滇东南含锰建造沉积相及聚锰条件分析     

李志群  梁秋原  刘文佳  陈明伟  邹云达  郑荣华  郭欣 《地球学报》2013,34(S1):17-24

在对滇东南区域地质及锰矿研究成果综合分析的基础上, 以中三叠世拉丁期含锰建造的沉积相研究为基础, 把滇东南的法郎组中的锰矿总结为碎屑岩建造中的斗南式锰矿和碳酸盐岩建造中的白显式锰矿两类, 从解析典型锰矿床的沉积格局入手, 研究了中三叠世拉丁期典型矿床的岩相古地理特征。斗南锰矿形成于礁(滩)后泻湖的滨浅海碎屑岩建造相区、台地碳酸盐建造相区和斜坡碎屑岩建造相区中, 在斜坡碎屑岩建造相内多具有异地堆积的重力流沉积。白显锰矿形成于局限台地水体较为滞流的泻湖相-潮坪相中。在不同沉积格架下, 海水物理化学条件、水动力环境、生物作用和同生断裂活动是影响聚锰作用的重要因素。  相似文献   

铁锰氧化物在污染土壤修复中的作用   总被引：22，自引：0，他引：22  

汤艳杰  贾建业  谢先德 《地球科学进展》2002,17(4):557-564

矿物学在环境科学中的应用将是21世纪矿物学研究的一个主要方面。土壤污染作为一个制约人类社会可持续发展的基本问题正受到日益广泛的关注，污染土壤的修复已成为环境科学研究的一个重点。污染土壤的修复技术主要有物理、化学、生物等方法，但是，它们都不同程度地存在着缺陷。众所周知，铁和锰是自然界中少数但常见的变价元素。含有变价元素和带有表面电荷的铁锰氧化物具有良好的表面活性，不仅对有毒有害的无机污染物具有良好的净化功能，而且对土壤中有机污染物具有氧化降解作用。利用这些矿物来修复污染土壤，具有成本低、无二次污染等优点，体现出天然净化作用的特色，展现出广阔的环境矿物学应用前景。  相似文献   

初论发现于西太平洋富钴结壳的羟锰矿     

赵磊  田川  杨华  王丽娟  方念乔 《现代地质》2007,21(2):371-375

大多数研究者认为富钴结壳中的锰矿物主要是水羟锰矿。X-射线衍射数据表明这次所研究的富钴结壳中主要的富锰矿物相是羟锰矿,这是在以往的结核和结壳研究中鲜为人知。探讨了羟锰矿和水羟锰矿的名称由来、化学式、晶胞参数及X射线粉晶衍射值,建议将X-射线衍射特征值为2.4×10^-10 m和1.4×10^-10 m的锰矿物相统称为水羟锰矿;通过研究这两种矿物的成因、产状及环境,认为结壳中羟锰矿的存在表明结壳在生长中后阶段仍处于还原环境。  相似文献   

生物结皮恢复过程中土壤生态因子分异特征   总被引：19，自引：14，他引：5  

吴楠  张元明  张静  王红玲  聂华丽  陈荣毅 《中国沙漠》2007,27(3):397-404

对新疆古尔班通古特沙漠生物结皮恢复过程中土壤因子的动态变化进行关联性测度、方差分析、相关性分析相结合的定量研究,着重分析结皮恢复年限对土壤微生物数量、养分、盐分、土壤酶的影响,有机质与土壤盐分、pH值、土壤酶的线性关系及土壤生态因子间的相关性。结果表明：相对于土层深度,有机养分、土壤酶等生态因子与生物结皮恢复年限的联系更加紧密。结皮恢复年限对全P、全K、有机质、脲酶、真菌的影响极显著（P<0.01）;对速效P、速效K、全N、总盐、中性碱性磷酸酶、蛋白酶的影响显著(P<0.05)。随结皮恢复年限的增加,结皮层和结皮以下土层中有机养分、土壤酶均有不同程度的增加,逐步具备较高的生物学活性,沙土性状变化较快,渐渐形成抗风蚀、抗干扰能力较强的地衣苔藓结皮。结皮恢复过程中pH值与有机质呈显著线性负相关（R2＝0.701,P<0.05）,土壤盐分与有机质存在线性正相关（R2＝0.653）,但显著性不强（P>0.05）。电导率、脲酶、碱性磷酸酶、中性磷酸酶、蛋白酶与有机质存在极为显著的线性正相关（R2分别为0.888、0.993、0.958、0.948、0.911,P<0.01）,土壤生态因子的协调发展和紧密配合促进了生物结皮的恢复。  相似文献   

Experimental Study of Gold and Platinum Solubility in a Complex Fluid under Hydrothermal Conditions   总被引：2，自引：0，他引：2  

G. G. LIKHOIDOV  L. P. PLYUSNINA  J. A. SCHEKA  T. B. APHANAS EVA 《Resource Geology》2000,50(2):83-92

Abstract: The solubility of gold was studied in water and aqueous NaCl (1– 5 m) solutions under oxygen and sulfur buffered conditions between 300–500C at a constant pressure 1 kb. Two buffer assemblages HMP and PPM were used. Analysis of the scatter in measured values in log m_Au–m_NaCl–T frame fixed linear dependence between log m_Au and T at any studied iso‐pleth (m_NaCl) in the form of log m_Au = a. T(C) + b. Coefficients of the equation were calculated for water and NaCl (1, 3, 5 m) solutions. The maximum solubility characterizes the NaCl‐free system in the presence of HMP. In the case, Au solubility increases from (log m_Au) –6. 72 to –5. 04 at 300 and 500C, respectively. In the presence of PPM, maximum of Au solubility was obtained for the 5 mNaCl solution. In a similar manner solubility rises from –6. 54 to –5. 77 at 300 and 500C, accordingly. In studied f_O2/f_S2 area the behavior of Au solubility testified that: (i) – a composite interaction between chloride and hydrosulfide speciation of gold affects its total solubility; (ii) – in addition of NaCl up to about 1. 5 m the solubility decreases, more pronounced in the presence of HMP; (iii) – the contribution of chloride in total Au solubility is more for PPM despite of lower f_O2value, than for HMP. The solubility of platinum was studied in the Pt–Cl–S–H₂O system between 300 and 500C, 1 kb. PPM solid buffer controlled oxidation state, pH and sulfur activity of solutions (H₂O, 1 mNaCl and 0. 1 mHCl). Under the conditions, PtS precipitated from the solutions with increasing temperature and acidity. The PtS solubility in the 0. 1 m_HCl solutions lowers slightly in the range of 300–500C from –5. 30 to –5. 60 (in log m_Pt) that is typical to the hydrosulfide species. It was deduced that reducing media, regulated by the PPM assemblage, suppress activity of chloride species of Pt. More oxidizing conditions were modeled in runs using mixtures of Mn(II), Mn(III) and Mn(IV) oxides to buffer the aqueous‐chloride solutions between 300 and 500C, 1 kb. It was found that MnO tends to oxidize at T below 400C forming intermediate Mn‐hydroxides (β–MnOOH, Mn (OH)₂ and Mn₂(OH)₃Cl). These phases are metastable and transfer to Mn₃O₄ with increasing duration. Generation of the Mn‐hydroxides leads to a change of physical‐chemical parameters of the solutions, such as water activity, pH and Eh. The last results in abrupt increase in the noble metals dissolution. At stable existence of only Mn₃O₄, the solubility of both Pt and Au lowers to equilibrium values. Essential catalysis effect of Pt on intensity and rate of Mn(II) oxidation was found. The dominant role of chloride of Pt and Au was defined under most oxidized conditions, specified by Mn₂O₃–MnO₂ buffer. So at 400C, dissolved Au (log m_Au) increases from –4. 40 in water to –1. 00 in 0. 1 m_HCl, and ones of Pt (log m_Pt) from –4. 80 to –2. 90 accordingly. Thus, mixing of hydrosulfide and chloride solutions, as well as transformation of the systems to the stable state act upon total solubility of the noble metals.  相似文献   

Distribution and Classification of Cobalt-Rich Crust     

Liang Dehua Zhu Benduo Guangzhou Marine Geological Survey  Guangzhou 《中国地质大学学报(英文版)》2000,11(2)

INTRODUTIONThe sea- floor metallic mineral resources are classified asmany types such as multi- m etallic nodules,metallic oozes,massive sulfide deposits and iron- manganese crusts.Before1980 s,China did not made any researches into metallic oozeand massive sulfide deposits;but China started to study m ul-ti- metallic nodules in the early1980 s,15 - 2 0 years later thanthe developed industry countries did.However,in the shortten years,we have caught up with the developed countries,and our…  相似文献   

西太平洋维嘉海山埋藏型富钴结壳生长速率初步研究     

赵斌  何高文  马维林 《地质论评》2024,70(S1):101-103

  相似文献   

A numerical survey of neutron star crustal density profiles     

B. Datta  A. V. Thampan  D. Bhattacharya 《Journal of Astrophysics and Astronomy》1995,16(3-4):375-391

An accurate numerical survey of the density profiles corresponding to the crusts of neutron stars for representative equation of state models is presented. This will find application in calculations of thermal and magnetic evolution of neutron stars.  相似文献   

A Simple Kinetic Model for Autoxidation of S(IV) Oxides Catalyzed by Iron and/or Manganese Ions     

Irena Grgić  Gorazd Berčič 《Journal of Atmospheric Chemistry》2001,39(2):155-170

The reaction kinetics of S(IV) autoxidation catalyzed by single metal ions of Mn(II) and Fe(II) or Fe(III) and by a mixture of Mn(II) and Fe(II) under the conditions representative for acidified atmospheric liquid water was investigated. A simple power law kinetic model based on the stability constants for metal-sulfito complexes formed during the first step of a radical chain mechanism predicts well the kinetics for the reactions catalyzed by single metal ions. The calculated stability constants for iron (5.7×10³ dm³ mol^–1) and manganese (10×10⁴ dm³ mol^–1) sulfito complexes are close to those reported in the literature. The catalytic synergism between Mn(II) and Fe(II) was confirmed. For this system the following power law rate equation was suggested:r_tot = S_Fe · r_Fe + S_Mn · r_Mn ,where r_Fe and r_Mn are the reaction rates in the presence of Fe(II) and Mn(II), respectively. S_Fe and S_Mn are proportional factors, which account for the synergistic effect. The proposed power law rate equation predicts the reaction kinetics very well. The values of S_Fe (1.35) and S_Mn (15) indicate that the influence of Fe(II)/Fe(III) on Mn(II)/Mn(III) cycling is larger than, vice versa, agreeing with the reaction mechanism proposed for the S(IV) autoxidation catalyzed by mixed metal ions.  相似文献   

土壤铁锰结核中生命有关元素的化学地理特征   总被引：11，自引：1，他引：11  

李永华  王五一  谭文峰  刘凡 《地理研究》2001,20(5):609-615

研究了我国亚热带、暖温带几种土壤铁锰结核中锰矿物的类型,探讨了它们形成的地球化学过程与特征。结果表明:不同土壤铁锰结核锰矿物的类型及其含量不尽相同,但锂硬锰矿普遍存在且结晶程度较高;与土壤相比,土壤铁锰结核的化学组成仍以Si、Al、Fe为主,但Fe含量超过了Al,Mn含量远大于Mg、Ca;结核中一些重金属富集顺序为Pb>Co>Ni>Cu>Zn>Cr;揭示了土壤铁锰结核形成过程中存在着成核富集作用、成矿作用、专性吸附作用和轻度积钙作用。  相似文献