涂钨热解石墨管－石墨炉原子吸收法测定天然水中痕量钡   总被引：3，自引：0，他引：3  

何自蓂 《岩矿测试》1996,(2):97-103

选择涂钨热解石墨管测钡，克服了钡的碳化物形成而提高了方法的灵敏度，采用钙做基体补偿不仅克服钙对测钡的影响，同时也对测钡起增敏作用，结合其它测定条件的优化实现了石墨炉原子吸收法测定天然水中的痕量钡。其线性范围在０～７０μｇ／Ｌ检出限３．３ｐｇ，特征质量为２．９ｐｇ／１％吸收，对５μｇ／ＬＢａ试液测定１１次，其ＲＳＤ为６．９％，加标回收率８９％～１２０％。方法经标样分析验证，结果与标准值相符。  相似文献   

Transport in a 2-D saturated porous medium: A new method for particle tracking   总被引：2，自引：0，他引：2  

Frédérick Delay  Hélène Housset-Resche  Gilles Porel  Ghislain de Marsily 《Mathematical Geology》1996,28(1):45-71

A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed.  相似文献   

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Multifractal modeling and spatial statistics   总被引：9，自引：0，他引：9  

Qiuming Cheng  Frederik P. Agterberg 《Mathematical Geology》1996,28(1):1-16

In general, the multifractal model provides more information about measurements on spatial objects than a fractal model. It also results in mathematical equations for the covariance function and semivariogram in spatial statistics which are determined primarily by the second-order mass exponent. However, these equations can be approximated by power-law relations which are comparable directly to equations based on fractal modeling. The multifractal approach is used to describe the underlying spatial structure of De Wijs 's example of zinc values from a sphalerite-bearing quartz vein near Pulacayo, Bolivia. It is shown that these data are multifractal instead of fractal, and that the second-order mass exponent (=0.979±0.011 for the example) can be used in spatial statistical analysis.  相似文献   

超灵敏加速器质谱计测定^32Si样品制备新技术   总被引：1，自引：0，他引：1  

刘存富  王佩仪 《地质科技情报》1997,16(3):97-101

介绍了制备元素硅的一种化学方法，它可用于ＡＭＳ装置的离子源。含硅的物质溶解在ＨＦ中，用ＬｉＡｌＨ４把ＳｉＦ４还原成ＳｉＨ４，再将ＳｉＨ４加热分解成元素硅，并且沉淀在石墨盘上，用ＡＭＳ测定ｗ３２Ｓｉ／ｗＳｉ总比值，其灵敏度可达１０＾－１３。  相似文献   

裂隙岩体渗流与应力耦合的试验研究   总被引：16，自引：2，他引：16  

张玉卓  张金才 《岩土力学》1997,18(4):59-62

通过对较大尺寸的裂隙岩体试块进行不同侧压力和加载条件下的渗流试验结果研究，分析了裂隙岩体渗流与应力的耦合机理，得出了不同应力条件下裂隙岩体渗流量与应力成四次方的关系。并且得出并非压应力都引起裂隙岩体的渗流量减小，当裂隙岩体受平行于裂隙面方向的单向压应力时，渗流量随着压应力的增加而增加。  相似文献   

桩后劈裂压浆施工技术          下载免费PDF全文

陈振  何文生 《探矿工程》1997,(4):11-13

阐述了桩后劈裂压浆提高单桩承载力的机理、使用设备、操作方法工艺参数和操作注意事项，并对劈裂压浆的压入量及压力进行了初步探讨。  相似文献   

流体地质作用的构造效应   总被引：2，自引：1，他引：2  

赵志忠  邱亮斌 《大地构造与成矿学》1997,21(1):62-69

许多事实证明，在地壳及地球深部存在着大量的流体，它们以气体、液体、熔融体等形式存在于地球内部不同深度处。这些流体的活动在地壳及岩石圈运动演化过程中扮演着十分重要的角色，其作用贯穿于地壳与岩石圈运动演化的全过程，地球表面形成的各种构造与流体作用的参与有着密切的联系。  相似文献   

松江河电厂小山水电站导流洞出口边坡稳定性分析     

王振环  邢帼君 《吉林地质》1997,16(4):77-81

小山水电站导流洞出口边坡其地质结构为下部中侏罗世安山岩（αＪ２），其上覆盖了第三纪末第四纪初的玄武岩（βＮ～Ｑ），两者间为不整合接触，不整合面夹有０．１～０．６ｍ厚的粘土状及碎石粘土状夹层，产状倾向河床，倾角±２５°。在上覆玄武岩层中见有高倾角的宽张裂隙带，与不整合面一起构成松动岩体，不整合面为底滑面。通过边界条件的分析和稳定计算，松动岩体的抗滑系数Ｋ＝３．１０２，边坡是稳定的。在施工过程中采取了相应的安全保护措施，导流洞出口提前２８ｍ进洞，节约挖方量６００００ｍ３，提前了工期。经三年多的施工到运行，边坡无异常变化，表明该项优化设计是可行的。  相似文献   

山谷冰川稳定态时积累区面积比率研究     

王宁练  薄健辰 《冰川冻土》1997,19(2):167-172

探讨山谷冰川稳定状态时积累区面积比率，即ＡＡＲ值的大小，认为冰川物质平衡高程分布，平面形态及坡面坡度沿程变化形式是影响山谷冰川稳定态ＡＡＲ值的主要因素，并 山谷冰川稳定态ＡＡＲ值与物质平衡高程分布及平面形态之间的定量关系。山谷冰川适合于应用ＡＲ值法来研究古冰川的零平衡线高程。  相似文献