铂族元素的表生地球化学研究进展   总被引：2，自引：0，他引：2  

皮道会  邓海琳  李朝阳  朱维光 《矿物岩石地球化学通报》2004,23(4):355-361

基性-超基性岩及黑色页岩等风化过程中铂族元素发生了活化和迁移。铂族元素在岩体附近土壤、植物和水体等表生介质中的迁移富集特征可以用来寻找岩浆型铂族元素矿床。黑色页岩风化过程中，Os的表生迁移对海洋^187Os／^188Os值上升有重要意义。此外，作为重金属元素，机动车铂族元素催化剂在环境中的释放，也会带来潜在的生态环境和人体健康问题。  相似文献   

XML Web Service及其在地球数据共享中的应用研究     

景民昌  杨革联 《物探化探计算技术》2004,26(4):346-350

地球科学研究产生了大量的地球数据，其特点决定了地球数据共享的必要性。分析了网络化过程中地球数据共享存在的若干问题，介绍了XML Web Service及其相关技术．提出了基于XML Web Service的地球数据共享模型。在VS．NET中对XML Web Service在地球数据共享的应用进行了测试．指出XML Web Service是未来实现全球级的地球数据共享应用的理想选择。  相似文献   

双剪统一强度准则改进及其在岩土工程中的应用     

胡小荣  周洪华  胡昌斌 《岩土力学》2004,25(Z2):97-102

在分析Mohr-Coulomb强度准则和双剪统一强度准则的基础上,提出了主剪面应力对和主剪面应力对的作用这2个新概念,并以此为出发点,通过考虑十二面体单元主剪面上所有3个主剪面应力对的共同作用,在双剪强度准则的基础上提出了一个新准则,并对其作了极限线分析.应用该新强度准则研究了静水压力条件下圆形巷道围岩弹塑性分析和土压力计算问题.研究表明,该准则不仅能较好地非线性反映岩土的3个基本强度特征,还解决了双剪统一准则中存在的双重破坏角问题.  相似文献   

Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study     

J. A. Proenza  F. Ortega-Gutirrez  A. Camprubí  J. Tritlla  M. Elías-Herrera  M. Reyes-Salas 《Journal of South American Earth Sciences》2004,16(8):129

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.  相似文献   

Mudstones of the Tanqua Basin, South Africa: an analysis of lateral and stratigraphic variations within mudstones, and a comparison of mudstones within and between turbidite fans     

P. O. D. Andersson  R. H. Worden† 《Sedimentology》2004,51(3):479-502

Permian deep‐water mudstones in the Tanqua Basin, South Africa, have been studied using geochemical and spectral gamma ray techniques. The mudstones occur as thick sequences between sand‐rich submarine fans, but also occur as thinner mud‐rich units within each fan. The interfan mudstones are interpreted to have accumulated during transgression and the consequent period of relatively high sea‐level, while the submarine fans and their intrafan mudstones were deposited during regression and relatively low sea‐level. Geochemical analyses revealed systematic differences between interfan and intrafan mudstones because the two types of mudstones have slightly different source lithologies. Differences between the two types of mudstone suggest that changes in relative sea‐level played a role in controlling exposure of sediment source areas. There are geochemical signals that display systematic stratigraphic trends within both interfan and intrafan mudstones. These are best explained by gradual denudation, exposure and weathering of different lithologies within a single sediment source area. Both interfan and intrafan mudstones have uniform geochemical signals along the flow direction except for the relative amount of uranium. It is most likely that the basinward increase in uranium in the mudstones is the result of reduced clastic dilution of uranium‐bearing pelagic fallout.  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献   

Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry   总被引：190，自引：0，他引：190  

Honglin Yuan  Shan Gao  Xiaoming Liu  Huiming Li  Detlef Günther  Fuyuan Wu 《Geostandards and Geoanalytical Research》2004,28(3):353-370

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.  相似文献   

Nuclear Waste Disposal Simulations: Couplex Test Cases     

H. Hoteit  Ph. Ackerer  R. Mosé 《Computational Geosciences》2004,8(2):99-124

We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods.  相似文献   

Regional moment tensor uncertainty due to mismodeling of the crust     

Jan ílený 《Tectonophysics》2004,383(3-4):133-147

The retrieval of earthquake moment tensor (MT) requires the response of the medium, in which seismic waves travel from the hypocenter to the stations, to be known. In inverting long-period (LP) seismic data (teleseismic and LP regional records), a gross earth model is sufficient; with decreasing periods, a more detailed model is needed. This is the case when waveforms of weak earthquakes at regional distances are to be inverted. Regional moment tensors (RMTs) of mostly Mediterranean earthquakes are determined on a routine basis by the Swiss Seismological Survey (SED) by using averaged models of the earth's crust. By inverting broad-band records of the M_w=4.8 earthquake near Udine, N Italy, on Feb. 14, 2002, we tested the sensitivity of the MT solution with respect to possible errors in the earth model used and in the location of the hypocenter depth. We perturbed the P and S velocities and the thickness in the 1-D earth model in the range from 3% to 30% of the parameter values and constructed estimates of confidence regions of the MT and error bars of the source time function (STF) and scalar moment in three frequency bands. Similarly, these error characteristics were determined assuming a mislocation in the hypocenter depth. We found that, in the band of periods from 25 to 50 s, the mechanism is resolved well (at the confidence level 95% at least) up to an earth model uncertainty of 30%, in the passband 10–25 s up to about 10%, but it is undetermined completely at periods of 5–10 s. An error in hypocenter depth of as much as double the value reported by the location procedure does not destroy the resolution of the mechanism at periods above 10 s. In the RMT catalog of the SED, earthquakes of M_w greater than about 3.5 are processed at periods above 30 s; thus, the solutions for these events are robust with respect to a possible uncertainty in the earth model used. Mechanisms of weaker earthquakes, retrieved from short periods, should be interpreted with caution.  相似文献   

From in-situ coal to fly ash: a study of coal mines and power plants from Indiana     

Maria Mastalerz  James C Hower  Agnieszka Drobniak  Sarah M Mardon  Grzegorz Lis   《International Journal of Coal Geology》2004,59(3-4):171-192

This paper presents data on the properties of coal and fly ash from two coal mines and two power plants that burn single-source coal from two mines in Indiana. One mine is in the low-sulfur (<1%) Danville Coal Member of the Dugger Formation (Pennsylvanian) and the other mines the high-sulfur (>5%) Springfield Coal Member of the Petersburg Formation (Pennsylvanian). Both seams have comparable ash contents (11%). Coals sampled at the mines (both raw and washed fractions) were analyzed for proximate/ultimate/sulfur forms/heating value, major oxides, trace elements and petrographic composition. The properties of fly ash from these coals reflect the properties of the feed coal, as well as local combustion and post-combustion conditions. Sulfur and spinel content, and As, Pb and Zn concentrations of the fly ash are the parameters that most closely reflect the properties of the source coal.  相似文献