Toxic metals in Venice lagoon sediments: model,observation, and possible removal   总被引：1，自引：0，他引：1  

A. Basu  E. Molinaroli 《Environmental Geology》1994,24(3):203-216

We have modeled the distribution of nine toxic metals in the surface sediments from 163 stations in the Venice lagoon using published data. Three entrances from the Adriatic Sea control the circulation in the lagoon and divide it into three basins. We assume, for purposes of modeling, that Porto Marghera at the head of the Industrial Zone area is the single source of toxic metals in the Venice lagoon. In a standing body of lagoon water, concentration of pollutants at distancex from the source (C ₀) may be given byC=C ₀e^–kx wherek is the rate constant of dispersal. We calculatedk empirically using concentrations at the source, and those farthest from it, that is the end points of the lagoon. Averagek values (ppm/km) in the lagoon are: Zn 0.165, Cd 0.116, Hg 0.110, Cu 0.105, Co 0.072, Pb 0.058, Ni 0.008, Cr (0.011) and Fe (0.018 percent/km), and they have complex distributions. Given thek values, concentration at source (C ₀), and the distancex of any point in the lagoon from the source, we have calculated the model concentrations of the nine metals at each sampling station. Tides, currents, floor morphology, additional sources, and continued dumping perturb model distributions causing anomalies (observed minus model concentrations). Positive anomalies are found near the source, where continued dumping perturbs initial boundary conditions, and in areas of sluggish circulation. Negative anomalies are found in areas with strong currents that may flush sediments out of the lagoon. We have thus identified areas in the lagoon where higher rate of sediment removal and exchange may lessen pollution.  相似文献   

大兴安岭中南段金属矿床流体包裹体研究   总被引：10，自引：0，他引：10       下载免费PDF全文

盛继福  张德全 《地质学报》1995,69(1):56-66

作者通过在不同温度下对包裹体特征、相变行为的系统观察与测定，以及对包裹体气、液相成分的分析、获取了研究区内主要矿床成矿过程中成矿液体的温度、盐度、密度、流体成分、流体的沸腾现象、成矿压力以及ＰＨ，Ｅｈ，Ｆｏ２，还原参数等成矿的物理化学参数，从而为划分矿化蚀变阶段，矿床类型、成矿系列和深化对矿床成矿作用与成矿机制的认识提供了科学依据。尽管矿床属于不同的成矿系列，只要矿床类型相同，矿床的流体包裹体地球  相似文献   

The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi     

Chen Yuchuan  Mao Jinwen  Wang Ping''an Chinese Academy of Geological Sciences  Beijing Fei Zhenbi 《《地质学报》英文版》1995,69(2)

The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.  相似文献   

High resolution time series of lead and zinc in sediments of Lake Constance   总被引：3，自引：0，他引：3  

Martin Wessels  Angela Lenhard  Federico Giovanoli  Andreas Bollhöfer 《Aquatic Sciences - Research Across Boundaries》1995,57(4):291-304

Sediments in Lake Constance have been dated by radiometric methods and lamination counting. Investigations into the concentrations of lead and zinc in the sediments were carried out to get detailed information about environmental history. Maximum concentrations were found at the beginning of the 1960's. The lead maximum contamination occurred 3 years before the zinc maximum and has an unidentified source. The use of coal, leaded gasoline or the remobilization within the sediment could be excluded to result in the lead maximum. The fluctuations in zinc contamination could be explained with increasing and decreasing pollution (industry, coal burning, building of sewage plants). The greatest fluctuations of both metals occur during periods of great change in the economic history of Germany.  相似文献   

我国金属矿产成矿区带地球化学普查发展历史     

李幸凡 《矿产与地质》2005,19(6):592-598

二十世纪60～70年代是我国金属矿产成矿区带地球化学普查发展的初期阶段.1976年,成矿区带地球化学普查规划制订,我国金属矿产成矿区带地球化学普查进入大规模普查实施的第一阶段;随着一系列新技术规定的颁布执行,1992年开始进入第二阶段的成矿区带地球化学异常详细检查评价与综合研究;1993年以后,成矿区带地球化学普查与详查仍然以寻找金属矿产为主要任务,同时,成矿区带地球化学普查成果开始向应用地球化学方向发展,这标志着第三个阶段的开始,即应用成矿区带地球化学普查成果进行生态环境地球化学与人类健康、综合农林业地球化学研究和开发.  相似文献   

灌河口潮滩重金属累积特征及污染评价   总被引：6，自引：3，他引：6  

于文金  邹欣庆 《地球化学》2007,36(4):425-433

河口地区潮滩是重金属重要的"汇"。测定了灌河口(燕尾港)潮滩高中低滩的33个表面样粒度、重金属数据,研究了4根柱状样的重金属和粒度特征,利用地累积指数法、潜在生态危害指数法及富集指数法等评价指标,对灌河口重金属的污染状况进行了评价,并对其结果进行了相互比较和印证。分析结果显示,灌河口潮滩重金属的分布主要受水动力影响,特别是受粘土分布的控制。Cd与粒径Ф值相关性不显著,相关系数只有0.099,而与粘土含量呈明显正相关关系,Hg的变化趋势恰恰相反,其含量随着距离河口距离的加大反而有增加的趋势;其他元素的变化趋势不明显。重金属元素Zn、Pb、Cu、Hg含量变化走势基本相同,用Li作归一化标准元素归一化后,所有重金属元素的归一化值变化波动范围均比重金属含量值明显收窄,波峰和波谷有后延的趋势。灌河口滩涂总体重金属环境尚可,但存在一定程度的Hg、Cu污染富集。柱状样Hg、Cu的地累积污染指数总体上均呈现随深度增加而降低的趋势。  相似文献   

Potential hyperaccumulation of Pb, Zn, Cu and Cd in endurant plants distributed in an old smeltery, northeast China   总被引：1，自引：0，他引：1  

Shuang Cui  Qixing Zhou  Lei Chao 《Environmental Geology》2007,51(6):1043-1048

The absorption and accumulation of Pb, Zn, Cu and Cd in some endurant weed plant species that survived in an old smeltery in Liaoning, China, were systematically investigated. Potential hyperaccumulative characteristics of these species were also discussed. The results showed that metal accumulation in plants differed with species, tissues and metals. Endurant weed plants growing in this contaminated site exhibited high metal adaptability. Both the metal exclusion and detoxification tolerance strategies were involved in the species studied. Seven species for Pb and four species for Cd were satisfied for the concentration time level standard for hyperaccumulator. Considering translocation factor (TF) values, one species for Pb, seven species for Zn, two species for Cu and five species for Cd possessed the characteristic of hyperaccumulator. Particularly, Abutilon theophrasti Medic, exhibited strong accumulative ability to four heavy metals. Although enrichment coefficients of all samples were lesser than 1 and the absolute concentrations didn’t reach the standard, species mentioned above were primarily believed to be potential hyperaccumulators.  相似文献   

衡水湖湿地底泥重金属污染及潜在生态风险评价   总被引：11，自引：1，他引：11  

张曼胤  崔丽娟  盛连喜  王义飞 《湿地科学》2007,5(4):362-369

测定了衡水湖湿地20个采样点底泥中的7种重金属含量,并与环境背景值进行了比较。结果显示,衡水湖湿地底泥中的Hg含量普遍高于环境背景值,为衡水湖湿地底泥中主要富集的重金属元素,而Cr和Cd基本无富集。用地积累指数、某种重金属的潜在生态危害系数和多种重金属的潜在生态风险指数评价了各个采样点的污染程度和潜在生态风险。结果表明,Hg为高风险元素,底泥中重金属污染主要以Hg为主;衡水湖湖内大部分地区的潜在生态风险相对较低,综合潜在生态风险最高处为魏屯闸,然后依次为南关闸、106国道、大赵闸和湖内岛,核心区的综合潜在生态风险最小。另外,还对魏屯闸处的3个采样点的多种重金属的潜在生态风险指数值进行了讨论。  相似文献   

垃圾焚烧灰治理垃圾渗滤液重金属污染的试验研究     

侯晓龙  马祥庆 《亚热带资源与环境学报》2007,2(2):30-36

通过垃圾焚烧灰对模拟垃圾渗滤液重金属废水的正交吸附实验研究,并讨论其对重金属吸附的一般规律及pH、加入量和振荡时间几个影响因素对吸附效果的影响.研究结果表明:在一定的pH、加入量和振荡时间下,垃圾焚烧灰对Pb、Ni、Cd、Mn、Zn、Cr有一定的吸附效果,最大吸附率分别可以达到100%、84.18%、96.74%、93.52%、99%、81.69%.焚烧灰对重金属的吸附能力表现为Pb＞Mn＞Cd＞Zn＞Ni＞Cr.各影响因素对重金属吸附效率的影响大小顺序表现为pH＞加入量＞振荡时间,pH值对吸附率的影响最大,为主要影响因素.  相似文献   

The impact of hurricanes on sedimenting particulate matter in the semi-arid Bahía de La Paz,Gulf of California     

Norman Silverberg  Evgueni Shumilin  Fernando Aguirre-Bahena  Ana Patricia Rodríguez-Castañeda  Dmitry Sapozhnikov 《Continental Shelf Research》2007

From 2002 through 2004, time-series sediment trap samples were collected from a depth of 410 m in Cuenca Alfonso, Bahía de La Paz, on the SW coast of the Gulf of California. The instrument recorded the impact of the local passage of hurricanes “Ignacio” (24–26 August) and “Marty” (21–23 September) in 2003. These two events accounted for 82% of the total rainfall measured in 2003, equivalent to the annual average precipitation in years without hurricanes. Mean total mass fluxes (TMFs) of 2.88 and 3.58 g m⁻² d⁻¹ were measured during the week of each hurricane as well as the following week. This may have been enough to produce a lamina in the underlying sediment with characteristics peculiar to such events. The terrigenous component was particularly abundant, with notably higher concentrations of Fe, Sc, Co and Cs and REEs. In contrast, TMFs throughout 2002–2004 (excluding the hurricane periods) averaged only 0.73 g m⁻² d⁻¹ and had a larger marine biogenic component. The extraordinary elemental fluxes during the 29 days of hurricane-influenced sedimentation represented a great proportion of the totals over an entire “normal” year: Co (67.8%) >Sc (62.6) >Fe (59.6) >Cs (53.4)>Lu (51.5)>La (51.3)>Yb (51.0)>Ce (49.5) >Tb (48.4) >Sm (44.7)>Cr (36.5) >Ca (31.0)>Eu (25.4%). The terrigenous fraction was calculated using (a) TMF minus the sum of CaCO₃, biogenic silica and organic matter and (b) the ratio of Sc in the trap samples to the average in the Earth's crust. The latter was consistently smaller, but the two methods offered similar results following hurricanes (78% vs. 63%, respectively). For normal sedimentation, however, the difference method yielded values twice as large as the Sc method (58% vs. 30%) This suggests that the mineralogy of the terrigenous fraction may also vary, with unsorted dessert soil being carried to sea by the powerful flash floods associated with hurricanes. Eolian supply of particles, particularly Sc-free quartz grains, possibly from beyond the limited fluvial drainage basin, apparently dominates normal sedimentation.  相似文献