天然气的无机元素的土壤化探元素预测指标的探索   总被引：1，自引：0，他引：1  

赵琦  罗正春  刘永平 《四川地质学报》2001,21(4):229-232

通过德阳新场气田化探成果与气田上有机元素异常，物探异常和钻孔实际见气的对比，以及对成都地区，宜宾地区化探成果的综合研究，认为As,Sb,Hb,Ba,Mn五元素及Cu,Pb,Zn,Mo,Cd,Ni,V,P等是预测天然气的指标，用该指标对新场气田和成都地区实际勘察结果对照，证实预测指标是正确的，从而探索出一条利用化探无机元素异常寻找天然气的新路。  相似文献   

多种方法确定单井中的地层重复——以吐鲁番—哈密盆地鄯科1井三叠系为例     

杨永泰  刘桂侠  刘海涛  傅国斌 《地层学杂志》2001,25(3):228-234

鄯科 1井是吐鲁番—哈密盆地台北凹陷首次钻穿三叠系的一口科学探索井 ,并首次在三叠系发现轻质油流。文内以鄯科 1井为例 ,运用孢粉组合、岩性组合、地震剖面、倾角测井、无机元素、地球化学等多种方法从不同侧面分析了鄯科 1井三叠系内部地层重复的现象 ,这些方法有机的结合和相互的补充打破了单一方法进行地层划分的旧模式 ,初步进行了多方法交互使用进行地质分层的尝试 ,从而有效地消除了地层划分与对比中的多解性 ,使地层划分更可靠 ,相信这些方法的交互使用在其他地区和单井的地层划分对比中也同样有较好的使用价值  相似文献   

环境矿物材料基本性能：无机界矿物天然自净化功能   总被引：53，自引：23，他引：53       下载免费PDF全文

鲁安怀 《岩石矿物学杂志》2001,20(4):371-381

重点阐述环境矿物材料基本性能，包括矿物表面吸附、孔道过滤、结构调整、离子交换、化学活性、物理效应、纳米效应及与生物交互作用等，旨在发掘、凝炼并新提出物理方法和化学方法之后与有机界生物同效的无机界矿物天然自净化功能的基础理论与应用方法，以发展和完善无机矿物与有机生物所共同构筑的自然界中存在的天然自净化系统，并就目前笔者在黄铁矿、锰钾矿、金红石、蛭石、蒙脱石、苋铁铁钒等天然矿物方面已经完成和正在开展的一系列环境矿物材料研究工作进行了举例说明。  相似文献   

Studies on Intercorrelation between Ions Co-Occurring in Precipitation in the Gdańsk-Sopot-Gdynia Tricity (Poland)     

Żaneta Polkowska  Aleksander Astel  Marzena Grynkiewicz  Tadeusz Górecki  Jacek Namieśnik 《Journal of Atmospheric Chemistry》2002,41(3):239-264

The paper presents monitoring results and environmental pollution assessment for the Gdask-Sopot-Gdynia Tricity (Poland), based onanalysis of precipitation. Precipitation samples were collected over a period of 12 months (January–December 1998) at ten locations in the Tricity. The following selected ions were determined in the samples:SO₄ ^2–, F^–, Cl^–, NO₃ ^–,PO₄ ^3–, NH₄ ⁺, Na⁺,Mg²⁺, Ca²⁺, K⁺. The results were subjected to full statistical evaluation. Values of the parameters determined were correlated with each other. An attempt was made to explain co-occurrences of certain ions and the significance of their mutual effects. Pollutant concentrations and loads in precipitation were also correlated with data on wind direction and temperature in the region.Deposition of pollutants was very high in spring due to the prevailing air circulation patterns and low temperatures. Analysis of the correlations between co-occurring ions confirmed the significant impact of the location (sea coast) on the composition of rain water. Ionic ratios in rainwater were similar to those observed for sea salt samples. In addition, heavy traffic was most probably responsible for high concentrations of various forms of nitrogen and sulphates in the vicinity of major highways.  相似文献   

融入WTO——为农业服务的化工矿产资源发展战略构想     

姜树叶  王炳铨  王君 《化工矿产地质》2002,24(4):193-197

我国直接为农业服务的磷、硫、钾矿资源总体形势不容乐观。针对各自资源特点,应采取不同的发展战略:磷——立足国内,有进有出,南出北进;硫——立足国内,适当进口,调整结构,必要储备;钾——稳定进口,国外开发,国内开发,国内找矿,四位一体,分三步走。为此建议:将磷、硫、钾纳入战略性矿产资源的范畴进行管理和规划;强化地勘队伍,加大找矿力度;增加投入,寻求新的突破;加大“走出去”的步伐;规范进出口秩序;国家在更高的层面进行宏观调控;拓宽为农业服务的新领域。  相似文献   

Historical trophic evolutions and their ecological responses from shallow lakes in the middle and lower reaches of the Yangtze River: Case studies on Longgan Lake and Taibai Lake     

YANG Xiangdong  SHEN Ji  DONG Xuhui  LIU Enfeng  WANG Sumin 《中国科学D辑(英文版)》2006,49(Z1)

The evolutions of diatom floras and the total phosphorous (TP) concentrations in the historical period were reconstructed for two lakes, Longgan and Taibai in the middle Yangtze River,based on high resolutional fossil diatom study from two sediment cores and an established regional diatom-TP transfer function. The TP concentration in Longgan Lake changed slightly in the range of 36-62 μg/L and kept its middle trophic level in the past 200 years. The changes of diatom assemblages reflect a macrophyte-dominated history of the lake. During the nineteenth century, the lake TP concentration increased comparatively, corresponding to the increase in abundance of benthic diatoms. The progressive increase of epiphytic diatoms since the onset of the twentieth century indicates the development of aquatic plants, coinciding with the twice drops of water TP level. The TP concentration in Taibai Lake kept a stable status about 50 μg/L before 1953 AD, while diatoms dominated by facultative planktonic Aulacoseira granulata shifted quickly to epiphytic diatom species, indicating a rapid expansion of aquatic vegetation. During 1953-1970 AD, the coverage of aquatic plants decreased greatly inferred by the low abundance of epiphytic diatoms as well as declined planktonic types, and the reconstructed TP concentration shows an obvious rising trend firstly, suggesting the beginning of the lake eutrophication. The lake was in the eutrophic condition after 1970, coinciding with the successive increase of planktonic diatoms. The comparison of the two lakes suggests the internal adjustment and purification function of aquatic plants for nutrients in water. The discrepancy of TP trends in the two lakes after 1960 reflects two different patterns of lake environmental response to human disturbance. Sediments in Taibai Lake clearly recorded the process of lake ecological transformation from the macrophyte-dominated stage to the algae-dominated stage. The limits of TP concentration (68-118 μg/L) in the transitional state can be considered as the critical value between the two stable ecosystems. Further work will be necessary to provide more evidence from the sediments in more eutrophic lakes for the primary inference. The reconstructive TP level and the inference of aquatic plants from fossil diatoms in different lakes, as well as their comparison provide a scientific basis for ecological restoration of eutrophic lakes in research regions.  相似文献   

微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷   总被引：1，自引：1，他引：1  

马名扬张丽佳  张朝阳毕鸿亮李幼菊  卢普相 《岩矿测试》2007,26(5):372-376

建立了微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷的分析方法。用正交试验设计结合单因素试验优化了样品粒度、提取温度、提取时间、固液比等微波提取条件，研究了共存离子对无机砷测定的干扰情况。方法的线性范围为0．25～40．0μg/g，无机砷的检出限为0．05μg/g，样品加标回收率为92．9％～105．0％。方法的精密度（RSD，n=11）为0．3％。与水浴提取法相比，微波辅助提取法具有快速、高效的优势。方法已用于分析3个不同产地有代表性土壤中无机砷含量。  相似文献   

Inorganic arsenic speciation in the waters of the Penzé estuary (NW France): Seasonal variations and fluxes to the coastal area     

Jennifer Vandenhecke  Matthieu Waeles  Jean-Yves Cabon  Cédric Garnier  Ricardo D. Riso 《Estuarine, Coastal and Shelf Science》2010

Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux.  相似文献   

Denitrification in Qi''ao Island coastal zone, the Zhujiang Estuary in China   总被引：1，自引：0，他引：1  

WANG Hu  ZHOU Huaiyang  PENG Xiaotong  YANG Qunhui  QIN Chaomei  YIN Xijie  CHEN Guangqian 《海洋学报(英文版)》2009,28(1):37-46

Samples of sediments and the overlying water were collected in the Qi'ao Island coastal zone, the Zhujiang (Pearl River) Estuary (ZE). Denitrification rates, sediment oxygen demand (SOD) , and fluxes of inorganic nitrogen compounds were investigated with N2 flux method, using a self-designed continuous flow through and auto-sampling system. The results indicate that the denitrification rates varied between 222 and 908 μmol/(m2·h) with an average of 499 μmol/(m2·h). During incubation, the sediments absorbed dissolved oxygen in the overlying water with SOD ranging from 300 to 2 363 μmol/(m2·h). The denitrification rates were highly correlated with the SOD (r2 =0.77) regardless of the NO3- + NO2- concentrations in the overlying water, organ- ic carbon contents in sediments and water temperature, suggesting that the SOD was probably the main environ-mental factor controlling the denitrification in the Qi'ao Island coastal zone. There was a net flux of NO3- + NO2-into the sediments from the overlying water. The NH4+ flux from sediments into water as the result of mineraliza-tion was between 12. 3 and 210. 3 μmol/(m2·h) ,which seems limited by both organic carbon content in sedi-ment and dissolved oxygen concentration in the overlying water.  相似文献   

春季水华对南黄海总溶解态无机砷生物地球化学行为的影响   总被引：1，自引：0，他引：1  

孙友旭  任景玲  刘素美  刘诚刚 《海洋学报》2015,37(4):16-27

利用氢化物发生-原子荧光光谱法(HG-AFS)对2007年3月30日至4月23日南黄海海域总溶解态无机砷(TDIAs,[TDIAs]=[As5+]+[As3+])的含量进行了测定,其中针对水华中心区域(BM1站)进行了25h的连续观测,以探讨春季水华对有毒类金属元素砷的生物地球化学行为的影响。结果表明,TDIAs的浓度范围为7.9~22.3nmol/L,平均值为(17.8±1.9)nmol/L。TDIAs在南黄海的分布主要表现为由近岸向外海逐渐升高的趋势,最大值出现在南部海域底层海水中。近岸海域表、底层TDIAs的含量相当,而中、南部海域由于存在明显的密度跃层,表、底层TDIAs的浓度具有显著性差异。2007年3月31日至4月1日研究区域西南部受到沙尘天气和降雨的影响,表层海水中TDIAs的含量显著升高。研究区域中、南部海域在观测期间暴发了典型的黄海春季水华,通过大面观测和对重点区域的连续观测可以发现,水华期间TDIAs的分布和磷酸盐类似,与Chl a呈现出较好的负相关关系(r=0.51,P0.05,n=39)。经初步计算,浮游植物水华对10m以上表层水体中TDIAs的清除量约为2.4nmol/L,占表层保有量的15%左右。通过箱式模型计算得出黄海TDIAs的停留时间约为(18.2±8.5)a,远远低于大洋。通过对该海域砷、磷摩尔比值的计算可以发现,南黄海砷、磷摩尔比值约为大洋中的20倍左右,这可能会引起浮游生物对砷酸盐的大量吸收和转化,从而带来潜在的生态危机,需要引起足够的重视。  相似文献