移极旋转坐标系中的大气动力学方程     

刘金达 《大气科学》1996,20(2):181-187

本文仅研究无粘、无地形和绝热运动假定下的大气动力学问题，用分析力学的方法求得了固定在地球上的移极旋转坐标系， 如直角坐标系， 球坐标系和柱坐标系中的第二类 Lagrange方程。从而求得普遍的大气动力学方程。所谓的视示力 —— Coriolis力和离心力 —— 与其它各种力统一处理。当地球自转轴不为坐标系的z轴时，不存在大气运动的对称和反对称性。特别值得提出的是以往很多学者利用柱坐标系来数值模拟台风(飓风)的轴对称和非轴对称性时所使用的基本方程是含糊的， 本文给出了准确的基本方程。  相似文献   

Precipitation of Fe and Al compounds from the acid mine waters in the dogyae area, Korea: A qualitative measure of equilibrium modeling applicability and neutralization capacity?     

Jae-Young Yu 《Aquatic Geochemistry》1996,2(1):81-105

To investigate the applicability of equilibrium modeling for the estimation of the chemical changes of acid mine waters, the phases predicted to precipitate by equilibrium calculation were compared with what actually precipitates from the stream and acid mine waters in the Dogyae area, Korea. The computer program MINTEQA2 was used for the equilibrium calculations based on the chemical compositional data of the water samples collected in the study area. XRD, IR, thermal and chemical analyses of the collected precipitates were performed to identify their phases.The results of the identification of the collected precipitates are inconsistent with what the equilibrium calculations predict. The equilibrium calculations indicate that ferrihydrite, FeOHSO₄, gibbsite, and AlOHSO₄ should precipitate from the stream and acid mine waters in the study area. However, the experimental analyses show that only ferrihydrite and Al₄(OH)₁₀SO₄ are the recognizable precipitates on the bottom of the stream and mine drainage channels. Comparing the stability relations among the possible precipitates with the field occurrence of the precipitates in the study area suggests that FeOHSO₄ and AIOHSO₄ are kinetically inhibited to precipitate and metastable ferrihydrite and Al₄(OH)₁₀SO₄ appear in their stability field instead. It indicates that the chemical compositional change of the waters due to the solid phase precipitation in the study area must be interpreted and predicted in terms of the precipitation of not the phases predicted by the equilibrium calculation but the actually identified ones.Assuming that the dissolved species in the aqueous phase are in equilibrium with respect to the currently precipitating solid phases in the study area, the water chemistries are attempted to interpret based on the plot of the theoretically calculated activities of the dissolved species on the stability diagram for the identified precipitates and gibbsite. The plot reveals a few evolution paths of the chemical composition of the acid mine water as the acid generation and neutralization progress. The evolution path producing ferrihydrite and then Al₄(OH)₁₀SO₄ precipitation suggests that the system including acid producing pyrite has lost significant amounts of its neutralizing capacity and thus, become intolerable to the impacts from acid mine water.  相似文献   

利用近地表化探资料研究油气藏的保存条件及埋藏深度     

许卫平  郭旭升  孙剑  陈柱泽 《物探与化探》1996,20(2):99-103

利用地面化探资料能够有效地圈定出化探异常,指出烃类垂向运移发生的范围。但对于油、气勘探的需要,这仅仅是最基本的,是远远不够的。本文通过对垂向化探资料及地面游离烃化探资料的分析,对利用地化动力学指标判断油、气藏的保存条件及埋藏深度进行了初步的探讨。  相似文献   

Turbulent kinetic energy budgets from a large-eddy simulation of airflow above and within a forest canopy   总被引：3，自引：2，他引：3  

Michael J. Dwyer  Edward G. Patton  Roger H. Shaw 《Boundary-Layer Meteorology》1997,84(1):23-43

The output of a large-eddy simulation was used to study the terms ofthe turbulent kinetic energy (TKE) budget for the air layers above andwithin a forest. The computation created a three-dimensional,time-dependent simulation of the airflow, in which the lowest third ofthe domain was occupied by drag elements and heat sources to representthe forest. Shear production was a principal source of TKE in theupper canopy, diminishing gradually above tree-top height and moresharply with depth in the canopy. The transfer of energy to subgridscales (dissipation) was the main sink in the upper part of the domainbut diminished rapidly with depth in the canopy. Removal ofresolved-scale TKE due to canopy drag was extremely important,occurring primarily in the upper half of the forest where the foliagedensity was large. Turbulent transport showed a loss at the canopytop and a gain within the canopy. These general features have beenfound elsewhere but uncertainty remains concerning the effects ofpressure transport. In the present work, pressure was calculateddirectly, allowing us to compute the pressure diffusion term. Wellabove the canopy, pressure transport was smaller than, and opposite insign to, the turbulent transport term. Near the canopy top andbelow, pressure transport acted in concert with turbulent transport toexport TKE from the region immediately above and within the uppercrown, and to provide turbulent energy for the lower parts of theforest. In combination, the transport terms accounted for over half ofthe TKE loss near the canopy top, and in the lowest two-thirds of thecanopy the transport terms were the dominant source terms in thebudget. Moreover, the pressure transport was the largest source ofturbulent kinetic energy in the lowest levels of the canopy, beingparticularly strong under convective conditions. These resultsindicate that pressure transport is important in the plant canopyturbulent kinetic energy budget, especially in the lowest portion ofthe stand, where it acts as the major driving force for turbulentmotions.  相似文献   

LIDAR DETERMINATION OF THE ENTRAINMENT ZONE THICKNESS AT THE TOP OF THE UNSTABLE MARINE ATMOSPHERIC BOUNDARY LAYER   总被引：10，自引：0，他引：10  

CYRILLE FLAMANT  JACQUES PELON  PIERRE H. FLAMANT  PIERRE DURAND 《Boundary-Layer Meteorology》1997,83(2):247-284

The thickness of the entrainment zone at the top of the marine atmosphericboundary layer (MABL) has been documented by an airborne lidar on twoconsecutive days during a cold-air outbreak episode over the Mediterranean.In addition to the lidar observations, in situ turbulent flux measurementsat three levels in the MABL were made by a second aircraft. The flights' tracksare broken down in segments 25–30 km long and the data are filtered for theparametrization of turbulent entrainment in the MABL at scales smaller thana few kilometres. The structural parameters of the entrainment zone aredetermined by lidar from the distributions of the instantaneous MABL topheight. The average values Ph0 and Ph2 of the cumulativeprobability distributions are used to define the bottom and top heights of the entrainment zone h0 and h2, respectively. The parameters h0 andh2 are calculated by reference to a linear vertical buoyancy flux profilein the framework of a first-order jump model. The model is constrained by bothlidar and in situ data to determine Ph0 and Ph2 and so h0and h2. In unstable conditions theaverage fraction Ph0 is estimated to be 6.0 ± 1%. It is shown to beslightly sensitive to the presence of cloud at small cloud fractions.The mean value of the ratio of the inversion level buoyancy flux to the surfacebuoyancy flux ARv is found to range from 0.15 to 0.30 depending on the shearin the MABL. The average value is 0.22 ± 0.05. Our resultsare in good agreement with previous analysis at comparable spatial scales.In purely convective conditions, the value of ARv given by theparametrizations fitted to our results is about 0.10–0.12, a value smallerthan the commonly accepted value of 0.2. When compared to previousparametrization results, our proportionality constant for the mechanicalproduction of turbulent kinetic energy is also found to be scaled down, ingood agreement with large-eddy simulation results. It is suggestedthat mesoscale organized motions in the MABL is the source of thisdifference.  相似文献   

Kinetics of the reactions of hydroxyl radicals with alkyl nitrates and with some oxygen-containing organic compounds studied under simulated atmospheric conditions   总被引：1，自引：0，他引：1  

J. Alistair Kerr  David W. Stocker 《Journal of Atmospheric Chemistry》1986,4(2):253-262

Rate constants have been measured for the reactions of hydroxyl radicals with alkyl nitrates and with some oxygen-containing organic compounds by a competitive technique. Mixtures of synthetic air containing a few ppm of nitrous acid, ethylene and the organic substrate were photolysed in a Teflon bag smog chamber. Based on the value k _HO+C2H₄}=8.1×10^-12 cm³ molecule^-1 s^-1 the following rate constants were obtained for the hydroxyl radical reactions at 750 Torr and at 303 K in units of 10^-12 cm³ molecule^-1: CH₃ONO₂, 0.37±0.09; C₂H₅ONO₂, 0.48±0.20; n-C₃H₇ONO₂, 0.70±0.22; C₂H₅OH, 3.6±0.4; CH₃COCH₃, 0.26±0.08; CH₃CO₂ i-C₃H₇, 3.0±0.8; CH₃CO₂ n-C₃H₇, 2.4±0.2. The results are discussed in relation to the available literature data and the implications of the results are considered in terms of the smog reactivity of these molecules.  相似文献   

化学动力学在地球化学中的某些应用   总被引：2，自引：0，他引：2  

Shi Pingfang Yu Chongwen 《地球科学》1986,(4)

化学动力学在地球化学（特别是成矿作用地球化学）研究中有极其重要的作用,其主要应用包括七个方面。本文重点介绍了地球化学中化学动力学的实验研究方法以及碳酸盐、硅酸盐、氧化物和硫化物等矿物的反应动力学实验成果;介绍了Helgeson的质量迁移理论及其研究热液在围岩中的运移方面的应用,并在热力学性质和动力学行为两方面研究了围岩的离解作用、蚀变作用与矿化作用及其相互关系。  相似文献   

The NO2-O3 system at sub-ppm concentrations: Influence of temperature and relative humidity     

P. W. C. Verhees  E. H. Adema 《Journal of Atmospheric Chemistry》1985,2(4):387-403

The stoichiometry and kinetics of the reaction of NO₂ with O₃ at sub-ppm concentration level have been investigated as a function of temperature and relative humidity. The experiments were performed in a continuous flow reactor using chemiluminescent and wet chemical methods of analysis.The rate constant found can be described by the Arrhenius expression: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikaiaaik% dacaGGUaGaaGyoaiaaiEdacqGHXcqScaaIWaGaaiOlaiaaigdacaaI% 0aGaaiykaiabgEna0kaaigdacaaIWaWaaWbaaSqabeaacqGHsislca% aIXaGaaG4maaaakiaabwgacaqG4bGaaeiCaiaacIcadaWcgaqaaiaa% cIcacqGHsislcaaIYaGaaGOnaiaaikdacaaIWaGaeyySaeRaaGyoai% aaicdacaGGPaaabaGaamivaiaacMcacaqGGaGaae4yaiaab2gadaah% aaWcbeqaaiaabodaaaGccaqGGaWaaSGbaeaacaqGTbGaae4BaiaabY% gacaqGLbGaae4yaiaabwhacaqGSbGaaeyzamaaCaaaleqabaGaaeyl% aiaabgdaaaaakeaacaqGZbWaaWbaaSqabeaacaqGTaGaaeymaaaaaa% aaaaaa!62A3!\[(2.97 \pm 0.14) \times 10^{ - 13} {\text{exp}}({{( - 2620 \pm 90)} \mathord{\left/ {\vphantom {{( - 2620 \pm 90)} {T){\text{ cm}}^{\text{3}} {\text{ }}{{{\text{molecule}}^{{\text{ - 1}}} } \mathord{\left/ {\vphantom {{{\text{molecule}}^{{\text{ - 1}}} } {{\text{s}}^{{\text{ - 1}}} }}} \right. \kern-\nulldelimiterspace} {{\text{s}}^{{\text{ - 1}}} }}}}} \right. \kern-\nulldelimiterspace} {T){\text{ cm}}^{\text{3}} {\text{ }}{{{\text{molecule}}^{{\text{ - 1}}} } \mathord{\left/ {\vphantom {{{\text{molecule}}^{{\text{ - 1}}} } {{\text{s}}^{{\text{ - 1}}} }}} \right. \kern-\nulldelimiterspace} {{\text{s}}^{{\text{ - 1}}} }}}}\] and are independent of the relative humidity. As commonly encountered in previous studies a lower-than-two reaction stoichiometry is observed.Heterogeneous reactions occurring at the reactor wall seem to be essential in the reaction mechanism. The NO₃ wall conversion to NO₂ and the N₂O₅ wall scavenging in the presence of H₂O are suggested to account for the observed stoichiometric factors.  相似文献   

A Breadth Averaged Numerical Model for Suspended Sediment Transport in Hooghly Estuary,East Coast of India   总被引：2，自引：0，他引：2  

Sinha  P. C.  Guliani  Pragya  Jena  G. K.  Rao  A. D.  Dube  S. K.  Chatterjee  A. K.  Murty  Tad 《Natural Hazards》2004,32(2):239-255

Sedimentation is of vital concern in the conservation, development and utilization ofour soil and water resources. The suspended sediment in estuarine waters is hazardousto navigation in estuaries, which have important ports and harbours. A breadth-averagednumerical model to study circulation and sediment transport is presented in this paper.The model is applied to Hooghly estuary, along the east coast of India. The model is fullynon-linear and uses a semi-explicit finite difference scheme to solve mass, momentum andadvection diffusion equation for suspended sediments in a vertical plane. The erosion anddeposition have been computed by empirically developed source and sink terms in thesuspended sediment equation.  相似文献   

Comparaison d'extractions séquentielles et cinétiques pour la spéciation de As dans des sols sableux contaminés     

Sophie Cornu  David Montagne  Pierre Conil 《Comptes Rendus Geoscience》2004,336(11):1007-1015

We compared the results obtained by sequential extraction combined with physical fractionation to those obtained by kinetics for As speciation in slightly polluted soils through irrigation. The soil samples were sieved through a 50-μm mesh. Particulate organic matter was manually sorted and joined to the less than 50-μm fractions. This last fraction was sequentially extracted with phosphates, NaOH and hydroxylamine + acetic acid at 90 °C. Kinetic extractions by EDTA were also performed on whole samples. Results show that As originating from irrigation was rather mobile. The different compartments defined by the sequential extraction were in agreement with those defines by kinetics. To cite this article: S. Cornu et al., C. R. Geoscience 336 (2004).  相似文献