纳米TiO2分离富集ICP-MS法测定河口环境样品中重金属研究     

黄霄红  卢豪良 《亚热带资源与环境学报》2013,(2):35-40

建立了以纳米二氧化钛（TiO2）作为吸附剂填充微柱,电感耦合等离子体质谱（ICP-MS）法测试Cu^2＋,Cd^2＋,Pb^2＋和Ni^2＋离子的分析方法．考察了不同pH值、洗脱液浓度、样品流速、体积和外源干扰离子的影响,实验结果表明在pH值8～10范围内待测离子可被TiO2定量吸附,2．0molL^-1HNO3可将吸附在微柱上的待测物完全洗脱,优化条件下本方法对溶液中Cu^2＋,Cd^2＋,Ph^2＋和M^2＋离子检出限分别为：0．02,0．01,0．01,0．02μgL～,相对标准偏差小于2％（n=7）,富集系数50倍．对水系沉积物标准物质（GBW07310）的测定值与标准值相一致,方法具有简便、快速,灵敏度高,重现性好的优点,可满足河口水体与沉积物样品中痕量金属元素定量分析的要求．  相似文献   

化探中痕量银的测定     

张霞 《化工矿产地质》2013,(1):47-51,64

对电感耦合等离子体质谱法与一米光栅发射光谱法在化探样品中的痕量银测定进行对比,实验表明,两种方法都具有高精密度和准确度,检出限也符合区域化探的要求,但是在大批量的化探测定及多元素同时测定方面,质谱法操作简单、快速、准确、成本低,优于一米光栅发射光谱法,更适合应用于批量化探样品中银的测定。  相似文献   

常压混酸溶矿一电感耦合等离子体发射光谱法测定铌钽     

闫红岭  来新泽  王琳  程祎  王筱丽 《世界地质》2011,30(3):493-496

混酸溶解矿石样品,在酒石酸介质中,用电感耦合等离子体发生光谱法(ICP-AES)测定溶液中的铌钽。该方法ρ(Nb₂O₅)和ρ(Ta₂O₅)在0～20 μg/mL时,铌钽原子发射光谱强度与浓度呈良好的直线关系,Nb、Ta标准曲线相关系数尺分别为0.999 9和0.999 7。检出限分别为0.023 μg/mL和0.072 μg/mL。本方法测定标准样品,测定值与认定值相符。对实际样品分析,Nh、Ta的相对标准偏差(n=6)分别为0.42％～2.3％和1.8％～3.3％,加标回收率均为97％～103％,适合地质找矿、选冶等领域的样品测试。  相似文献   

On the importance of auroral processes in the Universe     

Bengt Hultqvist   《Journal of Atmospheric and Solar》2008,70(18):2235-2245

Acceleration of charged particles in magnetic field-aligned electric potential differences at Earth and at the outer planets in the solar system is summarized and its general importance in the Universe is briefly discussed.The role of field-aligned currents, driven by parallel electric fields, in causing filamentary structure in stellar atmospheres is briefly reviewed.The differences between auroral optical emissions at various planets are summarized.The important role of field-aligned potential differences in the generation of AKR and corresponding emissions from other objects is discussed.Finally, aurora-associated processes for ejection of planetary plasma into space are briefly reviewed.  相似文献   

Possible ion-acoustic soliton formation in the ionospheric perturbations observed on DEMETER before the 2007 Pu’er earthquake     

U. A. Mofiz  R. Battiston 《地震学报(英文版)》2009,(3)

The data of ionospheric perturbations observed on DEMETER before the 2007 Pu’er earthquake are analyzed. The three-component plasma (ions, electrons and heavy ions) is studied in the fluid concept. The linear dispersion relation for ion-acoustic wave is found in the presence of heavy ions. The nonlinear dynamics is studied for arbitrary amplitude of the wave. The Sagdeev potential is calculated, which shows that solitary structure exists for Mach number within a range defined by the presence of heavy ions. ...  相似文献   

Possible ion-acoustic soliton formation in the ionospheric perturbations observed on DEMETER before the 2007 Pu＇er earthquake     

U. A. Mofiz  R. Battiston 《地震学报(英文版)》2009,(3):257-262

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A climatological study of nocturnal equatorial F-region irregularities at the west Pacific longitudes by using phase fluctuations of the global positioning system     

F.D. Chu  W.S. Chen  C.C. Lee  J.Y. Liu   《Journal of Atmospheric and Solar》2009,71(13):1441-1449

This study investigated a long-term climatology of nocturnal equatorial F-region irregularities by using phase fluctuations of the global positioning system during the solar cycle of 1996–2006 at the west Pacific longitudes. The results showed that the distribution of the occurrence of irregularities is a two-peak pattern, which peaks in equinoxes with a shallow/deep dip in June/December solstice during high solar activity but with two about the same dips in magnitude in both June and December solstices during low solar activity. Moreover, the most interesting longitudinal effect in the area is in solstice occurrences of irregularities during high solar activity that the irregularities in December solstice months develop easier in the west area but those in June solstice months develop easier in the east area.  相似文献   

On the spectrum of mid-latitude sporadic-E irregularities     

Yu. V. Kyzyurov 《Annales Geophysicae》2000,18(10):1283-1292

We discuss the creation of mid-latitude sporadic-E plasma irregularities (with length-scales smaller than sporadic layer thickness) by the neutral atmosphere turbulence. Using fluid equations, the relation between plasma density fluctuations and the velocity field of neutrals is derived. After a brief discussion of the relevant neutral turbulence, the analytical expression for the power spectrum of plasma irregularities is obtained. This expression allows a power-law type of experimental irregularity spectra (the spectral index depends on sporadic-E characteristics) and possible departures in detail of the irregularity spectra from the power-law form to be explained. In addition, it allows us to make estimates of length-scales at which such departures must occur.  相似文献   

The generation of non aspect sensitive plasma density irregularities by field aligned drifts in the lower ionosphere     

T. R. Robinson  K. Schlegel 《Annales Geophysicae》2000,18(7):799-806

A theory of the generation of plasma density irregularities with virtually no aspect sensitivity, in the lower ionosphere at high latitudes, by electron drifts aligned with the geomagnetic field, is presented. The theory is developed through fluid equations in which the destabilising mechanism involves positive feedback from electron collisional heating. When field aligned electron drift speeds exceed a few km s^–1, this effect destabilises waves with wavelengths in excess of a few tens of metres in the lower E-region, where collisional effects are sufficiently large. Furthermore, the threshold conditions are almost independent of the wave propagation direction and the unstable waves propagate at speeds well below the ion acoustic speed. The role that this new instability may play in recent radar backscatter observations of short scale irregularities propagating in directions close to that of the geomagnetic field, in the lower E-region is also considered.  相似文献   

Comment on “Concerning the generation of geomagnetic giant pulsations by drift-bounce resonance ring current instabilities” by K.-H. Glassmeier et al., Ann. Geophysicae, 17, 338/350, (1999)     

I. R. Mann  G. Chisham 《Annales Geophysicae》2000,18(2):161-166

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