氢化物发生原子荧光光谱法测定氢氧化铟中砷含量     

韦刚  周素莲  黄肇敏  宫辛玲 《矿产与地质》2016,(2):294-296

文章对氢化物发生原子荧光光谱法测量氢氧化铟中砷含量的分析方法进行了研究,采用硫酸联胺把五价砷预还原成三价砷,利用三氯化砷的挥发性,经蒸馏分离砷,消除了基体铟干扰。方法线性范围为2ng/mL~70ng/mL,检测下限为2ng/mL,加标回收率为96%~113%,实际样品分析相对标准偏差为4.57%(n=5)。本方法与等离子体发射光谱法、DDTC-Ag分光光度法的分析数据吻合。  相似文献   

太阳能海水淡化技术   总被引：6，自引：0，他引：6  

苏润西 《海洋技术学报》2002,21(4):27-32

文章论述应用太阳能集热和太阳能光伏发电系统进行蒸馏淡化和膜法淡化的海水淡化方法。与传统动力源和热源相比 ,太阳能具有安全、环保等优点 ,将太阳能采集与脱盐工艺两个系统结合是一种可持续发展的海水淡化技术  相似文献   

渗透蒸馏浓缩柠檬酸     

于伯杉 《盐湖研究》1994,2(2):70-75

渗透蒸馏是适用于浓缩生物制品的一种新型膜过程．以ＮａＣｌ—柠檬酸稀溶液为研究体系，对渗透蒸馏的传质过程进行了研究，实验结果表明，水通量大于６７Ｋｇ／ｍ２·ｄ，柠檬酸可由３００ｇ／Ｌ浓缩到５００ｇ／Ｌ以上，同时还探索了渗透蒸馏和膜蒸馏浓缩柠檬酸的集成膜过程．  相似文献   

共沸蒸馏法制备电气石超细粉末   总被引：1，自引：0，他引：1       下载免费PDF全文

瞿金蓉胡明安  陈敬中 《岩石矿物学杂志》2003,22(4):401-404

分别以水和正丁醇为研磨介质，得到电气石超细粉末的液相悬浮体，利用水和正丁醇可以形成共沸物的特点，分别采用直接加热和共沸蒸馏法脱分散介质干燥悬浮体制备电气石超细粉末。透射电镜分析结果表明，直接加热脱去水或正丁醇会使电气石超细颗粒发生硬团聚，而共沸蒸馏法则可有效防止硬团聚的产生；拉曼光谱结果表明，共沸蒸馏法制备的电气石粉末表面存在O—H和C—H键，说明正丁醇在颗粒表面为化学吸附，而直接干燥法得到的电气石粉末表面则没有；X射线粉晶衍射结果表明，研磨过程降低了粉末衍射峰的强度，但直接加热干燥和共沸蒸馏干燥均未破坏电气石的晶格结构。正丁醇中的丁氧基在共沸蒸馏过程中在电气石颗粒表面可取代羟基，产生化学吸附，能有效防止液桥的产生，阻止干燥过程中超细粉末的硬团聚。  相似文献   

铼-锇同位素分析样品预处理研究进展   总被引：1，自引：0，他引：1  

黄小文  漆亮  高剑峰 《岩矿测试》2011,30(1):90-103

文章评述并归纳了近年来地质样品中Re-Os同位素分析的化学前处理方法研究进展。总结了锍镍火试金法、碱熔法、Carius管溶样法以及HPA-S高温高压釜溶样法等常用的Re-Os同位素样品消解方法。归纳了离子交换、溶剂萃取富集Re以及蒸馏、萃取等分离富集Os的方法。由于地质样品的复杂性,Re、Os含量的不均一性及测试方法的多样性,要求在具体分析过程中不同的样品使用不同的消解方法和分离富集方法。当前国内应用较成熟的Re、Os分离方法是Carius管逆王水分解样品,原位蒸馏或CCl4萃取方法分离Os,阴离子交换法或丙酮萃取分离Re。  相似文献   

蒸馏分离-电感耦合等离子体质谱法测定地球化学样品中痕量钌和锇   总被引：1，自引：1，他引：0  

施意华  杨仲平  熊传信  徐华 《岩矿测试》2010,29(4):350-354

建立了蒸馏分离-电感耦合等离子体质谱法测定地球化学样品中痕量钌和锇的分析方法。进行了蒸馏温度和时间、氧化剂、吸收液等条件的选择,消除了等离子体质谱法测定钌和锇的干扰。样品用过氧化钠熔融,酸化后以高锰酸钾-过硫酸钾-氯化钠作为同时蒸馏钌和锇的氧化剂,采用20 mL 50 g/L水合肼溶液同时吸收从混合物中分离出来的痕量钌和锇,用电感耦合等离子体质谱法测定。方法的检出限Ru为0.020 ng/g,Os为0.015 ng/g;方法加标回收率Ru为94.0%~102.7%,Os为96.0%~102.4%;精密度为4.72%~9.58%(n=12)。方法经国家一级标准物质验证,钌和锇的测定结果与标准值相符。  相似文献   

四川攀西地区钒钛磁铁矿成矿元素富集过程模拟与资源潜力评价     

刘才泽  秦建华  李明雄  张启明 《吉林大学学报(地球科学版)》2013,43(3):758-764,775

根据层状含钒钛磁铁矿岩体的韵律特征及其铁质量分数变化规律,探索性地应用瑞利分馏模型模拟四川攀西地区攀枝花、红格、白马、太和等岩体成矿元素富集过程,分别建立了各岩体的统计模型和理想模型,并据此估算了铁矿石以及伴生钒、钛资源量。其中:攀枝花、红格、太和等岩体的数学模型比较一致,可能与这些岩体岩浆结晶分异比较彻底、成矿性好有关;而白马岩体的模型参数有较大差异,充分体现了该岩体结晶分异不彻底、成矿性相对较差的特点。  相似文献   

天然海水硝酸盐氮同位素组成的蒸馏法测定     

杨志  陈敏  曹建平  邱雨生 《海洋学报》2012,34(3):72-79

建立了测定天然海水中硝酸盐氮同位素组成的蒸馏法,该方法主要是在碱性条件下利用戴氏合金将海水中的硝酸盐还原为氨,后利用稀盐酸吸收生产的氨,将得到的氨吸收液浓缩后干燥结晶,利用同位素比值质谱仪测定所得晶体的氮同位素组成。研究中开展了戴氏合金添加量及氨吸收溶液在不同条件下干燥结晶对氮同位素测值的影响研究。结果表明,戴氏合金添加量为3.0 g及60 ℃下直接干燥结晶为最佳的实验条件。所建立的氨蒸馏法氮空白值仅为(0.90±0.19) μmol,低于此前文献报道的氮空白值;氮同位素组成(δ15N)空白值为(-14.7±4.1)×10-3。运用所建立的氨蒸馏法实测得到的硝酸盐δ15N值与氨扩散法、硝酸盐直接测定法得到的数值非常吻合,进一步证明所建立氨蒸馏法的可靠性。改进后的氨蒸馏法适用于硝酸盐浓度在2~50 μmol/dm3内的天然海水硝酸盐氮同位素组成的测定,方法的标准偏差为±0.3×10-3。  相似文献   

Quantitative Recovery of Elemental Sulfur and Improved Selectivity in a Chromium-Reducible Sulfur Distillation     

Jens Gröger  Jennifer Franke  Kay Hamer  Horst D. Schulz 《Geostandards and Geoanalytical Research》2009,33(1):17-27

Chromium-reducible sulfur (CRS) distillations are intended to recover only reduced inorganic sulfur compounds (RIS) including elemental sulfur. However, the quantitative recovery of elemental sulfur is not ensured in common CRS-distillations. The new method presented here was designed to remedy this deficiency. An increase in ethanol concentration assured the quantitative recovery of elemental sulfur in various forms and, in addition, all other RIS-compounds were quantitatively recovered. Furthermore, the selectivity of the procedure was improved by an additional filtration step to eliminate zinc particles from the Cr(II)-solution. Thus, the recovery of sulfates and organic sulfur compounds was significantly decreased by a factor of up to 35, depending on the compound analysed. Exhaustive testing with a variety of pure phases, rock and soil samples demonstrated the precision and accuracy of the new method. The new protocol eliminated the constraints of previous procedures. The improved distillation efficiency for elemental sulfur ensured the quantitative recovery of all RIS-compounds in a single-step distillation.  相似文献   

Refinement of the Micro‐Distillation Technique for Isotopic Analysis of Geological Samples with pg‐Level Osmium Contents     

Nao Nakanishi  Tetsuya Yokoyama  Akira Ishikawa 《Geostandards and Geoanalytical Research》2019,43(2):231-243

In recent years, the ¹⁸⁷Re–¹⁸⁷Os isotope system has been increasingly used to study samples containing very small quantities of Os. For such samples, optimisation of measurement procedures is essential to minimise the loss of Os before mass spectrometric measurements. Micro‐distillation is a necessary purification step that is applied after the main Os chemical separation procedure, prior to Os isotope ratio measurements by negative‐thermal ionisation mass spectrometry (N‐TIMS). However, unlike the other separation steps, this procedure has not yet been optimised for small samples. In this study, we present a refined micro‐distillation method that achieved higher yields and allowed high‐precision R(¹⁸⁷Os/¹⁸⁸Os) expressed as ¹⁸⁷Os/¹⁸⁸Os measurements for small‐sized geological samples that contain only a few pg Os. The Os recovery in the micro‐distillation step was tested by changing the operating conditions including heating time and temperature, and amounts of oxidant and reductant. Recoveries were measured by the isotope dilution ICP‐MS method after the addition of ¹⁹⁰Os‐enriched spike solution. We found that the most critical factor controlling the chemical yield of Os during micro‐distillation is the extent of dilution of the reductant (HBr) by H₂O evaporated from the oxidant. A refined micro‐distillation method, in which the amount of oxidant solution is reduced from the conventional method, achieved an improved chemical yield of Os (~ 90%). This refined method was applied to the measurement of ¹⁸⁷Os/¹⁸⁸Os by N‐TIMS of varying test portions of the geological reference material BIR‐1a. The resulting ¹⁸⁷Os/¹⁸⁸Os ratios of BIR‐1a matched the literature data, with propagated uncertainties of 0.2, 1.1 and 11% digested sample quantities containing 150, 10 and 1 pg of Os, respectively.  相似文献