海水中一氧化氮的极谱法测定     

任春艳  张正斌  邢磊  刘春颖  刘莲生 《中国海洋大学学报(自然科学版)》2003,33(5):801-808

本文首次采用 Nafion和 Co(salen) /Nafion修饰铂电极测定海水中的 NO,对实验条件进行了选择 ,确定了最佳实验条件 ,即反应池通氮除氧 30 min,富集时间为 4min。同时用线性扫描法对海水中的 NO进行测定 ,测得海水中 NO的浓度与氧化峰电流之间有一定线性关系。对 Nafion修饰电极而言 ,线性范围 1～ 76.9μmol/L,R2 =0 .991 6,检出限为 1 μmol/L。同时对 2种方法修饰的铂电极进行了比较 ,即当 NO浓度在 1 0 -6mol/L数量级时 2种电极基本上无差别 ,而在 1 0 -7mol/L数量级时 Co(salen) /Nafion修饰电极要明显优于 Nafion修饰电极  相似文献   

塞曼石墨炉原子吸收法直接测定海水中的铬     

杨秀环  李攻科  唐宝英  张展霞 《热带海洋学报》1991,(3)

海水基体对Cr有增感作用。本文研究了抗坏血酸、柠檬酸三铵、酒石酸、乙酸铵等有机基体改进剂对消除基体干扰效果。前二者均有效地消除基体干扰,但1％抗坏血酸 1％柠檬酸三铵混合试剂的效果更好,它不仅可以消除基体干扰,还可降低背景及噪声,Cr的吸收峰也较平滑。本法准确,相对偏差在0.7—4.4％范围内。回收率在92—109％范围内。若海水Cr含量低于定量下限时,可采用多次进样法。  相似文献   

Geographic variability in trace element levels in Spartina alterniflora     

J.E. Drifmeyer  B. Redd 《Estuarine, Coastal and Shelf Science》1981,13(6):709-716

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The effect of submarine groundwater discharge on nutrient and salinity regimes in a coastal lagoon off Perth, Western Australia     

R. E. Johannes  C. J. Hearn 《Estuarine, Coastal and Shelf Science》1985,21(6):789-800

Submarine groundwater discharge (SGD) into a coastal lagoon off Perth, Western Australia, contains nitrate and silicate in concentrations two orders of magnitude higher than those of the receiving waters. This discharge delivers enough nitrate to replace that dissolved in the lagoon water mass about every eight days and enough silicate to replace the lagoon silicate in about 48 days. The delivery rate of nitrate nitrogen by SGD is equal to about 48% of that required for observed growth rates of lagoon macrophytes. Surface salinity is lower close to the shore as a result of SGD. During calm conditions a salinity front was observed in the lagoon, with a nearshore pool of nutrient-enriched water floating above the more saline ocean water.  相似文献   

Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

2000年夏季莱州湾生态环境要素的分布特征   总被引：1，自引：0，他引：1  

高会旺  吴德星  白洁  石金辉  李正炎  江文胜 《中国海洋大学学报(自然科学版)》2003,33(2):185-191

论文依据 2 0 0 0年夏季 8月 2 9日至 9月 2日莱州湾的 1次综合性生态环境调查资料 ,给出了表、中、底 3层的平均温度、盐度、主要营养盐浓度及其比例和叶绿素 a浓度 ,分析了莱州湾的温盐结构、主要营养盐和叶绿素 a的分布特征。由于莱州湾的水深较浅 ,各要素的垂直分布都比较均匀。生态环境要素的水平分布表现为小清河口为高温、低盐、高营养盐和高叶绿素 a浓度区 ,小清河口东测的湾顶区域为高温、高盐、相对低的营养盐和叶绿素 a浓度区。此次观测到的盐度较 1997年以前有明显升高。莱州湾各层平均的 N/ P和 Si/ N分别为 16.73和 1.67,都比 1998～ 1999年渤海中部的值大 ,但 N/ P比 1992 ,1995和 1996年莱州湾的 N/ P明显偏低。叶绿素 a浓度与硅酸盐浓度之间有较好的相关关系 (α=0 .0 1) ,表、中、底 3层叶绿素 a浓度同硅酸盐浓度的线性相关系数分别为 :0 .5 4 ,0 .68和 0 .67  相似文献   

海水中低含量铵氮的高灵敏度荧光法测定   总被引：3，自引：0，他引：3  

余翔翔  郭卫东 《海洋科学》2007,31(4):37-41

提出了一种改进的、可测定海水中低含量铵氮的高灵敏度荧光分析方法。其原理是在硼酸缓冲溶液的作用下,海水中的铵氮与邻苯二甲醛(OPA)发生衍生化反应,通过测定生成的荧光产物来确定水体中铵氮的浓度。方法的检测限极低(0.002 5μmol/L),重现性好,且水样用量少(10 mL),适用于海水中溶解有机物的光铵化研究及其他低铵含量水样的测定。  相似文献   

Are invasive species most successful in habitats of low native species richness across European brackish water seas?   总被引：5，自引：0，他引：5  

Marjo Paavola  Sergej Olenin  Erkki Leppkoski 《Estuarine, Coastal and Shelf Science》2005,64(4):738-750

European brackish water seas (Baltic Sea, Black Sea and Sea of Azov, Caspian Sea) are subject to intense invasion of non-indigenous species (NIS). In these seas, salinity is the most important range limiting factor and native species seem to reach a minimum species richness at intermediate salinities. This trend, revealed by Remane in 1934 and later on confirmed by many other scientists, was compared to the salinity range of already established NIS in the European brackish water seas. It turned out that most NIS are well adapted to the salinities holding lowest native species richness, already in their native area, and that NIS richness maximum in brackish water seas occurs in the salinity intervals of native species richness minimum. A predictable pattern in the salinity range of NIS can be used as a tool in initial risk assessment of future invasions in brackish water seas, especially when mapping highly potential donor and recipient areas. A product of empty niches, suitable environmental conditions, and availability of proper vectors might be the most effective predictor for the invasibility of brackish water areas.  相似文献   

黄海表层盐度年变化的谐波分析     

沈佩玉 《海洋预报》1994,11(4):59-63

本文采用黄海（３５°Ｎ以北，１２４°Ｅ以西）断面调查资料，对海域表层盐度年变化进行谐波分析，讨论了年波与半年波位相与振幅在海区的分 布不同水系消长及运动的关系。  相似文献   

强壮箭虫对温度、盐度的耐受性研究   总被引：7，自引：0，他引：7  

刘青  曲晗  张硕 《海洋湖沼通报》2007,(1):111-116

研究强壮箭虫对突变温度、突变盐度和渐变温度、渐变盐度的耐受性.结果表明:水温由15℃突变到1℃时,存活率为75%;水温由15℃突变为30℃时,存活率仅为5%.求得24h急性半致死温度上限为27.2℃.水温从20℃逐渐上升至25、30、35℃,存活率分别为85 %、10 %、0 %;水温从20℃逐渐下降至15、10、5℃,其存活率分别为 100 %、95 %和80 %.盐度从31突变为20、40,箭虫的存活率均为100%,随着盐度突变幅度的增大,强壮箭虫的存活率呈降低趋势.求得24h急性半致死盐度上限为45,24h急性半致死盐度下限为13.3.盐度逐渐从31上升到46、 52,其存活率由90%下降到0%;盐度逐渐从31降到13、6,其存活率由95%下降到0%.求得间隔12h半致死渐变盐度上限为48.7,半致死渐变盐度下限为9.3.根据实验结果,强壮箭虫应属喜冷广温种和近岸广盐种.  相似文献