A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

基于贡献权重迭加法的滑坡风险区划   总被引：7，自引：1，他引：6  

乔建平  石莉莉王萌 《地质通报》2008,27(11):1787-1794

贡献权重迭加法是对滑坡本底因子和承灾体因子在滑坡发育中的贡献率进行统计后,通过贡献率均值化、规一化处理,利用权重转换模型计算出每一个因子内部的权重——自权重W和因子相互之间的权重——互权重W＇。将滑坡因子、承灾体因子和两者的自权重、互权重分别相乘迭加,得到滑坡危险度和易损度区划结果,再将2项结果相乘得出滑坡风险区划。  相似文献   

青藏高原西北缘祁漫塔格山中新世快速抬升 的磷灰石裂变径迹证据   总被引：1，自引：0，他引：1  

拜永山  任二峰  范桂兰  许长青 《地质通报》2008,27(7):1044-1048

对祁漫塔格山体不同海拔高度所取的9个磷灰石样品的裂变径迹分析结果表明,东昆仑西段中新世早中期为主要的隆升期且隆升速率较高,早期隆升速率为111m／Ma,晚期隆升速率为98m／Ma,总体隆升速率为100m／Ma。样品显示出磷灰石裂变径迹长度大致分2类,一类磷灰石裂变径迹长度为（12．21±10．20）-（13．75±0．30）μm,径迹长度分布图基本上为窄而对称的正态分布,反映具有快的剥露冷却速率,未受到后期热事件的干扰。另一类磷灰石裂变径迹长度为（11．88±0．33）～（13．32±0．27）μm,较前一类具有稍慢的剥露冷却速率,并且受到了后期热事件的干扰。  相似文献   

Actinic flux and photolysis frequency comparison computations using the model PHOTOGT     

Carsten Blindauer  Vladimir Rozanov  John Philip Burrows 《Journal of Atmospheric Chemistry》1996,24(1):1-21

The accurate radiative transfer model GOMETRAN, initially designed to yield radiances at TOA in the wavelength range 240–790 nm, has been extended to allow for the computation of actinic fluxes down to 175 nm and for the calculation of photolysis frequencies in the atmosphere. The capability of the extended model PHOTOGT (PHOTOGOMETRAN) is demonstrated in a number of successful comparison studies both with recent experiments (ground-based, balloonborne, airborne) and model calculations of radiances, actinic fluxes and photolysis frequencies in the stratosphere and troposphere. In an atmospheric case study, the impact of new quantum yield data for the O₃ » O₂+O(¹ d) photodissociation channel on the photolytic production of O(¹ d) atoms in the lower atmosphere has been quantified.  相似文献   

关于海平面上升及其环境效应   总被引：12，自引：0，他引：12  

陈梦熊 《地学前缘》1996,3(2):133-140

沿海地区地质环境复杂。由于国民经济的迅速发展,人类活动日益增多,对地质环境进一步造成严重的不利影响。特别是“温室效应”引发的海平面上升,使各种地质灾害更加激化。文章详细探讨了海平面上升的影响因素,理论海平面与相对海平面升降幅度的评估,以及海平面上升所造成的地质环境效应与相应的防治对策,特别强调控制沿海城市地面沉降,以减轻海平面相对上升造成的危害,具有特殊而重要的意义。  相似文献   

Rupture process of large earthquakes in the northern Mexico subduction zone     

Larry J. Ruff  Angus D. Miller 《Pure and Applied Geophysics》1994,142(1):101-172

The Cocos plate subducts beneath North America at the Mexico trench. The northernmost segment of this trench, between the Orozco and Rivera fracture zones, has ruptured in a sequence of five large earthquakes from 1973 to 1985; the Jan. 30, 1973 Colima event (M _s 7.5) at the northern end of the segment near Rivera fracture zone; the Mar. 14, 1979 Petatlan event (M _s 7.6) at the southern end of the segment on the Orozco fracture zone; the Oct. 25, 1981 Playa Azul event (M _s 7.3) in the middle of the Michoacan gap; the Sept. 19, 1985 Michoacan mainshock (M _s 8.1); and the Sept. 21, 1985 Michoacan aftershock (M _s 7.6) that reruptured part of the Petatlan zone. Body wave inversion for the rupture process of these earthquakes finds the best: earthquake depth; focal mechanism; overall source time function; and seismic moment, for each earthquake. In addition, we have determined spatial concentrations of seismic moment release for the Colima earthquake, and the Michoacan mainshock and aftershock. These spatial concentrations of slip are interpreted as asperities; and the resultant asperity distribution for Mexico is compared to other subduction zones. The body wave inversion technique also determines theMoment Tensor Rate Functions; but there is no evidence for statistically significant changes in the moment tensor during rupture for any of the five earthquakes. An appendix describes theMoment Tensor Rate Functions methodology in detail.The systematic bias between global and regional determinations of epicentral locations in Mexico must be resolved to enable plotting of asperities with aftershocks and geographic features. We have spatially shifted all of our results to regional determinations of epicenters. The best point source depths for the five earthquakes are all above 30 km, consistent with the idea that the down-dip edge of the seismogenic plate interface in Mexico is shallow compared to other subduction zones. Consideration of uncertainties in the focal mechanisms allows us to state that all five earthquakes occurred on fault planes with the same strike (N65°W to N70°W) and dip (15±3°), except for the smaller Playa Azul event at the down-dip edge which has a steeper dip angle of 20 to 25°. However, the Petatlan earthquake does prefer a fault plane that is rotated to a more east-west orientation—one explanation may be that this earthquake is located near the crest of the subducting Orozco fracture zone. The slip vectors of all five earthquakes are similar and generally consistent with the NUVEL-predicted Cocos-North America convergence direction of N33°E for this segment. The most important deviation is the more northerly slip direction for the Petatlan earthquake. Also, the slip vectors from the Harvard CMT solutions for large and small events in this segment prefer an overall convergence direction of about N20°E to N25°E.All five earthquakes share a common feature in the rupture process: each earthquake has a small initial precursory arrival followed by a large pulse of moment release with a distinct onset. The delay time varies from 4 s for the Playa Azul event to 8 s for the Colima event. While there is some evidence of spatial concentration of moment release for each event, our overall asperity distribution for the northern Mexico segment consists of one clear asperity, in the epicentral region of the 1973 Colima earthquake, and then a scattering of diffuse and overlapping regions of high moment release for the remainder of the segment. This character is directly displayed in the overlapping of rupture zones between the 1979 Petatlan event and the 1985 Michoacan aftershock. This character of the asperity distribution is in contrast to the widely spaced distinct asperities in the northern Japan-Kuriles Islands subduction zone, but is somewhat similar to the asperity distributions found in the central Peru and Santa Cruz Islands subduction zones. Subduction of the Orozco fracture zone may strongly affect the seismogenic character as the overlapping rupture zones are located on the crest of the subducted fracture zone. There is also a distinct change in the physiography of the upper plate that coincides with the subducting fracture zone, and the Guerrero seismic gap to the south of the Petatlan earthquake is in the wake of the Orozco fracture zone. At the northern end, the Rivera fracture zone in the subducting plate and the Colima graben in the upper plate coincide with the northernmost extent of the Colima rupture zone.  相似文献   

About the specification of erosion flux for soft stratified cohesive sediments     

Georges Chapalain  Y. Peter Sheng  André T. Temperville 《Mathematical Geology》1994,26(6):651-676

The present paper deals with the specification of bed erosion flux that accounts for the effects of sediment-induced stratification in the water column. Owing to difficulties in measuring the bed shear stress _b and the erosive shear strength _s, we suggest a series of methods that combine laboratory and numerical experiments. A simplified turbulent transport model that includes these effects helps to quantify _b and _s. Focusing on soft stratified beds, the present study considers erosion rate formulas of the form =_f exp {[T_b-T_s]} where is a model constant (=1 for Gularte's (1978) formula and =1/2 for Parchure's (1984) formula). First, the bed erosive strength profile _s(Z) is adjusted by forcing the turbulent transport model with measured erosion rates. Second, three procedures are suggested to determine the erosion rate formula coefficients _f and : a global procedure and two different layer-by-layer procedures. Each procedure is applied to an erosion experiment conducted in a rotating annular flume by Villaret and Paulic (1986). The use of the layer-by-layer procedure based on a least squares fitting technique provides a closer fit than the global procedure. The present study points out the complementarity of experimental and numerical approaches and also suggests possible improvements in laboratory test procedures.  相似文献   

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate     

Gerhard Kramm  Ralph Dlugi 《Journal of Atmospheric Chemistry》1994,18(4):319-357

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.  相似文献   

河北省唐山地区丰台—野鸡坨断裂第四纪活动性——来自¹⁴C和磁性地层年代学的证据          下载免费PDF全文

陈宏强  专少鹏  陈超  赵华平  杨瑞  何娇月  胥勤勉 《中国地质》2021,48(2):605-617

丰台—野鸡坨断裂为唐山地区主要断裂之一，西侧为鸦鸿桥凹陷，东侧为唐山凸起，断裂两侧第四系厚度之差巨大。本文依据该断层两侧钻孔对其第四纪以来活动性进行初步的探讨。通过对丰台—野鸡坨断裂上下两盘PZK14和PZK20孔磁性地层学研究，并结合钻孔岩石地层，及浅部光释光和¹⁴C测年结果，建立第四纪地层格架。结果表明：两孔底部“泥包砾”为新近纪沉积；PZK14孔下更新统底界埋深为387 m，中更新统底界埋深为114 m，上更新统底界埋深为71 m，全新统底界埋深为6 m；PZK20孔下更新统底界埋深为155 m，中更新统底界埋深为73 m，上更新统底界为36 m，无全新世地层。丰台—野鸡坨断裂活动在早更新世时表现为逐渐增强的特点，活动速率由早期的5.4 cm/ka增加到13.9 cm/ka。中更新世断裂活动基本处于停滞状态，活动速率为1.0 cm/ka。晚更新世以后，断裂重新活动，且更加剧烈，活动速率达到了54.5 cm/ka。  相似文献   

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S     

A. Hofzumahaus  T. Brauers  U. Platt  J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.  相似文献