Determination of Halogens (F, Cl, Br, I), Sulfur and Water in Seventeen Geological Reference Materials   总被引：5，自引：0，他引：5  

Agnès Michel  Benoît Villemant 《Geostandards and Geoanalytical Research》2003,27(2):163-171

Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l⁻¹. Bromine and I were measured by ICP-MS with detection limits of 1 μg l⁻¹ for Br and 0.1 μg l⁻¹ for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg⁻¹ for F and Cl, 15 mg kg⁻¹ for S, 0.2 mg kg⁻¹ for Br and 0.02 mg kg⁻¹ for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H₂O degassing, reduction on zinc at 1000 °C and H₂ manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   

水电解制氢设备在使用中应注意的问题     

刘希林  黄伟成  王永林  黎桂发 《气象研究与应用》2003,24(3):57-58

介绍GX-2型水电解制氢设备在使用过程中,对电解液的配制与氢气纯度分析应注意的问题。  相似文献   

Diurnal Variations of Atmospheric Hydrogen Peroxide Concentrations in Saxony (Germany)     

THOMAS GNAUK  WOLFGANG ROLLE†  GERALD SPINDLER 《Journal of Atmospheric Chemistry》1997,27(1):79-103

During a 3-year study, gaseous hydrogenperoxide (H₂O₂) concentrations were measuredas part of the SANA project at the Melpitz FieldResearch Station and in the city of Leipzig. Typicaldaily mean H₂O₂ mixing ratios on sunny dayswere 0.15 to 0.25 ppbv with maximum values of 0.3 to0.5 ppbv at Melpitz, and 0.3 to 0.6 ppbv with maximumvalues of 0.4 to 1.0 ppbv in Leipzig. Over the entireperiod of the project the maximum hourly mean valueswere 2.1 ppbv and 5.3 ppbv in Melpitz and Leipzig,respectively. The data were not complete enough to show a trend.Linear regression analysis shows, that ozone(O₃), temperature and solar radiation arepositively correlated with H₂O₂, whereasnitrogen oxides (NO_x), carbon monoxide (CO) andrelative humidity are negatively correlated. Negativecorrelation between H₂O₂ and CO is caused byjoint occurrence of CO with NO_x in exhaust gases.Negative correlation between H₂O₂ andrelative humidity is not necessarily in contradictionto the accelerating effect of water vapour onH₂O₂ formation. The strong positivecorrelation of H₂O₂ with the dew pointdifference however seems to better reflect theinfluence of water vapour. Multiple linear regression analysis (MLRA) of thecomponents measured, indicates the great influence of CO on the formation of H₂O₂ in the gasphase.  相似文献   

Organic pollutants associated with macromolecular soil organic matter: Mode of binding   总被引：2，自引：0，他引：2  

H. H. Richnow  R. Seifert  J. Hefter  M. Link  W. Francke  G. Schaefer  W. Michaelis   《Organic Geochemistry》1997,26(11-12)

A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.  相似文献   

栖霞金矿床成矿流体地球化学研究   总被引：2，自引：1，他引：2  

翟建平  胡凯 《地球化学》1996,25(6):568-574

栖霞金矿床是胶东地区产在变质岩中的石英脉型金矿床较典型的代表。该矿床属中低温热液矿床，成矿流体的盐度较低，气相成分以Ｈ２Ｏ，ＣＯ２为主；液相成分中Ｎａ＾＋，Ｃａ＾２＋和Ｃｌ＾－的含量料高，相对贫Ｋ＾＋和Ｆ＾－，流体的成分与大气降水热液的相类似。  相似文献   

大别山双河片麻岩氢氧同位素特征及其变质地球化学意义   总被引：4，自引：2，他引：4  

傅斌  郑永飞 《岩石学报》1997,13(4):451-472

  相似文献   

Molecular modeling of the 10-Å phase at subduction zone conditions     

Jianwei Wang 《Earth and Planetary Science Letters》2004,222(2):517-527

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.  相似文献   

洪水保险债券的运作机制与发展思路          下载免费PDF全文

魏敏杰  纪昌明 《水科学进展》2004,15(1):113-116

由于传统(再)保险,难以将洪灾风险进行有效的分散,因此,有必要寻求有效的金融工具将洪灾风险向资本市场转移。在建立洪水保险债券的概念框架基础上,阐述了与普通债券及传统再保险的区别。从经济学和精算学的角度对洪水保险债券进行分析,揭示了洪水保险债券定价机制。通过研究洪水保险债券的运作模式,分析了我国洪水保险债券的发行条件与发展思路,指出洪水保险债券为我国防洪减灾提供了可资借鉴的崭新方法与工具。  相似文献   

Genesis of Kanggur Gold Deposit in Eastern Tianshan Orogenic Belt, NW China: Fluid Inclusion and Oxygen and Hydrogen Isotope Constraints   总被引：3，自引：0，他引：3  

Zhiliang Wang    Neng Jiang  Yitian Wang    Jingwen Mao  Jianmin Yang 《Resource Geology》2004,54(2):177-185

Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO₂-H₂O inclusions that have a constant range in CO₂ content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120 to 310C) and CO₂-H₂O inclusions (140 to 340C). Estimates of fluid salinity for CO₂-H₂O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl.
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ¹⁸O and δD values of the ore-forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ¹⁸O and δD values, magmatic and/or meta-morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water.  相似文献   

Isotopic evidence of TSR origin for natural gas bearing high H_2S contents within the Feixianguan Formation of the northeastern Sichuan Basin, southwestern China   总被引：9，自引：0，他引：9  

ZHU Guangyou  ZHANG Shuichang  LIANG Yingbo  DAI Jinxing & LI Jian Research Institute of Petroleum Exploration  Development  PetroChina  Beijing  China 《中国科学D辑(英文版)》2005,48(11)

Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be…  相似文献