Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses     

Martin Rosner  Michael Wiedenbeck  Thomas Ludwig 《Geostandards and Geoanalytical Research》2008,32(1):27-38

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.  相似文献   

Recommended Values of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry     

Taeko Shinonaga  Helmuth Aigner  Dilani Klose  Peter Spinder  Heinz Fröschl  David Donohue 《Geostandards and Geoanalytical Research》2008,32(1):93-101

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.  相似文献   

河流活性物质入海通量:概念与方法   总被引：1，自引：0，他引：1  

周国华  孙彬彬  刘占元  魏华玲  曾道明 《地质通报》2008,27(2):182-187

河流水体中呈溶解态和悬浮物结合态的元素活动性强,具有生态环境意义,查明其入海通量是当前生态地球化学评价的重要任务。通过总结前人的相关研究成果,确定了影响河流水体悬浮物的浓度及其矿物、化学组成的主要因素。从沿海经济带区域生态地球化学评价的实际需要出发,拟定了开展中国主要入海河流水溶态和悬浮物结合态元素入海通量调查的基本框架。  相似文献   

Effect of volatiles erupted from Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China     

Zhengfu Guo  Xiaoyu Chen  Jiaqi Liu 《Frontiers of Earth Science》2008,2(2):236-239

Based on the determination of composition of volcanic volatiles and petrologic estimation of the total mass of volatiles erupted, we showed important advances in the study of the impact of Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China. The volcanic activities include western Liaoning and Zhangjiakou Mesozoic intermediate-acidic explosive eruptions, southern Tibet and Shanwang Cenozoic volcanism, and Mt. Changbai volcanic eruption around one thousand years ago. The paper predominantly discusses the earth’s surface temperature changes, ozone depletion, acidic rain formation and mass mortalities of vertebrate induced by the Mesozoic and Cenozoic volcanism in China. __________ Translated from Bulletin of Mineralogy, Petrology and Geochemistry, 2007, 26(4): 319–322 [译自: 矿物岩石地球化学通报]  相似文献   

临涣矿区界沟煤矿工程地质条件研究     

黄芳友  张文永  徐胜平 《中国煤炭地质》2008,(7):55-58

根据主采煤层顶底板岩体岩性类型及结构面发育程度对其稳定性进行了评价：72煤层顶板以中等稳定一不稳定类型为主,82煤层顶板以中等稳定类型为主,10煤层顶板以中等稳定一稳定类型为主。在大量统计见煤点硬质岩百分含量（k值）的基础上,结合顶板岩石的单轴抗压强度,对各主采煤层顶底板工程地质类型进行了划分：72煤层以一、二类顶板为主,82、10煤层均以五类顶板为主。综合评价该矿工程地质条件为中等即Ⅲ类二型。根据研究成果,指出该矿在采掘过程中可能出现的工程地质问题,并依此提出了治理建议。  相似文献   

The discovery of metal trace elements in natural gas and its ecologic environmental significance.     

WANG Che-Xi DENG Mei-Zhou LIU Ying-Han LIU E-Wei LI Nie-Yun LU Ren-Ji 《地学前缘》2008,15(6):124

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A quantitative analysis of the prototype [WCL] star CPD-56° 8032     

Paul A. Crowther  Orsola De Marco  M. J. Barlow  P. J. Storey 《Astrophysics and Space Science》1996,238(1):119-123

We present a detailed, quantitative study of the standard [WC10] Wolf-Rayet central star CPD-56^o 8032 based on new high resolution AAT UCLES observations and the Hillier (1990) WR standard model. Our analysis of CPD-56^o 8032 gives the wind properties (T _*=34500K, lg (L/L )=3.8, lg (M/M a^–1)=–5.4,v =225 km s^–1) and chemistry (C/He=0.5, O/He=0.1, by number), the latter suggesting an intimate relationship with the Ovi PN central stars and the PG 1159-035 objects. A comparison between the wind properties of CPD-56^o 8032 and Sk-66^o 40 (WN 10) indicates that low excitation, low wind velocity WR winds are common to both low mass PN central stars (WC sequence) and high mass post-LBV's (WN sequence).  相似文献   

Whistler observations of the quiet time plasmasphere-ionosphere coupling fluxes at low latitude     

Lalmani  R. P. Singh  Rajesh Singh  Altaf Ahmad 《Earth, Moon, and Planets》1996,74(1):7-15

Observations of whistlers during quiet times made at low-latitude ground station Nainital (geomag. lat. 19 1 N) are used to deduce plasmasphere-ionosphere coupling fluxes. The whistler data from 3 magnetically quiet days are presented that show a smooth decrease in dispersion with time. This decrease in dispersion is interpreted in terms of a corresponding decrease in electron content of tubes of ionization. The electron densities, electron tube contents (10¹⁶ el/m²-tube) and coupling fluxes (10 el m^–1 s^–2) are computed by means of an accurate curve fitting method developed by Tarcsai (1975) and are in good agreement with the results reported by other workers.  相似文献   

不均匀植被分布对地表面和大气边界层影响的数值试验   总被引：9，自引：0，他引：9  

季劲钧  苗曼倩 《大气科学》1994,18(3):293-302

研究陆地与大气间相互作用的方法之一是建立联系地表面层与大气间各种过程的数值模式进行模拟。本文是建立一个陆面过程与二维大气边界层相耦合的模式,耦合模式中包含了发生在大气边界层、植被冠层和土壤表层各种动力、热力和水文过程。运用这一模式模拟了荒漠环境中一片绿洲的不均匀地表面形成的局地气候。由于绿洲植被与周围荒漠有着显著不同的水份与能量平衡关系,使绿洲表面与边界层较四周荒漠冷而湿,并形成了相应的局地环流,即所谓“绿洲效应”。试验结果表明,模拟的气候状况与观测现象是一致的。模式可以用于陆气相互作用的研究。  相似文献