Determination of Halogens (F, Cl, Br, I), Sulfur and Water in Seventeen Geological Reference Materials   总被引：5，自引：0，他引：5  

Agnès Michel  Benoît Villemant 《Geostandards and Geoanalytical Research》2003,27(2):163-171

Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l⁻¹. Bromine and I were measured by ICP-MS with detection limits of 1 μg l⁻¹ for Br and 0.1 μg l⁻¹ for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg⁻¹ for F and Cl, 15 mg kg⁻¹ for S, 0.2 mg kg⁻¹ for Br and 0.02 mg kg⁻¹ for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H₂O degassing, reduction on zinc at 1000 °C and H₂ manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   

Origin and tectonic significance of a Mesozoic multi-layer over-thrust system within the Yangtze Block (South China)   总被引：21，自引：0，他引：21  

Dan-Ping Yan  Mei-Fu Zhou  Hong-Lin Song  Xin-Wen Wang  John Malpas 《Tectonophysics》2003,361(3-4):239-254

In the Yangtze Block (South China), a well-developed Mesozoic thrust system extends through the Xuefeng and Wuling mountains in the southeast to the Sichuan basin in the northwest. The system comprises both thin- and thick-skinned thrust units separated by a boundary detachment fault, the Dayin fault. To the northwest, the thin-skinned belt is characterized by either chevron anticlines and box synclines to the northwest or chevron synclines to the southeast. The former structural style displays narrow exposures for the cores of anticlines and wider exposures for the cores of synclines. Thrust detachments occur along Silurian (Fs) and Lower Cambrian (Fc) strata and are dominantly associated with the anticlines. To the southeast, this style of deformation passes gradually into one characterized by chevron synclines with associated principal detachment faults along Silurian (Fs), Cambrian (Fc) and Lower Sinian (Fz) strata. There are, however, numerous secondary back thrusts. Therefore, the thin-skinned belt is like the Valley and Ridge Province of the North American Applachian Mountains. The thick-skinned belt structurally overlies the thin-skinned belt and is characterized by a number of klippen including the Xuefeng and Wuling nappes. It is thus comparable to the Blue Ridge Province of Appalachia.The structural pattern of this thrust system in South China can be explained by a model involving detachment faulting along various stratigraphic layers at different stages of its evolution. The system was developed through a northwest stepwise progression of deformation with the earliest delamination along Lower Sinian strata (Fz). Analyses of balanced geological cross-sections yield about 18.1–21% (total 88 km) shortening for the thin-skinned unit and at least this amount of shortening for the thick-skinned unit. The compressional deformation from southeast to northwest during Late Jurassic to Cretaceous time occurred after the westward progressive collision of the Yangtze Block with the North China Block and suggests that the orogenic event was intracontinental in nature.  相似文献   

The anisotropy of magnetic susceptibility in biotite, muscovite and chlorite single crystals     

Ftima Martín-Hernndez  Ann M. Hirt 《Tectonophysics》2003,367(1-2):13-28

The anisotropy of magnetic susceptibility (AMS) of single crystals of biotite, muscovite and chlorite has been measured in order to provide accurate values of the magnetic anisotropy properties for these common rock-forming minerals. The low-field AMS and the high-field paramagnetic susceptibility are defined. For the high-field values, it is necessary to combine the paramagnetic deviatoric tensor obtained from the high-field torque magnetometer with the paramagnetic bulk susceptibility measured from magnetization curves of the crystals. This leads to the full paramagnetic susceptibility ellipsoid due to the anisotropic distribution of iron cations in the silicate lattice. The ellipsoid of paramagnetic susceptibility, which was obtained for the three phyllosilicates, is highly oblate in shape and the minimum susceptibility direction is subparallel to the crystallographic c-axes. The anisotropy of the susceptibility within the basal plane of the biotite has been evaluated and found to be isotropic within the accuracy of the instrumental measurements. The degree of anisotropy of biotite and chlorite is compatible with previously reported values while for muscovite the smaller than previously published values. The shape of the chlorite AMS ellipsoid for all the samples is near-perfect oblate in contrast with a wide distribution of oblate and prolate values reported in earlier studies. Reliable values are important for deriving models of the magnetic anisotropy where it reflects mineral fabrics and deformation of rocks.  相似文献   

Early formed regional antiforms and synforms that fold younger matrix schistosities: their effect on sites of mineral growth     

T. H. Bell  A. P. Ham  K. A. Hickey 《Tectonophysics》2003,367(3-4):253-278

In the metamorphic cores of many orogenic belts, large macroscopic folds in compositional layering also appear to fold one or more pervasive matrix foliations. The latter geometry suggests the folds formed relatively late in the tectonic history, after foliation development. However, microstructural analysis of four examples of such folds suggests this is not the case. The folds formed relatively early in the orogenic history and are the end product of multiple, near orthogonal, overprinting bulk shortening events. Once large macroscopic folds initiate, they may tighten further during successive periods of sub-parallel shortening, folding or reactivation of foliations that develop during intervening periods of near orthogonal shortening. Reactivation of the compositional layering defining the fold limbs causes foliation to be rotated into parallelism with the limbs.Multiple periods of porphyroblast growth accompanied the multiple phases of deformation that postdated the initial development of these folds. Some of these phases of deformation were attended by the development of large numbers of same asymmetry spiral-shaped inclusion trails in porphyroblasts on one limb of the fold and not the other, or larger numbers of opposite asymmetry spirals on the other limb, or similar numbers of the same asymmetry spirals on both limbs. Significantly, the largest disparity in numbers from limb to limb occurred for the first of these cases. For all four regional folds examined, the structural relationships that accompanied these large disparities were identical. In each case the shear sense operating on steeply dipping foliations was opposite to that required to originally develop the fold. Reactivation of the folded compositional layering was not possible for this shear sense. This favoured the development of sites of approximately coaxial shortening early during the deformation history, enhancing microfracture and promoting the growth of porphyroblasts on this limb in comparision to the other. These distributions of inclusion trail geometries from limb to limb cannot be explained by porphyroblast rotation, or folding of pre-existing rotated porphyroblasts within a shear zone, but can be explained by development of the inclusion trails synchronous with successive sub-vertical and sub-horizontal foliations.  相似文献   

闪长岩强风化带做高层建筑天然地基的可行性研究   总被引：1，自引：0，他引：1  

尚敏  王清  樊祜传 《岩土力学》2003,(Z1)

借助于中国工商银行山东省分行营业办公楼的工程实践,将常规勘察与原位测试相结合,运用野外钻探、室内试验、原位测试多种手段,对闪长岩强风化带的物理力学性质进行了测试分析和深入地研究,并通过对承载力、沉降变形的验算,得出其作为高层建筑的天然地基是可行的。实践证明,与桩基础处理方案相比,节省资金近200万元,大大加快了施工进度,减少了基础施工难度,取得了巨大的经济效益与社会效益;同时,也提出了研究岩石风化带所遇到的问题:由于采取原状试样及制样难,导致对其物理力学性质了解不够。  相似文献   

对目前岩石“全曲线”测试的若干看法   总被引：1，自引：0，他引：1  

马世民  马宇博 《岩土力学》2003,(Z1)

从电液伺服岩石压力试验机工作机理的角度,对目前岩石应力-应变全过程曲线(以下简称“全曲线”)测试中的一些问题进行了分析,提出了自己的看法,目的是为了解决“全曲线”测试的2个问题,即如何测出“全曲线”;如何使测出的“全曲线”真实反映岩石的力学特性,并将其用到工程中。  相似文献   

长效振弦式锚索测力计应用研究   总被引：1，自引：0，他引：1  

王清标  吕爱钟  邓铁六 《岩土力学》2003,(Z1)

介绍了长效振弦式锚索测力计传感器的工作原理、结构特点、技术性能和配套仪器,并对主要相关技术的应用研究成果作了论述:(1)弱激发电路解决频率不一致问题;(2)微小变形原则解决长期稳定性问题;(3)新数学模型提高了传感器准确度,二次仪表提高了传感器准确度。  相似文献   

兴山县龙王嘴边坡稳定性分析与加固设计     

傅旭东  邹勇  邵中勇 《岩土力学》2003,(Z2)

龙王嘴边坡系坡高达70 m、坡角达70 °的高陡岩质边坡。分析了宜-秭公路石峡段龙王嘴高边坡变形的地质条件,在定量评价龙王嘴高边坡稳定性的基础上,进行了该高边坡的施工图加固设计。根据其特点将350 m长的坡段分为A,B,C三个区,分别采取预应力锚索与锚杆加固、挂网喷射混凝土支护和喷射混凝土支护等措施,实践证明,工程治理效果良好。  相似文献   

Fractal and Multifractal Modeling of Hydrothermal Mineral Deposit Spectrum： Application to Gold Deposits in Abitibi Area, Ontario, Canada   总被引：2，自引：0，他引：2  

ChengQiuming 《中国地质大学学报(英文版)》2003,14(3):199-206

A number of fractal/multifractal methods are introduced for quantifying the mineral de-lmsit spectrum which include a number-size, grade-tonnage model, power spectrmn model,multi-fractal model and an eigeavalue spectrmn model The first two models characterize mineral deposits spec-tra based on relationships among the measures of mineral deposits.These include the number of deposits,size of deposits,concentration and volume of mineral deposits.The last three methods that deal with the spatial-temporal spectra of mineral deposit studies are all expected to be popularized in near future.A case study of hydrothermal gold deposits from the Abitibi area,a world-class mineral district is used to demonstrate the principle as well as the applications of methods proposed in this paper,It has been shown that fractal and multifractal models are generally applicable to modeling of mineral deposits and occurrences.Clusters of mineral deposits were identified by several methods including the power spectral eral deposits in the Timmins and Kirkland Lake camps.  相似文献   

Theory and Method of Mineral Resource Prediction Based on Synthetic Information     

WangShicheng YeShuisheng ZhouDongdai 《中国地质大学学报(英文版)》2003,14(3):207-214

Metallogenic prognosis of synthetic information uses the geological body and the miaeral resource body as a statistical unit to interpret synthetically the information of geology, geophysics, geo-chemistry and remote sensing from the evolution of geology and puts all the information into one entire system by drawing up digitalized interpretation maps of the synthetic information. On such basis, differ-ent grades and types of mineral resource prospecting models and predictive models of synthetic informa-tion can be established. Hence, a new integrated prediction system will be formed of metallogenic prog-nosis (qualitative prediction), mineral resources statistic prediction (determining targets) and mlaeral resources prediction (determining resources amount).  相似文献