华南二叠－三叠系的事件地层与生物地层界线   总被引：10，自引：1，他引：9  

王成源 《地层学杂志》1994,18(2):110-118,145

华南二叠－三叠系界线研究应严格区分事件地层界线与生物地层界线。“界线粘土”层的底界即为事件地层界线。生物地层界线定义不能与“混生层”或“过渡层”的概念连在一起。长兴煤山忠心大队剖面是最好的二叠－三叠系全球界线层型剖面点（ＧＳＳＰ）。二叠－三叠系生物地层界线定义为ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,其位置就在长兴剖面界线层（混生层）２的内部,比事件地层界线高１５ｃｍ。ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,即为长兴阶的顶界。  相似文献   

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K     

M. Exner  H. Herrmann  R. Zellner 《Journal of Atmospheric Chemistry》1994,18(4):359-378

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.  相似文献   

Subarcsec 10μm imaging of bipolar flow sources     

S. Cabrit  P. O. Lagage  E. Pantin 《Experimental Astronomy》1994,3(1-4):151-152

We have started a program of high-resolution (0.4/pixel) 10m imaging of bipolar outflow sources using the 10m camera CAMIRAS. We present recent results obtained at the Canada France Hawaii Telescope which reveal extended emission or IR companions in several luminous objects. The extended emission we detected probably arises from transiently heated very small grains, while the newly discovered companions could contribute significantly to the outflow activity and extended far-IR emission usually attributed to the main optical source.  相似文献   

Densities of Huanghe River estuary and Bohai Bay waters     

陈国华  季荣  谢式南  张力军 《中国海洋湖沼学报》1994,12(2):130-135

The densities of 36 water samples from the Huanghe River estuary and Bohai Bay were determinedby a magnetic float densimcter under three temperatures from 15℃ to 25℃.All the measured densities ofsamples were greater than that of the values calculated from the International Equation of State of Seawater.The differences between the measured and calculated densities increased with the decrease of salinities.The dif-ferences appeared exponentially correlated with[Ca~(2+)]/s,[Mg~(2+)]/s and[SO_4~(2-)]/s,and had"s"type curverelationship with the alkalinity in all salinity range.But in the salinity ranging from 25.72 to 31.57,therelationships were all linear.The density difference can be estimated from the equation △ρ（10~3kg·m~(-3)）=（-2.79+236.5([Ca~(2+)]/s)/(-9.7464×10~（-3）+[Ca~(2+)]/s).It was the high alkalinity and[Ca~(2+)]/s that resulted in the measured densi-ties of seawaters being higher than the calculated densities in the Huanghe estuary and Bohai Bay.  相似文献   

Sub-arcsec 10 μm imaging of β pictoris and other star disk candidates     

P. O. Lagage  E. Pantin 《Experimental Astronomy》1994,3(1-4):57-60

We have used the ESO 10 m camera, TIMMI, to image with a very high angular resolution (PFoV: 0.3; FWHM:0.9) several main-sequence star disk candidates. Information on the -Pictoris dust disk has been obtained in a region largely inaccessible to previous observations: 0–80 AU, with a resolution of about 5 AU after deconvolution. Another promising target for 10 m imaging, 51 Ophiuchi, appears point-like.based on data collected at the European Southern Observatory (ESO), La Silla, Chile  相似文献   

勘查油气田化探新方法——土壤相态烃测量法     

李生郁  徐丰孚 《物探与化探》1993,17(6):441-448

烃气测量是油气化探最主要的方法。目前应用的烃气测量方法有两类:一类是测量土壤中游离烃气如K—V指纹法、吸附丝法、物上气法及直接取土壤气测量法等。此类方法由于需特殊设备及壤气测量方法本身固有的缺陷,目前还未得到普遍应用,另一类为土壤吸附烃气法即国内外目前普遍使用的酸解烃气法、此法在多数油气田上取得好效果,但也有相当多的地区如黄土、荒漠及水网发育等特殊景观区效果不好或不显著。本文介绍一种新的烃气测量法──土壤相态烃测量法。这是用一种特殊的技术,只选择性提取由油气藏渗漏过程中保存在运移通道围岩及近地表土壤各种次生矿物结构中以"穴居"态存在的轻烃组分。"穴居"态烃为累积性的指标,不受外界温度、修水等的影响,保存较牢固,测定结果稳定。相态烃法避免了酸解烃法存在的生物成因烃、矿物同生烃及碳酸盐的干扰影响,提高了测量指标的信噪比,突出了应有的异常。本方法已在黄土厚覆盖区两个已知油气田和一个风成沙覆盖的断裂发育油田上试验获得成功,结果表明相态烃法优于酸解烃法。  相似文献   

The deposit size frequency method for estimating undiscovered uranium deposits     

Richard B. McCammon  Warren I. Finch 《Natural Resources Research》1993,2(2):106-112

The deposit size frequency (DSF) method has been developed as a generalization of the method that was used in the National Uranium Resource Evaluation (NURE) program to estimate the uranium endowment of the United States. The DSF method overcomes difficulties encountered during the NURE program when geologists were asked to provide subjective estimates of (1) the endowed fraction of an area judged favorable (factorF) for the occurrence of undiscovered uranium deposits and (2) the tons of endowed rock per unit area (factorT) within the endowed fraction of the favorable area. Because the magnitudes of factorsF andT were unfamiliar to nearly all of the geologists, most geologists responded by estimating the number of undiscovered deposits likely to occur within the favorable area and the average size of these deposits. The DSF method combines factorsF andT into a single factor (F·T) that represents the tons of endowed rock per unit area of the undiscovered deposits within the favorable area. FactorF·T, provided by the geologist, is the estimated number of undiscovered deposits per unit area in each of a number of specified deposit-size classes. The number of deposit-size classes and the size interval of each class are based on the data collected from the deposits in known (control) areas. The DSF method affords greater latitude in making subjective estimates than the NURE method and emphasizes more of the everyday experience of exploration geologists. Using the DSF method, new assessments have been made for the young, organic-rich surficial uranium deposits in Washington and idaho and for the solution-collapse breccia pipe uranium deposits in the Grand Canyon region in Arizona and adjacent Utah.  相似文献   

Channel overflows of the Pōhue Bay flow,Mauna Loa,Hawai'i: examples of the contrast between surface and interior lava     

Zinzuni Jurado-Chichay  Scott K. Rowland 《Bulletin of Volcanology》1995,57(2):117-126

A number of overflows from a large lava channel and tube system on the southwest rift zone of Mauna Loa were studied. Initial overflows were very low viscosity gas-rich phoehoe evidenced by flow-unit aspect ratios and vesicle sizes and contents. Calculated volumetric flow-rates in the channel range between 80 and 890 m³/s, and those of the overflows between 35 and 110 m³/s. After traveling tens to hundreds of meters the tops of these sheet-like overflows were disrupted into a surface composed of clinker and phoehoe fragments. After these 'a' overflows came to rest, lava from the interiors was able to break out on to the surface as phoehoe. The surface structure of a lava flow records the interaction between the differential shear rate (usually correlated with the volumetric flow-rate) and viscosity-induced resistance to flow. However, the interior of a flow, being better insulated, may react differently or record a later set of emplacement conditions. Clefts of toothpaste lava occurring within fields of clinker on proximal-type 'a' flows also record different shear rates during different times of flow emplacement. The interplay between viscosity and shear rate determines the final morphological lava type, and although no specific portion of lava ever makes a transition from 'a' back to phoehoe, parts of a flow can appear to do so.  相似文献   

Diagenesis of vascular plant organic matter components during burial in lake sediments   总被引：12，自引：0，他引：12  

Philip A. Meyers  Mary J. Leenheer  Richard A. Bourbonniere 《Aquatic Geochemistry》1995,1(1):35-52

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.  相似文献   

Geochronology and geochemistry of eclogites from the Mariánské Lázně Complex,Czech Republic: Implications for Variscan orogenesis     

Brian L. Beard  L. Gordon Medaris Jr  Clark M. Johnson  Emil Jelínek  J. Tonika  Lee R. Riciputi 《International Journal of Earth Sciences》1995,84(3):552-567

The Mariánské Lázn complex (MLC) is located in the Bohemian Massif along the north-western margin of the Teplá-Barrandian microplate and consists of metagabbro, amphibolite and eclogite, with subordinate amounts of serpentinite, felsic gneiss and calcsilicate rocks. The MLC is interpreted as a metaophiolite complex that marks the suture zone between the Saxothuringian rocks to the north-west and the Teplá-Barrandian microplate to the south-east. Sm-Nd geochronology of garnet-omphacite pairs from two eclogite samples yields ages of 377±7, and 367±4 Ma. Samples of eclogite and amphibolite do not define a whole rock Sm-Nd isochron, even though there is a large range in Sm/Nd ratio, implying that the suite of samples may not be cogenetic. Eclogites do not have correlated _Nd values and initial ⁸⁷Sr/⁸⁶Sr ratios. Five of the eight eclogite samples have high _Nd values (+10.2 to +7.1) consistent with derivation from a MORB-like source, but variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7059) which probably reflect hydrothermal seawater alteration. Three other eclogite samples have lower _Nd values (+ 5.4 to –0.8) and widely variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7096). Such low _Nd values are inconsistent with derivation from a MORB, source and may reflect a subduction or oceanic island basalt component in their source. The MLC is an important petrotectonic element in the Bohemian Massif, providing evidence for Cambro-Ordovician formation of oceanic crust and interaction with seawater, Late Devonian (Frasnian-Famennian) high- and medium-pressure metamorphism related to closure of a Saxothuringian ocean basin, Early Carboniferous (Viséan) thrusting of the Teplá terrane over Saxothuringian rocks and Late Viséan extension.  相似文献