全文获取类型
收费全文 | 451篇 |
免费 | 89篇 |
国内免费 | 82篇 |
专业分类
测绘学 | 80篇 |
大气科学 | 194篇 |
地球物理 | 56篇 |
地质学 | 105篇 |
海洋学 | 62篇 |
天文学 | 5篇 |
综合类 | 50篇 |
自然地理 | 70篇 |
出版年
2024年 | 4篇 |
2023年 | 14篇 |
2022年 | 24篇 |
2021年 | 29篇 |
2020年 | 25篇 |
2019年 | 22篇 |
2018年 | 14篇 |
2017年 | 19篇 |
2016年 | 14篇 |
2015年 | 34篇 |
2014年 | 34篇 |
2013年 | 25篇 |
2012年 | 26篇 |
2011年 | 25篇 |
2010年 | 21篇 |
2009年 | 27篇 |
2008年 | 19篇 |
2007年 | 44篇 |
2006年 | 22篇 |
2005年 | 23篇 |
2004年 | 21篇 |
2003年 | 17篇 |
2002年 | 17篇 |
2001年 | 14篇 |
2000年 | 12篇 |
1999年 | 14篇 |
1998年 | 12篇 |
1997年 | 8篇 |
1996年 | 10篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有622条查询结果,搜索用时 15 毫秒
101.
西北干旱区一次阵风锋天气过程分析 总被引:1,自引:0,他引:1
利用银川新一代天气雷达观测资料和自动站实况资料,结合本地化非静力平衡中尺度数值预报MM5模式产品,对2004年6月7日银川地区一次区域大风天气过程进行了雷达气象学和中小尺度天气学背景分析。结果表明:这次突发短时大风天气由雷暴强烈下沉气流形成阵风锋引发。阵风锋导致风速增加、气温下降、相对湿度上升。阵风锋在对流云团减弱后仍向前推进,并继续维持30 min左右。阵风锋的长度超过40 km,宽3 km,主体顶高达1 500 m。当时空气层结不稳定,有利于对流运动发展。500 hPa冷空气因重力原因下泻,并与对流垂直环流的下沉气流相结合,是导致强烈下沉气流的根本原因。阵风锋东移过程中,冷气流受下垫面加热作用增暖变性,受地表磨擦而丧失动量;到达贺兰山麓后,环境大气温度随地形升高而下降,阵风锋前后的气温达到平衡而消失。宁夏本地化非静力平衡中尺度数值预报模式对此次阵风锋过程具有较好的模拟能力。 相似文献
102.
Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species. 相似文献
103.
Vic Wing-Hang Tsang 《Marine pollution bulletin》2009,58(10):1462-156
A mild, low-temperature analytical approach based on sonication assisted extraction coupled with HPLC electrospray ionization triple quadrupole tandem mass spectrometry has been developed for the simultaneous qualitative and quantitative determination of the four Irgarol-related s-triazine species, namely Irgarol-1051, M1, M2 and M3, in coastal sediments and Green-lipped mussel samples. Mild extraction conditions were necessary for the preservation of the thermally unstable M2. The Multiple Reaction Monitoring (MRM) mode of detection by ESI-MS/MS enabled reliable qualitative identification and sensitive quantitative determination of those s-triazines. This determination method was applied to evaluate the degree of Irgarol-1051 contamination in the sediments and biota of the coastal environment of Hong Kong - one of the busiest maritime ports in the world. All the four s-triazine species were observed in all of the samples. This is the first time that the newly identified M2 and M3 are detected in coastal sediments and biota tissues. 相似文献
104.
红三角地区农产品虚拟水的计算分析 总被引:1,自引:0,他引:1
农业是世界上最大的水资源利用部门,各种农产品中“寄存”了大量的水资源,蕴涵在产品生产和各种服务中的水资源就是产品或服务中的虚拟水.以红三角地区为例,分析了郴州市、韶关市、赣州市主要农产品的演变特征,计算了主要农产品的虚拟水含量及消费情况,在此基础上探讨了红三角地区农产品的战略性调整和水资源有效配置的政策意义.计算表明,不同区域生产同类型农产品所耗费的水资源不同,加上消费数量的差异,使居民人均农产品虚拟水消费也存在明显差异.红三角地区水资源富足的地区可通过农产品贸易方式更好地发挥区域水资源优势,主动开发和生产高效益的水资源密集型农产品;对局地水资源缺乏的山区,需要通过农产品生产的战略性调整,通过购入水资源密集型农产品,大力发展高效益的特色农业,实现生态-经济-水的良性循环. 相似文献
105.
利用四川省地面自动站2018年6月—2019年5月的逐小时降水观测资料,在邻近插值和双线性插值对比分析的基础上,从晴雨准确率、降水时空特征、降水分量级检验等多个方面,对国家气象信息中心研制的融合降水实况分析产品在四川地区的适用性进行评估分析.评估结果表明:(1)邻近插值和双线性插值对评估结果影响小.(2)融合降水实况分... 相似文献
106.
107.
108.
C. Warneke R. Holzinger A. Hansel A. Jordan W. Lindinger U. Pöschl J. Williams P. Hoor H. Fischer P. J. Crutzen H. A. Scheeren J. Lelieveld 《Journal of Atmospheric Chemistry》2001,38(2):167-185
Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 105molecules cm-3 averaged over 24 hours were calculated due to lossof OH and HO2 in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer. 相似文献
109.
110.
高岭石的热稳定性和热处理产物的DTA IR和EPR研究 总被引:8,自引:0,他引:8
本文利用DTA、IR和EPR等方法研究了高岭石的热稳定性及100—900℃热处理产物的系统特征。高岭石的热稳定性会因为堆垛层错缺陷浓度的增大而降低。根据IR和EPR实验,所有高岭石热处理过程中的变化包括:脱羟前、脱羟和脱羟后三个阶段。小于400℃时,产物成分和结构同原高岭石相同,≥400℃开始产物的堆垛层错浓度增大并有利于继续升温后的脱羟过程。变高岭石可能介于晶质和非晶质之间。此外,高岭石Ⅰ位Fe~(3+)和变高岭石结构中的Fe~(3+)可能有某些相似的特征。 相似文献