快速城镇化进程中珠江三角洲高铵地下水赋存环境及驱动因素          下载免费PDF全文

吕晓立  刘景涛  韩占涛  朱亮  杨明楠  李海军 《中国地质》2021,48(6):1770-1780

地下水中高浓度的铵态氮对生活饮用水安全及生态环境存在潜在威胁。相比较硝态氮，高浓度的铵态氮不仅有各种人为来源，天然沉积环境更是造成高铵地下水的主要成因。本文以城镇化快速发展的珠江三角洲为研究区，运用数理统计、主成分分析等方法深入探讨了研究区高铵地下水的赋存环境特征及驱动因素。结果表明，研究区地下水中NH₄⁺质量浓度介于未检出~180 mg/L。研究区1539组地下水样品中，NH₄⁺质量浓度大于10 mg/L的高铵地下水69组，其中含NH₄⁺质量浓度大于30 mg/L的高铵"肥水"23组。对比2005-2008年历史水化学数据，2009-2018年新增建设用地孔隙含水层高铵地下水样品比例增加25%。高铵地下水呈斑块状分布于三角洲平原区第四系底部低洼的基底、洼地等退积层序发育的淤泥质含水层中。淤泥层等富含有机质和总有机碳的沉积层是珠江三角洲地区的"生铵层"，有机氮的矿化是三角洲平原区城市化孔隙含水层中高铵地下水的主要驱动力。城镇化扩张引起生活污水及富铵工业废水的泄漏入渗是城乡结合部高铵地下水铵氮的重要来源。三角洲平原区中性至弱碱性富含有机质的还原环境是高铵地下水的主要成因。风化溶滤、阳离子交换吸附、海陆交互作用是珠江三角洲高铵地下水质演变的主要水文地球化学过程。  相似文献   

山东省德州市“中华碘泉”矿泉水的发现与开发     

曹钦臣  赵广涛 《高校地质学报》1995,1(1):97-100

在山东省德州市首次探明国内稀有含碘饮用用天然矿泉水－－“中华碘泉”,研究表明,矿泉水是在新生代断陷盆地的构造背景和弱碱氧化的水文地球化学环境条件下,地下水与含水介南长期水－岩反应中经溶滤形成的,矿泉水水量丰富,水质优良,为含碘水苏打型矿泉水,但氟含量偏讥;为合理开发这一富足资源,可选用电渗析,倾析方法降低氟含量,并将其作为规模化含碘矿泉水生产的技术工艺。  相似文献   

论四川盆地三叠系地下水水文地质条件   总被引：3，自引：0，他引：3       下载免费PDF全文

林耀庭 《盐湖研究》2006,14(1):1-8

四川盆地三叠系地下水可划分出碎屑岩孔隙裂隙和碳酸盐岩岩溶裂隙两大储集类型。按此处构造开启程度和埋深条件等的不同,下中三叠统地下水有沉积变质水和渗入淋滤水两种基本成因类型,水动力特征各异。沉积变质水处于深埋封闭条件,受地静压力驱动控制;渗入淋滤水分布于背斜露头区和浅部地区,受静水压力驱动控制。并由此控制了盆地三叠系盐类的保存条件。  相似文献   

基于区域竞争力对比的新疆旅游资源开发分析   总被引：10，自引：5，他引：10  

黄耀丽  吴兆宁  郑坚强 《干旱区地理》2006,29(3):403-410

由于资源赋存、区位优势、基础设施、经济发展等方而存在的地域差异,使不同区域在旅游业发展中有不同的业绩和发展潜力。以20纪90年代以来新疆旅游接待量和旅游收入不断增长但旅游目的地地位明显下降为线索,对比研究了新疆的资源禀赋、开发程度、客源市场竞争态等,并调查分析了东南沿海及港澳台地区游客旅游意愿和赴疆游的客源市场潜力。提出区位条件是新疆在现阶段不可抗拒和短期内难以改变的客观因素,必须在现实基础条件下转变思维方式,宏观上以国内远程市场为目标,建立民俗-湖泊-冰川-草原-古迹-沙漠的旅游开发序位；中观上整合近域特殊地理单元内的同构旅游产品以打造品牌；微观上倡导“旅游体验”为核心的管理模式和开发理念。  相似文献   

Studies on environment protection of vanadium exploitation in open air     

Shenggao CHENG Qi AN Jing HU 《中国地球化学学报》2006,25(B08):29-29

Vanadium, improving mechanism and jointing capacity of steel products, is a kind of excellent additive during steel-making and its industry gets support from national industry policy. On account of shallow buried depth and low technique request of exploitation, there is much exploitation by local people lacking system management and technique guidance in area rich in vanadium since years ago, which damages regional environment dramatically. Accordingly, taking stone coal-vanadium as an example, the paper focuses on environment impact on water environment and eco-environment caused by exploitation in open air. Impact of exploitation on surface water mainly includes mining drainage and eluviated water of stock yard. According to civilian exploitation in the area, the rock suffers man-made disturbance, therefore, water quality indicators of mining drainage like heavy metal, permanganate, CI, SO4^2-, F are able to be analogies of ground water quantity in the region since the primary component of drainage is surrounding rock ground water. Water monitoring result of local well shows as follows： pH 6.68, SO4^2- 5.76 mg/L, F- 0.005 mg/L, Fe 0.025 mg/L, Mo 8.08 μg/L, Ni 5.91 μg/L, Co 0.61 μg/L, and all of them reach corresponding standard of water quality. Ground water turns into acid mine water by oxygenation after it discharges and with the help of sulfur the acid water contains nocuous elements which permeate in groundwater and surface water arousing pollution. The value of pH in the range of standard indicates that the acidification of mine water is relatively weak in the diggings. Eco-environment damage is another aspect that cannot be ignored, it acts as： （1） peeling work and establishment construction destroy landform; （2） stack of waste soil and rock occupies amounts of land; （3） various exploitation activities like vegetation peeling, landform change will enlarge the scope or enhance the intensity of soil erosion, which destroys eco-environment by leading water and soil loss;  相似文献   

XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit     

Yoko Fujikawa Daisuke Yoneda Atushi Minami Hiroshi Yashima Toshio Tonokai Sotoji Tani Masami Fukui Tatuhide Hamasaki Masataka Sugahara 《中国地球化学学报》2006,25(B08):113-113

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.  相似文献   

Metal contamination in southern Brazil vineyard softs     

《中国地球化学学报》2006,25(B08):120-120

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Analysis of the effect of geology, soil properties, and land use on groundwater quality using multivariate statistical and GIS methods     

Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152

The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use.  相似文献   

Application of HCA and PCA in the discrimination of not polluted tubular wells from tubular wells with incidence of anthropogenic pollution in Western Amazon Region     

《中国地球化学学报》2006,25(B08):165-165

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四川盆地地下卤水资源优势及综合开发前景   总被引：3，自引：0，他引：3       下载免费PDF全文

林耀庭 《盐湖研究》2006,14(4):1-8

四川盆地地下卤水自震旦系至白垩系各层系皆有分布。卤水具有分布广泛、资源丰富、品质优异、高承压及气卤同产等优势特点,是四川得天独厚的液态矿产资源。卤水中含有K+、Br-I、-、B3+、Li+、Sr2+、Rb+等多种有用组分,皆为国家紧缺和紧俏物质,其含量多数可达工业开采品位,为优质化工原料水,经济价值极高,综合开发利用前景广阔。  相似文献