The thermal maturity of sedimentary basins as revealed by magnetic mineralogy     

Mansour M. Abdelmalak  Stéphane Polteau 《Basin Research》2020,32(6):1510-1531

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

金堆城钼矿石的物质组成及钼、铜、铅的赋存状态研究     

崔学奇  吕宪俊  周国华 《矿物岩石地球化学通报》1999,(4)

金堆城钼业公司是我国重要的钼业基地,选矿产品质量与国外同类产品相比还有差距,存在质量不稳定的因素,如１９９７～１９９８年间,钼精矿中铜、铅杂质含量超标,影响了产品的销售;钼回收率较低,造成矿产资源的浪费。因此,开展钼矿石工艺矿物学研究,查明现采矿石的物质组成,钼、铜、铅的赋存状态、主要矿物的嵌布特征等工艺矿物学特征,对于进一步优化选矿流程和工艺条件,提高产品质量是十分必要的。１　样品的采集与制备取样点按１００×１００ｍ的网度在采场各平盘掌子面的交叉点上布置,沿掌子面的坡底线取样,每个样点采集化学…  相似文献   

陕西省潼关县碾头岔含金石墨矿工艺矿物学研究   总被引：2，自引：0，他引：2  

温志坚  汤集刚 《铀矿地质》1999,15(1):27-34

工艺矿物学系统研究表明：碾头岔含金石墨矿床的矿石中除石墨外,可综合利用的有用元素还有金、铜等。金矿物颗粒较细,主要以独立矿物形式赋存于载体矿物黄铜矿、黄铁矿及石墨中。黄铜矿是主要的铜矿物,其次有蓝辉铜矿。石墨呈独立矿物存在,片大且较平直,属于大鳞片石墨,矿石中总碳仅有６５％左右以石墨碳形态存在。上述３种有用元素均可通过合理磨矿,选择适宜的选矿条件得到金精矿、铜精矿和石墨精矿。然而由于石墨精矿中杂质较多且颗粒细小,主要为极细的片状硅酸盐,要得到高品级石墨,用机械选矿办法是无能为力的,需要对精矿进一步加工处理方可奏效。  相似文献   

碱性玄武岩中幔源岩石包体内尖晶石成分特征及其岩石学成因意义   总被引：4，自引：2，他引：2  

董振信  陈立辉 《岩石学报》1999,15(4):607-615

通过对我国东部北起黑龙江省南至海南省３１个产地的新生代碱性玄武岩中橄榄岩类 （纯橄岩、方辉橄榄岩及二辉橄榄岩） 包体和辉石岩类包体中的１６０ 多个尖晶石电子探针分析数据, 论述了尖晶石的Ｃｒ－Ａｌ, Ｆｅ－Ｍｇ, Ｎｉ－Ｍｇ 主元素及有关比值和端员组分之间的关系, 分析研究了不同岩类包体中尖晶石的颜色、成分及成因之间的联系。并利用所分析的有关橄榄石、斜方辉石、单斜辉石共生矿物的电子探针分析数据, 采用新的、较合理的Ｂｒｅｙ－Ｋｏｈｌｅｒ温度计及Ｋｏｈｌｅｒ－Ｂｒｅｙ 压力计和Ｂａｌｌｈａｕｓ ｅｔａｌ． 氧逸度计算方法进行了计算, 探讨了尖晶石成分与其形成温度、压力和氧逸度状态的关系, 指出了尖晶石成分所反映的地幔亏损程度及部分熔融程度的变化规律及尖晶石 （相） 稳定的温度、压力和氧逸度范围。  相似文献   

伟晶岩绿柱石矿物学及其通道水氢同位素研究进展   总被引：4，自引：0，他引：4  

张辉  刘丛强  马英军 《矿物学报》1999,19(3):370-378

自然界绿柱石存在三个类质同象系列,即“八面体”绿柱石（ｃ／ａ＝０．９９１￣０．９９６）,“正常”绿柱石和“四面体”绿柱石。绿柱石矿物精细结构研究表明,二价离子置换八面体中Ａｌ,Ｌｉ置换四面体中Ｂｅ,而碱离子被绿柱石通道所容纳,用于补偿低价阳离子置换Ａｌ八面体和Ｂｅ四面体引起的电价不足。伟晶岩绿柱石通常含有〉１．６ｗｔ％的通道水,而包裹体中流体仅为０．１５ｗｔ％左右。室温下绿柱石通道中存在１型和Ⅱ  相似文献   

Preliminary study on weathering and pedogenesis of carbonate rock   总被引：23，自引：0，他引：23  

Shijie Wang  Hongbing Ji  Ziyuan Ouyang  Dequan Zhou  Leping Zhen  Tingyu Li 《中国科学D辑(英文版)》1999,42(6):572-581

South China is the largest continuous distribution area of carbonate rock in the world. The origin of the soils over the bedrock carbonate rock has long been a controversial topic. Here further exploration is made by taking five soil profiles as examples, which are developed over the bedrock dolomitite and limestone and morphologically located in upland in karst terrain in the central, west and north Guizhou as well as west Hunan, and proved to be the weathering profiles of carbonate rock by the research results of acid-dissolved extraction experiment of bedrock, mineralogy and trace element geochemistry. Field, mineralogical and trace element geochemical characteristics of weathering and pedogenesis for carbonate rock are discussed in detail. It is pointed out that weathering and pedogenesis of carbonate rock are important pedogenetic mechanisms for soil resources in karst area, providing a basis for further researches on the origin of soils widely overlying bedrock carbonate rocks in South China. Project supported by the National Natural Science Foundation of China (Grant No. 498330003) and National Key Basic Research Project (Grant No. 95pre-39).  相似文献   

Anatomically preserved plants in siderite concretions in the shale split of the Foord Seam: mineralogy, geochemistry, genesis (Upper Carboniferous, Canada)     

Erwin L. Zodrow  Christopher J. Cleal 《International Journal of Coal Geology》1999,41(4):248

A shale split in the well-studied Foord Seam (Upper Carboniferous), Stellarton Basin, Nova Scotia, provides a rare opportunity to study little known siderite concretions with anatomically preserved plants from a limnic basin. Siderite concretions occur throughout the split, commonly as sheet-like, inter-connected lepidodendrid logs, or less frequently as spherical masses; they are typically vuggy. A sample of 14 stratigraphically oriented concretions in the split shows that primary siderite varies from 45% to 80% (wt.%) due to selective replacement by 5% to 40% ferroan dolomite or ankerite in plant tissues. These two minerals show large Mg/Fe and Mg/Ca variability and are Fezoned. Clay content ranges from trace to 20%, and quartz from 5% to 10%. Partial cell-wall destruction by erosion and changeable oxic/anoxic conditions, prior to siderite permineralization, resulted in preservation mainly of the more resistant plant tissues. On average, carbon from siderite is isotopically heavier (+4.8±1.9 0/00) than that from ‘dolomite' (−7.2±1.1 0/00). The distribution of and the positive correlation between δ¹³C and δ¹⁸O probably reflects the two fractionation processes associated with methanogenesis and ‘dolomitization', respectively, in the genetic history of the siderite concretions in the split. Siderite concretions formed diagenetically early from bicarbonate under reducing conditions in a slightly alkaline freshwater environment that precluded calcite deposition.  相似文献   

白云鄂博矿物岩石研究的新进展     

张培善  陶克捷  杨主明 《岩石矿物学杂志》1991,10(3):265-270

本文论述了近年来白云鄂博矿区在旷物学、岩石学、地球化学和矿床成因研究方面的进展。在矿物学研究方面,除以往研究过的一百多种矿物外,八十年代中期以后,又相继发现并研究了含铌锐钛矿、含铌钙钛矿、锶铁钛石、水磷钙钍石、白云鄂博矿、未命名氟碳酸盐新种矿物、珀硅钛铈铁矿、硅钡镁石、带云母等矿物;发现了矿物间的共生和交代关系。在岩石学研究方面,找到了霓长岩,发现了霓长岩化作用,确定了火成碳酸岩岩石的存在。在地球化学和矿床成因方面,提出了稀土稀有金属矿化与火成碳酸岩岩浆活动有成因联系的见解。  相似文献   

邯邢地区中生代侵入岩中磷灰石的成因矿物学研究     

梁贤 《地质与勘探》2020,56(5):969-984

氧逸度为有效的氧分压,是实验岩石学中重要的研究课题,岩浆的氧逸度是继温度、压力、浓度等影响成岩成矿过程的关键性物理化学参数。本文利用磷灰石的氧逸度计,对邯邢地区六大主要岩体的岩浆氧逸度进行了计算。研究结果显示,样品中的磷灰石主要为羟-氟磷灰石,磷灰石的形态、成分和结构特征指示其为岩浆成因。磷灰石中的Mn元素在晶格中有两种方式,多以Mn3＋和Mn5＋的方式进入晶格。磷灰石氧逸度计计算的logfo2为-12.31~-9.75,均值-11.02。参考与磷灰石共生角闪石的形成温度,认为邯邢地区岩浆岩普遍具有较高的氧逸度。根据磷灰石氧逸度值与矿床规模的填图结果,认为并非氧逸度越高越有利于邯邢式铁矿的形成。结合矿物学填图等值线闭合的趋势,进而推断邯邢地区中部的符山和武安岩体深部可能仍存在较好的找矿远景。  相似文献   

南阿尔金巴什瓦克基性麻粒岩的变质演化 P- T- t 轨迹     

郭晶  李云帅  张建新 《地质学报》2020,94(9):2698-2711

大陆碰撞造山带中高压麻粒岩的 P- T- t 轨迹研究对于理解造山带的热演化历史及大陆地壳的形成与演化具有重要的意义,然而,如何连接同位素年龄与变质演化过程是恢复和建立 P- T- t 轨迹的重点和难点。本文通过对南阿尔金巴什瓦克地区基性麻粒岩的详细岩相学研究,认为该基性麻粒岩经历了原岩阶段（M1）、峰期变质阶段（M2）、峰后退变质阶段（M3）以及晚期角闪岩相- 绿片岩相退变质阶段（M4）。其中,传统矿物温压计和矿物微量元素温压计获得该基性麻粒岩所记录的峰期变质条件分别为17. 5~22. 6 kbar,901~985℃ 和17~28 kbar,1012~1049℃,退变质阶段的温压条件为7. 6~10. 7 kbar,750~810℃。此外,锆石U- Pb 年代学结果表明基性麻粒岩的变质时代为491±3. 5 Ma (MSWD=0. 62),结合锆石和石榴子石的微量元素分配系数以及前人的实验岩石学数据,认为该变质时代记录了早古生代高压- 超高温的变质事件,进而恢复了南阿尔金基性麻粒岩所记录的顺时针 P- T- t 轨迹。  相似文献