A simple and rapid procedure to extract organochlorine pesticides (OCPs) from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone (1 : 1, v/v). The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate (80 : 20, v/v) and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent, 相似文献
The Tso Morari Complex, which is thought to be originally the margin of the Indian continent, is composed of pelitic gneisses and schists including mafic rock lenses (eclogites and basic schists). Eclogites studied here have the mineral assemblage Grt + Omp + Ca-Amp + Zo + Phn + Pg + Qtz + Rt. They also have coesite pseudomorph in garnet and quartz rods in omphacite, suggesting a record of ultrahigh-pressure metamorphism. They occur only in the cores of meter-scale mafic rock lenses intercalated with the pelitic schists. Small mafic lenses and the rim parts of large lenses have been strongly deformed to form the foliation parallel to that of the pelitic schists and show the mineral assemblages of upper greenschist to amphibolite facies metamorphism. The garnet–omphacite thermometry and the univariant reaction relations for jadeite formation give 13–21 kbar at 600 °C and 16–18 kbar at 750 °C for the eclogite formation using the jadeite content of clinopyroxene (XJd = 0.48).
Phengites in pelitic schists show variable Si / Al and Na / K ratios among grains as well as within single grains, and give K–Ar ages of 50–87 Ma. The pelitic schist with paragonite and phengite yielded K–Ar ages of 83.5 Ma (K = 4.9 wt.%) for paragonite–phengite mixture and 85.3 Ma (K = 7.8 wt.%) for phengite and an isochron age of 91 ± 13 Ma from the two dataset. The eclogite gives a plateau age of 132 Ma in Ar/Ar step-heating analyses using single phengite grain and an inverse isochron age of 130 ± 39 Ma with an initial 40Ar / 36Ar ratio of 434 ± 90 in Ar/Ar spot analyses of phengites and paragonites. The Cretaceous isochron ages are interpreted to represent the timing of early stage of exhumation of the eclogitic rocks assuming revised high closure temperature (500 °C) for phengite K–Ar system. The phengites in pelitic schists have experienced retrograde reaction which modified their chemistry during intense deformation associated with the exhumation of these rocks with the release of significant radiogenic 40Ar from the crystals. The argon release took place in the schists that experienced the retrogression to upper greenschist facies metamorphisms from the eclogite facies conditions. 相似文献
ABSTRACT. This study examines altitudinal residential segregation by race in 146 cities in the U.S. South. It begins by embedding the topic in recent theorizations of the social construction of nature, the geography of race, and environmental justice. Second, it focuses on how housing markets, particularly in the South, tend to segregate minorities in low‐lying, flood‐prone, and amenity‐poor segments of urban areas. It tests empirically the hypothesis that blacks are disproportionately concentrated in lower‐altitude areas using gis to correlate race and elevation by digital elevation‐model block group within each city in 1990 and 2000. The statistical results confirm the suspected trend. A map of coefficients indicates strong positive associations in cities in the interior South‐where the hypothesis is confirmed‐and an inverse relationship near the coast, where whites dominate higher‐valued coastal properties. Selected city case studies demonstrate these relationships connecting the broad dynamics of racial segregation to the particularities of individual places. 相似文献
This paper examines the debate surrounding a recent decision made by the Ghanaian government to permit gold exploration – and potentially, mining – in 'protected' forest reserves. In 2001, four mining companies were awarded mineral exploration concessions in forested regions of the country, and have since put forward applications to mine for gold. Notwithstanding the sharp divide in opinion on the issue, the continued uncertainty surrounding the implications of the proposed activities makes further research on the ground imperative in the short term. Work aiming to elicit indigenous perspectives on the projects, as well as research that facilitates dialogue between and/or among stakeholder parties, should be prioritized. 相似文献
Evaluation of Ontario's Environmental Farm Plan (EFP) scheme, launched in 1993, provides an opportunity for comparisons with agri-environmental measures instituted in the European Union and other parts of North America. The EFP has a strong 'bottom-up' dimension in that it is farmers' organizations that have been central both to the scheme's instigation and to its ongoing management. This has affected the nature of the actions taken by individual farmers participating in the scheme. These actions are reviewed, especially in terms of the participants' attitudes towards stewardship of the land, environmental outcomes, cross-compliance measures, barriers to participation and the role of statutory regulation. Some contrasts are drawn with the greater 'top-down' controls exerted in several EU agri-environment schemes, with the latter's promotion of extensification and the changing role of farmers as 'producers of countryside' in a multi-functional agricultural system. The diffusion of EFP schemes throughout Canada is noted and is cited as confirming the maintenance of fundamentally different attitudes to the development of farm-based environmental actions compared with those adopted in the EU. 相似文献