A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate     

Gerhard Kramm  Ralph Dlugi 《Journal of Atmospheric Chemistry》1994,18(4):319-357

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.  相似文献   

Nature minéralogique et rôle nutritionnel des argiles de sols céréaliers en région subhumide à semi-aride (Tunisie)     

Habib Ben Hassine 《Comptes Rendus Geoscience》2006,338(5):329-340

The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca⁺⁺, Mg⁺⁺ and K⁺ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006).  相似文献   

冻融作用对地气系统能量交换的影响分析   总被引：7，自引：12，他引：7  

李述训  南卓铜  赵林 《冰川冻土》2002,24(5):506-511

通过对温度波在地层内传播过程问题的分析研究, 讨论土在冻结和融化过程对地气系统能量交换的影响, 并以亚粘土为例应用近似方法计算了在冻结和融化过程地气系统能量交换和地温变化特征, 同时将相同条件下发生冻融作用与不发生冻融作用情况地气系统热交换量进行了比较. 结果表明, 冻融作用使地气系统热交换加强, 同时吸热和放热的过程也发生了改变.  相似文献   

质量传输和同位素交换:流动几何学和交换机制     

刘伟 《地学前缘》2002,9(4):423-428

耦合的质量传输和动力学限制的同位素交换模型综合考虑了平流、扩散、热液弥散 ,以及岩石与水之间的不平衡同位素交换等项因素。把耦合模型应用于 2个构造环境下的古热液系统 ,进而解释稳定同位素数据。对于造成环绕浅成侵入岩体分布的18O亏损环带的流体的流动几何学 ,以及浅部正断层流体流动的几何学 ,耦合模型提供了不同于单一同位素交换模型的解释。耦合模型也提供了关于同位素相对交换速率和同位素交换机制的信息。结果表明 ,断层带的动态重结晶促进了表面反应 ,进而便利了同位素交换 ;在化学不反应性和未变形的矿物中 ,同位素交换可能受制于固态条件下的扩散。  相似文献   

单道扫描电感耦合等离子体发射光谱法测定地质样品中的微量稀土元素     

郭振华  张立英  杜百娟 《化工矿产地质》2003,25(1):57-60

采用Na_2O_2熔融矿样,水提取,加三乙醇胺、EGTA做掩蔽剂。经氢型阳离子交换树脂交换分离富集稀土元素,由于选择了合适的仪器条件及测定波长,有效地消除了电感耦合等离子体发射光谱法(ICP-AES)测定过程中的基体干扰和光谱干扰。应用于地质样品中的稀土元素分析,获得了满意的准确度、精密度及检出限。  相似文献   

环电流区中性原子观测特性模拟研究   总被引：2，自引：1，他引：2       下载免费PDF全文

沈超  刘振兴 《地球物理学报》2003,46(1):1-1

为了给双星计划中性原子(ENA)探测仪的研制提供可靠 的理论依据，并为未来中性原子探测数据的分析及研究做好准备，针对双星轨道初步模拟计 算了双星ENA探测仪对磁暴时中性原子的观测特性. 建立了磁暴主相期间环电流离子分布的 一 个近似理论模式，并模拟计算了极轨卫星在极区上空、赤道面以及其他位置上对不同强度磁 暴主相期间环电流区ENA空间角分布及能谱的观测结果. 研究表明，存在环电流区方向和南 北极区环电流粒子沉降带两个中性原子强度极大区域；磁暴越强烈，注入区高度越低，环电 流区观测到的ENA通量越高；处于有利位置的ENA探测器可分辨注入区内边界或注入前沿；EN A探测器能够分辨环电流带离子分布的不均匀性；由于离子交换截面的差异，H，O，He 3种E NA的能谱分布不同；在10～80keV能谱范围内通量较强，易于观测；环电流区H，O两种ENA 通 量较强，有利于观测；而环电流区He ENA通量很弱，不易于观测. 模拟计算研究表明，双星 极轨卫星能够对环电流区ENA进行有效探测；低纬轨道上的ENA探测器也能够对环电流区ENA 进行一些观测；ENA探测器的研制应重视低、中能量范围ENA的探测.  相似文献   

Atmospheric Methyl Iodide at Cape Grim, Tasmania, from AGAGE Observations     

D. S. Cohan  G. A. Sturrock  A. P. Biazar  P. J. Fraser 《Journal of Atmospheric Chemistry》2003,44(2):131-150

Atmospheric mixing ratios of methyl iodide (CH₃I) and other methyl halides have been measured at Cape Grim, Tasmania (41°S, 145°E), since early 1998 as part of the Advanced Global Atmospheric Gases Experiment (AGAGE). This paper analyses about 1700 ambient air CH₃I measurements from the 14-month period (March 1998–April 1999). Mixing ratios peaked during the summer, despite faster photolytic loss, suggesting local oceanic emissions were about 2.2–3.6 times stronger in summer than in winter. Back trajectories show that CH₃I levels are strongly dependent on air mass origin, with highest mixing ratios in air from the Tasman Sea/Bass Strait region and lowest levels in air originating from the Southern Ocean at higher latitudes. CH₃I mixing ratios were not well correlated with other methyl halides in unpolluted marine air. The large variations with season and air mass origin suggest that high frequency, continuous data from key locations will make a significant contribution to the understanding of sources and sinks of this important short-lived atmospheric species.  相似文献   

A STUDY ON TYPHOON MOVEMENT PART Ⅲ:EFFECT OF THE HORIZONTAL MOMENTUM EXCHANGE BETWEEN TYPHOONS AND ENVIRONMENT     

贺海晏  董惠菁 《热带气象学报(英文版)》1997,3(1):1-10

Two semi-asymmetric flow patterns of typhoons are chosen to qualitatively determine the effect of exchange of horizontal momentum between inflow and outflow layers and the environment on the motion of typhoons. The results show that only the asymmetric flow component (residual after azimuthal mean flow has been removed) could cause a net momentum input into or output from a typhoon and therefore contribute to the changes in speed and direction of the typhoon movement. A typhoon with major inflow and/or outflow channels on its right (left) side would tend to accelerate and turn left (decelerate and turn right); On the other hand, a typhoon with major inflow and/or outflow channels in the rear (front) semicircle would tend to accelerate and turn right (decelerate and turn left).  相似文献   

The respiratory environment of the Namib Desert Golden Mole     

Roger S. Seymour  Mary K. Seely 《Journal of Arid Environments》1996,32(4):453-461

We measured the partial pressure of oxygen (PO₂) in the interstitial gas surrounding the sand-swimming Namib moleEremitalpa granti namibensis. At a sand temperature of 26 °C, which produced a nearly maximal rate of oxygen consumption, thePO₂near the noses of the animals averaged only 0·9 kPa (6·7 Torr) below the level in the free atmosphere. High oxygen availability was a result of the notably low metabolic rate in the 20 g mammals and the dry, porous and metabolically inactive nature of dune sand. A mathematical model indicated that normal mammals weighing 200 g or more could comfortably exist completely encased in dune sand. We concluded that the moles' small size and low metabolic rate are not adaptations to hypoxia or hypercapnia underground but are probably related to low food availability and the energetic cost of foraging in their desert environment.  相似文献