Rare-earth element mobility during ore-forming hydrothermal alteration: A case study of Dongping gold deposit Hebei Province,China     

包志伟  赵振华 《中国地球化学学报》2003,22(1):45-57

REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized.The Dongping gold deposit,which is located in northwestern Hebei Province,China,occurring in the inner contact zone of the Shuiquangou syenite complex,is spatially,and probably genetically,related to the syenite,the deposit was formed under the moderate to high temperature(220℃ to 320℃),weakly acidic to weakly alkaline,rather high fo2(lgfo2=-30～-34)environment.The REE study of the host rocks,altered wall rocks,ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification.The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite.The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages,LREE/HREE ratios in the gangue quartz and hydrothermal Kfeldspars are relatively low.The most significant observation is that the gangue quartz shows significant positive Eu anomaly,whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process.Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce.The REE,Y,U,Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins.As the ores were deposited under a rather oxidized environment,Ce^4 predominated over Ce^3 .The precipitation of the former in the form of CeO2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks.in contrast,Eu was present mainly in a low valence state (Eu^2 ).The geochemical differences from the other REE^3 and much less sites in the secondary minerals to accommodate the Eu released form the original minerals resulted in the enrichment of Eu in the fluids.The mobility and differentiation of REE and the coherent mobilities of Y,U,Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization.The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.  相似文献   

山西义兴寨金矿床金矿物颗粒的产出及其成矿动力学意义   总被引：1，自引：0，他引：1  

叶荣  涂光炽  赵伦山  沈镛立  罗丽 《矿床地质》2002,21(3):278-282

山西义兴寨金矿床的金主要呈包体金和裂隙金两种产出状态.文章根据成矿地球化学动力学理论,论证了金元素在含矿断裂发生脆性破裂和脆-韧性扩张活动中析出的化学反应类型,以及受反应动力学条件的制约,形成矿石中金不同产出状态的规律.指出热液矿床中普遍存在的包体金为热液成矿早期阶段断裂发生脆性破裂和成矿流体沸腾,导致快速反应结晶的产物;而裂隙金和晶隙金为成矿晚期金等矿质在流体中残余富集,同时成矿断裂再次发生脉动破裂,即成矿热力学演化与有利的构造动力学因素耦合作用的结果.得出金矿物颗粒的产出状态具有成矿动力学意义的结论.  相似文献   

陕西二台子铜金床钠长石碳酸（角砾）岩类特征及形成构造背景分析   总被引：7，自引：0，他引：7  

方维萱  张国伟 《岩石学报》2000,16(3):392-400

从岩石学、矿物学、岩石化学、地球化学、稀土元素等方面研究了二台子铜金矿内长石炭酸（角砾）岩类地质地球化学特征。晚泥盆世－石炭纪,在区域幔羽构造作用下,深部热流体沿先存在构造通道上升进入镇安二台子三级热水沉积盆地之中,形成了石英重晶石炭酸角砾岩、碳酸角砾岩、复成分角砾岩、钠长岩、钠长石碳酸岩,受同性断裂及层位控制明显,并构成了金的矿源层及普遍金矿化。燕山期,具有幔源特征的深部含矿热流体在北东、北西向  相似文献   

A field study of the coupled effects of aquifer stratification,fluid density,and groundwater fluctuations on dispersivity assessments     

Robert S. Woumeni  Michel Vauclin 《Advances in water resources》2006

A number of experimental studies have tackled the issue of solute transport parameter assessments either in the laboratory or in the field. But yet, the behavior of a plume in the field under density driven forces, is not well known due to possible development of instabilities. Some field tracer tests on the fate of plumes denser than native groundwater such as those encountered under waste disposal facilities, have pointed out the processes of sinking and splitting at the early stage of migration. The process of dispersion was widely investigated, but the range of dispersivity values obtained from either experimental tests, or numerical and theoretical calculations is still very large, even for the same type of aquifers. These discrepancies were considered to be essentially caused by soil heterogeneities and scale effects. In the meantime, studies on the influence of sinking and fingering have remained more scarce. The objective of the work is to analyze how transport parameters such as dispersivities can be affected by unstable conditions, which lead to plume sinking and fingering. A series of tracer tests were carried out to study under natural conditions, the transport of a dense chloride solution injected in a shallow two-layered aquifer. Two types of experiments were performed: in the first type, source injection was such that the plume could travel downward from one layer to the other of higher pore velocity, and in the second one, the migration took place only in the faster layer. The results suggest some new insights in the processes occurring at the early stages of a dense plume migration moving in a stratified aquifer under groundwater fluctuations, which can be summarized through the following points: (i) Above a stability criterion threshold, a fingering process and a multi modal plume transport take place, but local dispersivities can be cautiously derived, using breakthrough curves matching. (ii) When water table is subject to some cycling or rising, the plume can be significantly distorted in the transverse direction, leading to unusual values of the ratio between longitudinal and transverse dispersivities. (iii) Under stable conditions, for example in the case of straightforward injection in the faster aquifer layer, longitudinal dispersivity is greater than the transverse component as usually encountered, and the obtained transport parameters are closed to macro dispersivity values, which reach their asymptotic limit at very short distances. (iv) The classical scale effect about the varying dispersivity at short distances could be a process mainly due to the distance required for a plume stabilization.  相似文献   

胶东金矿集区硫和碳的循环与控矿作用     

孙林  杨斌  郭建军  杨开春 《矿产与地质》2006,20(2):97-101

胶东金矿集区矿石中普遍含金属硫化物和碳酸盐矿物,某些矿床中还见有富含炭质的断裂破碎带.成矿溶液中含有大量的SO4^2-、HCO3^-、CO2和有机质等的含硫和含碳组分.矿石硫同位素组成明显富集重硫,结合胶东金矿主要成矿时期（早白垩世）特殊的地质背景、同期海水硫酸盐δ^34S平均值（约＋16‰）及现代海水沿NE-NNE向断裂倒灌情况,笔者认为,硫的主要来源与海水硫的大量补给有关.而根据碳、氧同位素组成特征分析,形成金矿床中方解石的物源有很大一部分来自前寒武系碳酸盐岩.浅表环境下成矿金属元素及硫、碳等物质在热液对流系统中的大规模循环是成矿的关键,SO4^2-与S2^-之间的临界转化是制约成矿金属元素活化-迁移-聚集的重要因素,而含碳组分（CO3^2-、HCO3^-、CO2和有机质）则有利于Au、Cu、Pb、Zn等元素的活化和迁移,含硫和含碳组分的循环及有关的物理化学反应之间有明显的关联性.  相似文献   

白河黄石板铅锌矿的热水沉积岩及找矿潜力     

魏东  吴邦朝  朱经祥 《陕西地质》2006,24(1):66-73

经过对黄石板铅锌矿含矿层展布、产态、矿化富集规律等基本特征的总结,以及对含矿层中典型热水沉积岩岩石学特征、岩石化学特征、含矿物质来源初步分析,通过热水沉积岩和盆地正常水沉积围岩的稀土元素地球化学等与南秦岭泥盆纪热水沉积岩的对比、研究,初步认为白河县黄石板铅锌矿为一较典型的热水沉积矿床。提出黄石板矿区西段高家沟一带深部仍存在隐伏矿体的可能性较大,并通过钻探验证发现较富隐伏铅锌矿体。运用热水沉积成岩成矿理论指出该地区找矿方向。  相似文献   

贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响   总被引：19，自引：0，他引：19  

代世峰  任德贻  李丹  雒昆利 《地质学报》2006,80(4):589-597

运用电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、带能谱仪的扫描电镜(SEM-EDX)、逐级化学提取(SCEP)和光学显微镜等方法,对贵州大方煤田11号煤层的地球化学和矿物学进行了研究。结果表明,大方煤田11号煤层中有高含量的脉状石英(11.4%)和脉状铁白云石(10.2%),铁白云石周边常被针铁矿所包裹,在脉状石英中发现有热液成因的黄铜矿、闪锌矿和硒方铅矿,此外,还有少量高岭石充填在脉中,这7种矿物常常同脉共存。脉状石英和脉状铁白云石分别来源于硅质和富铁的钙质低温热液流体,形成温度分别为180℃和85℃。脉状石英早于脉状铁白云石形成。根据Ca/Sr和Fe/Mn值,确定出铁白云石的形成至少经历了3个时期。这7种矿物按照从早到晚的生成顺序为硫化物、石英、高岭石、铁白云石和针铁矿。铁白云石是煤中Mn、Cu、Ni、Pb和Zn富集的主要原因,这5种微量元素的含量分别为0.09%、74.0μg/g、33.6μg/g、185μg/g和289μg/g。脉状石英是煤中铂族元素Pd、Pt和Ir的主要载体,它们在煤中的含量分别为1.57μg/g、0.15μg/g和0.007μg/g。另外,黄铜矿、闪锌矿和硒方铅矿亦是11号煤层中Cu、Zn和Pb的重要载体。  相似文献   

河南冷水北沟铅锌矿地质地球化学特征及成因探讨   总被引：9，自引：4，他引：9  

王长明  张寿庭  邓军  孙艳霞  燕长海  叶会寿 《矿床地质》2007,26(2):175-183

冷水北沟铅锌矿床赋存于元古界栾川群和管道口群内,矿体受断裂破碎带及矽卡岩带的控制。矿石类型可分为热液脉型和矽卡岩型,矿体围岩蚀变强烈。根据矿床地质-地球化学特征,结合矿石的矿物共生组合、铅和硫同位素组成及成矿年龄、包裹体成分及特征,认为该矿床的矿源为岩浆岩,成矿溶液主要来自岩浆水和大气降水的混合溶液,矿床成因类型属中高温条件下形成的热液脉型-矽卡岩型矿床。  相似文献   

江西银山矿伊利石化过程中围岩化学成分变化及其成矿意义     

李满根  胡宝群  白丽红  郭国林  王正其  王振兴 《大地构造与成矿学》2007,31(3):353-358

江西银山热液多金属矿床矿体围岩发生了强烈的伊利石化,研究这些伊利石化是认识本矿床成矿作用的关键之一。通过伊利石的化学成分和矿体围岩蚀变前后的化学成分比较等方面的研究,本文得出以下认识:银山矿矿体围岩千枚岩、英安质流纹岩和中酸性次火山岩都发生了强烈的伊利石化,矿石与蚀变千枚岩中伊利石的化学成分最为相近。银山矿矿体蚀变围岩的化学成分以K2O的含量较高、Na2O和CaO的含量都很低(平均值都在0.11%左右)为特征,矿体围岩在伊利石化过程中Ca和Na被大量带出。综合各方面的证据推测,引起强烈伊利石化的热液是以H2O+CO2为主要组份的氧化性火山-次火山热液。  相似文献   

陕西凤县八方山-二里河（铜）铅锌矿床地质特征及成矿模式     

陈二虎张新胜  高卫宏 《西北地质》2007,40(B07):13-17

在综合分析凤-太矿集区成矿构造特征的基础上，依据以往总结的凤．太矿田铅锌、金矿聚矿构造模式，通过对八方山-二里河铅锌矿床地质特征的分析，总结了找矿标志，初步认为八方山-二里河（铜）铅锌矿床的成矿模式为：“前泥盆纪海底热水喷流沉积一印支-燕山期构造改造型”铅锌矿床。认为成矿物质来源于基底，后期的构造-岩浆改造使基底成矿元素活化，沿同生断裂迁移、改造，最后在泥盆系中形成的扩容性构造部位富集成矿。提出了下一步扩大找矿的方向和建议。  相似文献