Quantitative Recovery of Elemental Sulfur and Improved Selectivity in a Chromium-Reducible Sulfur Distillation     

Jens Gröger  Jennifer Franke  Kay Hamer  Horst D. Schulz 《Geostandards and Geoanalytical Research》2009,33(1):17-27

Chromium-reducible sulfur (CRS) distillations are intended to recover only reduced inorganic sulfur compounds (RIS) including elemental sulfur. However, the quantitative recovery of elemental sulfur is not ensured in common CRS-distillations. The new method presented here was designed to remedy this deficiency. An increase in ethanol concentration assured the quantitative recovery of elemental sulfur in various forms and, in addition, all other RIS-compounds were quantitatively recovered. Furthermore, the selectivity of the procedure was improved by an additional filtration step to eliminate zinc particles from the Cr(II)-solution. Thus, the recovery of sulfates and organic sulfur compounds was significantly decreased by a factor of up to 35, depending on the compound analysed. Exhaustive testing with a variety of pure phases, rock and soil samples demonstrated the precision and accuracy of the new method. The new protocol eliminated the constraints of previous procedures. The improved distillation efficiency for elemental sulfur ensured the quantitative recovery of all RIS-compounds in a single-step distillation.  相似文献   

以Hg~(2+)离子为前驱体标定煤热解气中气相元素汞量     

曹艳芝  郭少青  高丽兵 《岩矿测试》2017,36(6):581-586

汞易挥发且通常以气态形式在大气环境中迁移转化,检测汞在气相中的含量可为汞的治理工作提供依据,但检测气相汞的技术并不成熟。该项工作需要准确地对气相元素汞量进行测定,而测定的前提是必须具备准确、可靠的标定方法。本研究提出以Hg~(2+)离子为前驱体标定煤热解气中气相元素汞量的方法。该方法是基于水溶液中Hg~(2+)可被还原剂定量还原成元素汞蒸汽的原理,实现对气相元素汞量的标定。与传统的基于饱和蒸汽原理的标定方法相比,该方法的优点是取样时不易受温度影响,易于精确控制汞量,且避免了实验室内储存汞蒸汽所造成的汞污染。以测定四种煤在热解过程中元素汞的释放量为例考察了本方法的准确性,结果表明本方法具有较好的重复性和适应性。与美国Ontario-Hydro方法分析的结果进行对比,两种方法的相对标准偏差均小于3.0%,说明本研究的标定方法的可靠性较高。  相似文献   

In–situ LA–ICP–MS trace elemental analyzes of magnetite: The Tieshan skarn Fe–Cu deposit,Eastern China     

《Chemie der Erde / Geochemistry》2017,77(1):169-181

The Tieshan Fe–Cu deposit is located in the Edong district, which represents the westernmost and largest region within the Middle–Lower Yangtze River Metallogenic Belt (YRMB), Eastern China. Skarn Fe–Cu mineralization is spatially associated with the Tieshan pluton, which intruded carbonates of the Lower Triassic Daye Formation. Ore bodies are predominantly located along the contact between the diorite or quartz diorite and marbles/dolomitic marbles. This study investigates the mineral chemistry of magnetite in different skarn ore bodies. The contrasting composition of magnetite obtained are used to suggest different mechanisms of formation for magnetite in the western and eastern part of the Tieshan Fe–Cu deposit. A total of 178 grains of magnetite from four magnetite ore samples are analyzed by LA–ICP–MS, indicating a wide range of trace element contents, such as V (13.61–542.36 ppm), Cr (0.003–383.96 ppm), Co (11.12–187.55 ppm) and Ni (0.19–147.41 ppm), etc. The Ti/V ratio of magnetite from the Xiangbishan (western part of the Tieshan deposit) and Jianshan ore body (eastern part of the Tieshan deposit) ranges from 1.32 to 5.24, and 1.31 to 10.34, respectively, indicating a relatively reduced depositional environment in the Xiangbishan ore body. Incorporation of Ti and Al in magnetite are temperature dependent, which hence propose that the temperature of hydrothermal fluid from the Jianshan ore body (Al = 3747–9648 ppm, with 6381 ppm as an average; Ti = 381.7–952.0 ppm, with 628.2 ppm as an average) was higher than the Xiangbishan ore body (Al = 2011–11122 ppm, with 5997 ppm as an average, Ti = 302.5–734.8, with 530.8 ppm as an average), indicating a down–temperature precipitation trend from the Jianshan ore body to the Xiangbishan ore body. In addition, in the Ca + Al + Mn versus Ti + V diagram, magnetite is plotted in the skarn field, consideration with the ternary diagram of TiO₂–Al₂O₃–MgO, proposing that the magnetite ores are formed by replacement, instead of directly crystallized from iron oxide melts, which provide a better understanding regarding the composition of ore fluids and processes responsible for Fe mineralization in the Tieshan Fe–Cu deposit.  相似文献   

云南省新街-董干地区地球化学特征及找矿方向     

蒿金星 《地质与勘探》2019,55(S1):419-428

以云南省新街-董干地区1:50000水系沉积物测量成果为基础,统计分析了水系沉积物地球化学参数。运用变异系数、成矿有利度、聚类分析及因子分析等方法分析区内19种元素的地球化学特征, 划分出五类成矿元素组合,确定了主成矿元素。根据组合异常的空间分布及特征,圈定34处综合异常,结合成矿地质条件划分了四处成矿远景区。  相似文献   

南秦岭夏家店金矿床赋矿黑色岩系元素地球化学及其成矿意义     

李声浩  朱赖民  丁乐乐  熊潇  刘凯 《地学前缘》2019,26(5):129-145

夏家店金矿床位于扬子板块早古生代被动大陆北缘的柞水—山阳盆地内,其赋矿黑色岩系的岩性主要为浅红色硅质岩、蓝灰色蚀变硅泥质岩、灰黑色薄层碳硅质板岩、土黄色泥质板岩和黑色碳硅泥质岩。黑色岩系主量元素、微量元素以及稀土元素分析结果表明：其主要成分为SiO2,并在硅质岩中含量最高,其中大离子亲石元素及成矿元素明显富集,如Sr、Ba、U、Cu、Zn、V、Au和Ag等元素含量均较高,是地壳丰度的几倍到几十倍;硅质岩样品总体呈弱负Ce异常、弱负异常或正Eu异常,泥质岩类显示Ce、Eu负异常,而少数碳硅质岩样品则表现出Eu的正异常,它们的北美页岩标准化稀土配分模式曲线均为向左缓倾。结合黑色岩系的岩石学特征和产出的大地构造环境以及主量、微量和稀土元素特征参数比值和判别图解,研究表明夏家店黑色岩系的成岩物质来源具有多样性,其下部的硅质岩主要为热水沉积的产物,随着海水及陆源物质的逐渐加入,在热水沉积逐渐向正常沉积所转化的过程中,形成碳硅质岩与泥质岩。夏家店金矿床赋矿黑色岩系形成于大陆边缘深水半深水滞留缺氧盆地环境,属扬子板块被动陆缘裂陷沉积区。夏家店金矿床赋矿黑色岩系超常富集Au、Ag、Ni、Cu、Zn、V和Ba等元素,黑色岩系可能是该矿床的重要矿源层。  相似文献   

炭山地区延安组下部泥质岩元素地球化学特征及其地质意义——以固油-1井为例     

何伟  王金敏  海连富  王磊  赵亚  丁文明 《中国煤炭地质》2019,(2):7-14

炭山地区的沉积背景归属长时间存在争议,前人将其划分为山间盆地,与鄂尔多斯盆地相对独立。本次研究采集固油-1油页岩调查钻孔所获延安组下部泥质岩岩心样品,通过微量元素、稀土元素以及稀散元素的分析测试,恢复了延安组下部沉积水体环境、古盐度、氧化还原条件,同时通过对比研究证实了炭山地区延安组沉积物源除来自于基底沉积地层以外,还有南华山—西华山一带早古生代花岗岩和长城系海原岩群的物源供给,印证了炭山地区沉积范围较广,推测其为鄂尔多斯盆地的一部分,并且在六盘山盆地内部可能赋存有厚层延安组。  相似文献   

The role of phosphorus in growth of phytoplankton in Lake Vesijärvi,southern Finland – a multitechnique approach     

Anne?OjalaEmail author  Satu?Kokkonen  Timo?Kairesalo 《Aquatic Sciences - Research Across Boundaries》2003,65(3):287-296

The role of phosphorus in phytoplankton growth was studied in Lake Vesijärvi, a large previously eutrophic body of water with a history of flourishing fishery. The study combined different approaches: long-term algal enrichment experiments with natural phytoplankton assemblages were carried out together with observations on nutrient and chlorophyll a concentrations, elemental ratios (N:P, C:P, C:N) of particulate matter, and analysis of P uptake using [³³P]. None of the approaches revealed periods of P limitation, but some growth experiments as well as elemental ratios indicated slight deficiency in early summer. Concentrations of total dissolved phosphorus (TDP), which were usually 20–30 g l^–1, also indicated luxurious P resources. Thermal stratification was weak and the lake mixed twice during the study period; this was reflected in the phytoplankton biomass that increased up to 4-fold. Results of elemental ratios usually suggested the occurrence of nitrogen limitation, and in general these ratios were low for a lake. All size fractions >0.22 m in the experiments with [³³P] showed P uptake. In August most of the P was taken up by picoplankton, but when the lake turned over in September, the uptake of P by this fraction was absent. Thus, there was always a plentiful supply of P for phytoplankton, but the shortage of inorganic N may have affected those algae not capable of fixing N₂. These conditions should have favoured the growth of heterocystous cyanobacteria, but these prokaryotes never attained high abundances. This may have been due to the weak stability of the water column, or the growth of cyanobacteria may have been limited by trace elements such as molybdenum or iron.  相似文献   

广西龙胜蛇绿岩的元素和同位素地球化学研究   总被引：1，自引：0，他引：1  

李献华 《地球学报》1997,18(Z1):95-97

广西北部新元古代早期龙胜蛇绿岩中火山岩的主量和微量元素地球化学特征非常类似于现代岛弧火山岩，并具有一致的但较低的εNd(t)值（—+1.0），表明其源区不可能是高度亏损型地幔源，而很可能来源于亏损程度较低的地幔源。龙胜蛇绿岩很可能形成于大陆弧靠大陆一侧的弧后盆地扩张阶段，或在大陆弧伸展-减薄过程中形成。  相似文献   

我国平原区土壤地球化学异常成因研究     

朱立新  马生明 《物探化探计算技术》2005,27(3):237-240

我国平原地区土壤地球化学异常普遍存在,但是目前对这些异常的成因缺乏系统认识。这里以长春和南京地区的Hg、Cd异常试验研究结果为例,利用元素相关关系法,对此进行了系统研究。结果表明,城镇及其周边地区的土壤地球化学异常,异常组分叠加量表现出表层累积型特点,此类异常的成因与人类活动有关。分布在河流沿岸的土壤地球化学异常,在垂向上,异常组分叠加量表现出了连续型分布特点,且异常组分含量主要受土壤物质组成的控制,此类异常是在河流沉积物自然沉积过程中形成的。  相似文献   

1908年俄罗斯通古斯大爆炸的地球化学特征和爆炸物体的估计   总被引：1，自引：1，他引：1  

侯泉林  马配学 《地质论评》1997,43(2):131-138

本文用中子活化分析方法(NAA)分析了俄罗斯通古斯(Tunguska)地区1908年爆炸事件影响层中的元素地球化学特征,发现Ir,REE,Ni,Fe,Co等元素在事件层附近明显异常,异常因子达2-5。在事件主要影响层中Ir和Ni呈明显相关性,REE的碳质球粒陨石标准化配分曲线比较平坦,且比率在Ⅰ左右。因此,说明这些元素异常是由Tunguska爆炸事件引起的,爆炸物体可能是碳质小行星或与之类似的星体。此外,根据Ir的异常丰度,估算了爆炸物体的重量(约10~(10)t),半径(约1.5km)和爆炸释放出的能量  相似文献