highly dynamic, and most of the leaf material is decomposed or exported in less than one year, representing a net loss of nutrients. In contrast, belowground biomass (roots and rhizomes) has a turnover time of the order of centuries, with a consequent accumulation of organic matter in the sediment. The accumulation rates for the single elements rank in the order C > N > P. This ecosystem may be considered as a sink for biogenic elements. 相似文献
109.
Water, Salt, Phosphorus and Nitrogen Budgets of the Japan Sea 总被引:1,自引:0,他引:1
Tetsuo Yanagi 《Journal of Oceanography》2002,58(6):797-804
Water, salt, phosphorus and nitrogen budgets of the Japan Sea have been calculated by box model analysis using historical
data. Average residence time of the Tsushima Warm Current Water in the upper 200 m is 2.1 years and that of the Japan Sea
Proper Water is 90 years. The salt flux from the Tsushima Strait balances those through the Tsugaru and Soya Straits. Average
residence times of phosphorus and nitrogen from the Tsushima Strait are 2.2 years and 1.6 years, respectively, in the upper
200 m of the Japan Sea. Total nitrogen/total phosphorus ratios of riverine load, the Tsushima Warm Current water and the water
in the Japan Sea are 16.4, 16.6 and 11.3, respectively. This suggests that denitrification is dominant in the Japan Sea.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
110.
《Chemie der Erde / Geochemistry》2016,76(1):133-148
The variation of major and rare earth elements and yttrium (REY) in the monomictic hardwater Lake Tiberias during the wet and dry seasons of the hydrological year was studied in two profiles. The average volume and Cl concentration of the known and unknown saline inflows of 1.6 × 107 m3 and 1.2 × 109 mol are derived by closing both balances. This brine corresponds to a mixture of 83% of groundwater from Cretaceous aquifers and 17% of very saline deep brine. Taking cycling of calcite in the hypolimnion into account, the settling rate of authigenic calcite is estimated to be 3.3 mol m−2 a−1.In the stratified lake of the dry season dissolved inorganic carbon increases by 490 μM at the thermo-/chemocline due to microbial reduction of SO42−, NO3−, chemical reduction of Fe(III) and MnO2 colloids, and cycling of calcite in the hypolimnion. REY distribution in the stratified water column is dominantly controlled by coprecipitation with calcite, hydrous ferric oxides and MnO2 in the epilimnion and cycling of these compounds in the hypolimnion. The positive Ce anomaly in the hypolimnetic water is produced by cycling of MnO2. The simulation of the increase of REY in the hypolimnion reveals that hydrous ferric and manganese oxides only play a negligible role except Ce. Only about 10% of REY from cycled matter enhance REY in solution. Most of the released REY are adsorbed by particular matter and thus settling on the floor of the lake.Different from Na, U, SO42− and SiO2, the other elements, in particular REY, increase in the mixed water column from the top to the lower third and mostly decrease thereafter toward the bottom in the mixed lake during the wet season. The behavior of REY is caused by some cycling of calcite and pH-dependent re-equilibration of REY bound to hydrous ferric and manganese oxides adsorbed by particular matter. 相似文献