等离子体发射光谱法直接测定海洋沉积物中的微量稀土元素   总被引：1，自引：2，他引：1       下载免费PDF全文

陈道华  张欣 《岩矿测试》2003,22(1):61-63

应用全谱直读电感耦合等离子体发射光谱法对海洋沉积物中微量稀土元素的测定进行了研究，选择了最佳的仪器工作条件，采用多谱线拟合技术进行校正，样品的加标回收率为94．0％-110．0％。方法采用海底沉积物国家一级标准物质进行验证，测定结果与标准值较吻合，各元素10次测定的RSD≤11．3％。  相似文献   

森林沼泽区矿产资源地球化学勘查   总被引：12，自引：0，他引：12  

金浚  丁汝福  陈伟民 《物探与化探》2003,27(6):431-434,448

通过景观调查和中大比例尺化探方法试验,对我国东北森林沼泽区景观地球化学特征、元素存在形式、迁移富集机制、影响因素、采样介质、采样粒度、采样方法等理论和方法技术问题进行研究,提出该类地区元素表生分散富集的某些地球化学规律和中大比例尺化探工作方法.  相似文献   

西藏驱龙斑岩铜钼矿地球化学异常特征   总被引：6，自引：0，他引：6  

刘崇民  胡树起 《物探与化探》2003,27(6):441-444

驱龙铜矿发育多元素的岩石地球化学异常.成矿元素Cu、Mo、(Ag)异常强、规模大,异常与矿化区一致;伴生元素Au、Bi、Pb、As、Sb、Hg异常在Cu、Mo异常边部并套合产出的B Co、Ni Mn Zn的异常主要分布铜钼矿化带外侧.Na₂O在矿化区显示负异常,K₂O为正异常.从异常元素组合、水平分带性和贫Na₂O、富K₂O的成矿环境表明,矿床属典型的斑岩型铜矿地球化学特征,并受到了强烈的剥蚀.  相似文献   

呼和浩特市环境地球化学特征初探     

丁天才  安存杰  苏美霞  田林浩  刘还林  张玉宝 《物探与化探》2003,27(6):487-489

介绍了呼和浩特市环境地球化学特征,对该区土壤次生环境进行了质量分区划分,探讨该区土壤环境地球化学元素迁移概略,提出了土壤环境地球化学治理的具体意见.  相似文献   

基于自然水系网信息的元素运移分析     

侯遵泽  徐振邦 《物探化探计算技术》2003,25(1):65-69

地面上的矿物或污染物元素主要是随水系而运移的。因此，利用自然水系网信息来定量分析元素沿水系的迁移、分散，对于地质找矿和环境保护都具有重要意义。在研究应用主概率权模拟模型产生自然水系网的基础上，提出了元素在水系网中运移的计算方法，结合所模拟出的水系网，具体分析了元素在其中的迁移、扩散情况，给出了正问题和反问题的计算结果。结果表明，正、反问题的求解具有一致性，方法是有效、可行的。  相似文献   

On the field-aligned currents pattern formation in the magnetosphere     

P. Nenovski  D. Danov  A. Bochev   《Journal of Atmospheric and Solar》2003,65(16-18):1369-1383

  相似文献   

济阳坳陷稀土元素特征及其在物源对比中的应用   总被引：6，自引：1，他引：6  

陈庆春  吴智平李伟 《地质论评》2003,49(6):622-629

物源是控制沉积物中REE组成最主要的因素，济阳坳陷区岩石稀土元素特征表明：①济阳坳陷古生界与华北地台其他地区同时代地层岩石的REE分布特征具有极大的相似性，这体现了晚古生代济阳坳陷区所处的整个华北地台区为一稳定的克拉通沉积盆地，地层横向分布稳定，具有一致的物源和构造背景；②济阳坳陷古生界为中生界的物源，反映了济阳坳陷区由古生代稳定地台型沉积到中生代山间盆地沉积的转变，中生代洼陷区的沉积主要来自对附近凸起区古生代地层的剥蚀；③新生界样品与中生界样品的REE分布模式具有很大的相似性，从一个侧面反映了济阳坳陷中生代与新生代的构造格局的转变，中生代接受沉积的部分洼陷区至古近纪成为供给物源的凸起区。  相似文献   

Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses   总被引：9，自引：0，他引：9  

Stephen M. Eggins 《Geostandards and Geoanalytical Research》2003,27(2):147-162

A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis.  相似文献   

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1     

William J. Chazey III  Clive R. Neal  Jinesh C. Jain  William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).  相似文献   

富水水库中微生物成因的显微针铁矿及其对微量元素的富集   总被引：3，自引：0，他引：3       下载免费PDF全文

车遥  胡宝林  夏林  孙振亚  王利忠 《地球学报》2003,24(2):161-166

通过对湖北省富水水库坝基渗漏水及其析出物的研究，探讨了现代沉积环境（水库）中显微铁矿物形成的机理及微生物在铁的生物矿化中的作用和意义。对析出物中微量元素的富集特征也进行了初步研究。用化学分析方法测试出坝基渗漏水中阳离子以Ca^2 、Mg^2 、K^ 、Na^ 为主，Fe^2 和Fe^3 含量极少，阴离子以HCO3^-为主。析出物的化学成分以铁的氧化物为主。采用X射线衍射、差热分析、红外光谱和穆斯堡尔谱，以及透射电镜和扫描电镜等测试手段，分析研究了析出物的物相和形貌特征。析出物的主要矿物相为针铁矿、石英、伊利石、蒙脱石和微量方解石，呈弱结晶状态。由析出物中显微针铁矿特殊的形貌特征及其特征的穆斯堡尔谱图推测出富水水库沉积环境中显微针铁矿是由铁细菌形成。ICP－MS测试测试结果表明，析出物中不仅富集了铁，还富集了Yb、Pb、Dy、Zn、Co、Be、Eu、Sm和Tb等微量元素。微量元素的富集是微生物与显微针铁矿共同作用的结果。  相似文献