High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献   

亚、欧两大洲自然地理环境结构的整体性和差异性教学初探     

娄昭 《世界地理研究》2004,13(2):109-112

地理环境的结构，是指地理环境各组成要素之间和各组成部分之间相互关系性质的组合，它包括既有联系、又有区别的两个方面，即地理环境结构的整体性和差异性。笔者在亚、欧两洲自然地理数年的教学实践中，从自然环境结构的整体性和差异性特征入手，得出分析、综合、概括归纳和对比研究等方法是学习世界区域地理的主要方法。  相似文献   

Inviscid behaviour of fines-rich pyroclastic flows inferred from experiments on gas-particle mixtures     

O. Roche  M.A. Gilbertson  R.S.J. Sparks 《Earth and Planetary Science Letters》2005,240(2):401-414

Experiments were carried out on granular flows generated by instantaneous release of gas-fluidised, bidisperse mixtures and propagating into a horizontal channel. The mixture consists of fine (< 100 μm) and coarse (> 100 μm) particles of same density, with corresponding grain size ratios of ∼ 2 to 9. Initial fluidisation of the mixture destroys the interparticle frictional contacts, and the flow behaviour then depends on the initial bed packing and on the timescale required to re-establish strong frictional contacts. At a fines mass fraction (α) below that of optimal packing (∼ 40%), the initial mixtures consist of a continuous network of coarse particles with fines in interstitial voids. Strong frictional contacts between the coarse particles are probably rapidly re-established and the flows steadily decelerate. Some internal friction reduction appears to occur as α and the grain size ratio increases, possibly due to particle rolling and the lower roughness of internal shear surfaces. Segregation only occurs at large grain size ratio due to dynamical sieving with fines concentrated at the flow base. In contrast, at α above that for optimal packing, the initial mixtures consist of coarse particles embedded in a matrix of fines. Flow velocities and run-outs are similar to that of the monodisperse fine end-member, thus showing that the coarse particles are transported passively within the matrix whatever their amount and grain size are. These flows propagate at constant height and velocity as inviscid fluid gravity currents, thus suggesting negligible interparticle friction. We have determined a Froude number of 2.61 ± 0.08 consistent with the dam-break model for fluid flows, and with no significant variation as a function of α, the grain size ratio, and the initial bed expansion. Very little segregation occurs, which suggests low intensity particle interactions during flow propagation and that active fluidisation is not taking place. Strong frictional contacts are only re-established in the final stages of emplacement and stop the flow motion. We infer that fines-rich (i.e. matrix-supported) pyroclastic flows propagate as inviscid fluid gravity currents for most of their emplacement, and this is consistent with some field data.  相似文献   

土壤有机碳同位素样品制备过程的影响因素讨论   总被引：3，自引：1，他引：3  

曹蕴宁  刘卫国  宁有丰  张庆乐  王政 《地球化学》2005,34(4):91-100

土壤有机碳同位素地球化学在气候和植被恢复方面的研究已得到广泛应用,但目前对不同类型、不同时代的土壤总有机碳同位素样品制备过程的系统研究较少.本文选取黄土高原不同地区、不同类型的现代土壤和古土壤,对其有机碳同位素样品制备过程进行了较系统的研究.( 1)去除土壤中无机碳酸盐对有机碳同位素组成的干扰:对于现代土壤样品,在室温条件下,用 0.5～ 6 mol/L HCl反应 1 d去除碳酸盐,均可获得理想数据;在 70 ℃反应条件下,用 0.5～ 2 mol/L HCl反应 2 h去除碳酸盐可获得理想数据,但用 6 mol/L HCl,δ 13C值偏负 0.65‰;( 2)在 850 ℃氧化温度条件下,样品制备加铜丝,对现代土壤及古土壤样品的δ 13C值均没有影响,结果表明在用封管法进行现代土壤及古土壤的有机碳同位素样品制备时,可以不加铜丝;( 3)对于有机碳含量较高的有机碳标准物质、植物和现代土壤样品,在 850 ℃氧化条件下,恒温 2.5 h,足以保证样品有机质氧化完全,不会产生同位素分馏;对于深层黄土和红粘土样品,由于样品体系复杂,在上述氧化条件下难以获得理想数据,合适的氧化条件有待进一步深入研究.  相似文献   

Retrofit-reinforcement of cohesive soil slopes using high strength geotextiles with drainage capability     

T. F. Zimmie  A. Pamuk  K. Adalier  M. B. Mahmud 《Geotechnical and Geological Engineering》2005,23(4):447-459

A series of geotechnical centrifuge physical modeling tests were performed to assess the potential use of a new cost-effective mechanically stabilized earth system for retrofitting marginally stable cohesive slopes. The proposed system utilizes the dual functions of reinforcement and drainage by directly inserting high strength non-woven geotextile strips into slopes, with little or no excavation required behind the slope face. The system significantly increases the factor of safety of potentially unstable cohesive slopes, and can be constructed at less expense and more rapidly than conventional mechanically stabilized earth systems.  相似文献   

空间分析与自然地理综合研究   总被引：2，自引：1，他引：2  

郝成元  吴绍洪  杨勤业 《地理与地理信息科学》2005,21(1):52-55

通过对空间分析技术和自然地理综合研究发展历程与趋势的分析，得出两个结论：1)现代地理学的快速发展越来越离不开空间分析的支撑，即空间分析技术在地理学中的应用空间愈来愈广，在自然地理综合研究中尤为如此，其主要原因就是空间分析在综合研究中的优势愈来愈明显；2)空间分析技术随其理论与实践的迅速发展及逐步拓展，愈来愈成为自然地理学发展的巨大推动力，也越来越离不开自然地理综合研究这个促使其发展壮大的空间和能发挥其主导作用的领域。空间分析技术和自然地理综合研究的结合已经成为现代自然地理学以及地球空间信息学研究的主要发展趋势之一。  相似文献   

城市建成环境对居民体力活动的影响 ——以福州市的经验研究为例   总被引：2，自引：1，他引：1  

张延吉  陈小辉  赵立珍  马妍 《地理科学》2019,39(5):779-787

利用福州中心城区的社会调查、POI、道路网、用地性质等数据,在社区尺度探究城市建成环境对居民休闲型中高强度体力活动的影响。研究发现：① 低密度土地利用与体力活动时长呈正向关联,功能单一和邻近主干道则对体力活动起到抑制作用。② 体力活动目的地对不同人群具有差异化影响,体育用地和付费运动场所仅能促进中高阶层和中高收入者的体力活动,而周边公共运动设施的丰富程度更具普适性意义。③ 通过纳入运动偏好和单独分析保障房、单位大院及房改房住户达到规避居住自选择的目的,证明上述建成环境特征对体力活动的影响是独立且稳健的。  相似文献   

Elastoplastic model with loading memory surfaces (LMS) for monotonic and cyclic behaviour of geomaterials     

Hervé di Benedetto  Matthieu Blanc  Samir Tiouajni  Alan Ezaoui 《国际地质力学数值与分析法杂志》2014,38(14):1477-1502

A new elastoplastic model called loading memory surface based on the critical state concept and the multi‐surface framework is proposed for geomaterials. The model uses a hypoelastic formulation and two plastic mechanisms. The formulations of the model are made in three‐dimensional stress–strain space and work under both monotonic and cyclic loadings. A newly introduced formalism makes it possible to obtain the cyclic response directly from the monotonic loading one. This formalism gives a three‐dimensional generalization of the well‐known Masing rule. The model has been validated against test results of Hostun sand under several conditions: monotonic and cyclic, drained and undrained, tests in compression and in extension, and at different confining pressures and different densities. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Modelling and experimental study of coupled exchange of p,p′‐DDE and colloids in a flume simulated stream–streambed system          下载免费PDF全文

Celina Camarena  Doris Otero  Jianhong Ren 《水文研究》2016,30(1):40-56

Stream–subsurface exchange plays a significant role in the fate and transport of contaminants in streams. It has been modelled explicitly by considering fundamental processes such as hydraulic exchange, colloid filtration, and contaminant interactions with streambed sediments and colloids. The models have been successfully applied to simulate the transport of inorganic metals and nutrients. In this study, laboratory experiments were conducted in a recirculating flume to investigate the exchange of a hydrophobic organic contaminant, p,p′‐dichloro‐diphenyl‐dichloroethane (DDE), between a stream and a quartz sand bed. A previously developed process‐based multiphase exchange model was modified by accounting for the p,p′‐DDE kinetic adsorption to and desorption from the bed sediments/colloids and was applied to interpret the experimental results. Model input parameters were obtained by conducting independent small‐scale batch experiments. Results indicate that the immobilization of p,p′‐DDE in the quartz sand bed can occur under representative natural stream conditions. The observed p,p′‐DDE exchange was successfully simulated by the process‐based model. The model sensitivity analysis results show that the exchange of p,p′‐DDE can be sensitive to either the sediment sorption/desorption parameters or colloidal parameters depending on the experimental conditions tested. For the experimental conditions employed here, the effect of colloids on contaminant transport is expected to be minimal, and the stream–subsurface exchange of p,p′‐DDE is dominated by the interaction of p,p′‐DDE with bed sediment. The work presented here contributes to a better mechanistic understanding of the complex transport process that hydrophobic organic contaminants undergo in natural streams and to the development of reliable, predictive models for the assessment of impacted streams. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Research and Test of Real-time Search Algorithm of Fast Radio Bursts Based on GPU Acceleration     

WANG Jun  CHEN Mao-zheng  PEI Xin  WANG Zhi-qiao 《Chinese Astronomy and Astrophysics》2018,42(2):313-324

In order to satisfy the research need of Nanshan 25 m radio telescope of Xinjiang Astronomical Observatory (XAO) and study the key technology of the planned QiTai radio Telescope (QTT), on the basis of the original CPU (Central Processing Unit)-based real-time search algorithm of FRBs (Fast Radio Bursts), we have studied the GPU (Graphics Processing Unit)-based real-time search algorithm of FRBs, and built the corresponding real-time search system of FRBs. We have made the comparison and analysis on the GPU system and CPU system, the test result shows that under a given searching accuracy, the speed of the GPU-accelerated algorithm is improved by 35–45 times compared with that of the CPU algorithm.  相似文献