Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site     

Taoze LIU Yuangen YANG Bangyu LIU Xiangyang BI Feili LI 《中国地球化学学报》2006,25(B08):41-42

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.  相似文献   

Heavy metal contamination in the sediment of the Second Songhua River   总被引：1，自引：0，他引：1  

Chunye LIN Mengchang HE Baixing YAN Xiangchun QUAN Yuxiang ZHOU Wei GUO Zhifeng YANG 《中国地球化学学报》2006,25(B08):118-119

The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations （A1, Fe, Mg, Ca, K, Na） in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc.  相似文献   

The concentration and distribution of different mercury species in the water columns and sediment of Aha Lake     

Weiyang BAI Xinbin FENG Xuewu FU Tianrong HE Guangle QIU 《中国地球化学学报》2006,25(B08):154-154

In order to find out whether Aha Lake was polluted by the acid mining waste water or not, the concentration and distribution of different mercuryspecies in the water columns and sediment profile collected from Aha Lake were investigated. It was found that discernible seasonal variation of different mercury species in water body were obtained in the Aha Reservoir. With regards to the whole sampling periods, the concentrations of HgP in the Aha Reservoir water body were evidently correlated to the concentrations of total mercury, showing that total mercury was mostly associated with particle mercury. The concentrations of methylmercury in water body were also evidently correlated to the concentrations of dissolved mercury. The dissolved mercury evidently affects the distribution and transportation of methylmercury. However, there is no correlation between methylmercury and total mercury. The dissolved mercury, reactive mercury, dissolved methylmercury levels in the water body of high flow period were much higher than those in low flow period. The distribution, speciation and levels of mercury within the Aha Reservoir water body were governed by several factors, such as the output of river, the release of sediment . Discernible seasonal variation of total mercury and methylmercury in porewater was described during the sampling periods, with the concentrations in high flow period generally higher than those in low flow period. The methylmercury in pore water column was evidently correlated to that of the sediment. The results indicated that highly elevated MeHgD concentrations in the porewater were produced at the depths from 2 to 5 cm in the sediment profile, and decreased sharply with depth. A positive correlation has been found between MeHgD formation and sulfate reducing bacterial activity. These highly elevated concentrations of MeHgD at the intersurface between waters and sediments suggest a favorable methylation condition. Moreover,  相似文献   

The sequence of sediment behaviour during wave-induced liquefaction   总被引：4，自引：0，他引：4  

B. MUTLU SUMER  FIGEN HATIPOGLU  JØRGEN FREDSØE  S. KAAN SUMER 《Sedimentology》2006,53(3):611-629

This paper presents the results of an experimental investigation of the complete sequence of sediment behaviour beneath progressive waves. The sediment was silty with d ₅₀ = 0.060 mm. Two kinds of measurements were carried out: pore-water pressure measurements (across the sediment depth), and water-surface elevation measurements. The process of liquefaction/compaction was videotaped from the side simultaneously with the pressure and water-surface elevation measurements. The video records were then analysed to measure: (i) the time development of the mudline, (ii) the time development of liquefaction and compaction fronts in the sediment and (iii) the characteristics of the orbital motion of the liquefied sediment including the motion of the interface between the water body and the sediment. The ranges of the various quantities in the tests were: wave height, H  = 9–17 cm, wave period, T  = 1.6 sec, water depth = 42 cm, and the Shields parameter = 0.34–0.59. The experiments reveal that, with the introduction of waves, excess pore pressure builds up, which is followed by liquefaction during which internal waves are experienced at the interface of the water body and the liquefied sediment, the sequence of processes known from a previous investigation. This sequence of processes is followed by dissipation of the accumulated excess pore pressure and compaction of the sediment which is followed by the formation of bed ripples. The present results regarding the dissipation and compaction appear to be in agreement with recent centrifuge wave-tank experiments. As for the final stage of the sequence of processes (formation of ripples), the ripple steepness (normalized with the angle of repose) for sediment with liquefaction history is found to be the same as that in sediment with no liquefaction history.  相似文献   

重力取样器取样技术研究          下载免费PDF全文

毛志新  刘宝林  夏柏如 《探矿工程》2006,33(2):52-53,62

在湖泊环境研究中，淤泥质沉积物取样是一项很重要的工作，样品的取心率和原状性直接影响了环境研究的结果。重力取样器是获取湖泊、水库等水域浅层湖泊沉积物的一种经济有效、操作简单的常用工具。因此研究重力取样器的取样技术对环境研究具有积极的意义。研究了重力取样器的取样技术，并在此基础上成功设计了一种便携式的重力式取样器，非常适合环境研究机构的沉积物取样工作。  相似文献   

Microwave-assisted extraction of organochlorine pesticides from sediments and determination by gas chromatograph with electron capture detection     

Rama Mohan Kurakalva Narasimha Murthy Nyasavajhala Phani Homeshwari Mamidi Venkata Anjaiah Kanukuntla 《中国地球化学学报》2006,25(B08):202-203

A simple and rapid procedure to extract organochlorine pesticides （OCPs） from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone （1 ： 1, v/v）. The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate （80 ： 20, v/v） and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent,  相似文献   

Speciation analysis and significance of ecological geochemistry     

Yaping WANG Chunxue XU Ziyi AN Suming WANG 《中国地球化学学报》2006,25(B08):205-205

Different species of one element have different activities, so it has different effects on environment and human health. To analyze qualitatively and quantitatively the speciation of a special element in sample, which is the important basis for appraising the toxicity and studying the rule of transfer and translation of elements. Since the 1970＇s, the scheme of sequential extraction has already been used at many laboratories both at home and abroard, to get the information about heavy metals＇ activity in polluted soils. Because this method has the experimental nature, many schemes of problem has taken place, the absence of consistency of these sequential extraction have been formed. Thus the complexity of the schemes, the lack of selectivity of reagent, the lack of quality control, the result mainly related to the extraction scheme used, and so on. In the face of these problems, the study of experimental methods of sequential extraction on three different soils, sediment in Dongting Lake, soil in Jiangsu Province and loess in Shanxi Province was made. Reference materials of heavy metal speciation following sequential extraction in soil and sediment had been developed. Nowadays two kinds of sequential extraction methods which are widely used are BCR （three steps） and improved Tessier methods （seven steps）. Based on three steps of BCR, water-soluble speciation and the residual speciation were increased in our research. BCR701 was determined eight times at different laboratories using BCR three steps. The results showed that determined data obtained eight times were identical to the standard value, and it is indicated that this method has good reproducibility. The stability and homogeneity experiments indicated that the preparation of three types of candidates accorded with our requirements. Eight laboratories had afforded the determined values of 12 heavy metal elements （Cu, Pb, Zn, Mn, Co, Ni, Cd, Cr, Mo, As, Sb, Hg, Se et al.） using BCR three steps. Also, these three candidates afforded the determined values by seven steps, and 12 laboratories had participated.  相似文献   

Changes to cadmium associations in canal sediments on drying and oxidation     

Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.  相似文献   

Influence of humic acid on bioavailability of heavy metals in sediments     

Wenhong FAN Jun CHEN 《中国地球化学学报》2006,25(B08):261-261

The mimetic ocean environment and chemical method were used to research the bioavailability effect of humic acid on five heavy metals in sediment, including Cd, Cu, Zn, Pb and Ni. The sediment was separated into four containers with artificial seawater, and each of them had different concentrations of humic acid. The values of concentrations covered the whole range found in natural sediment （0.1%-10%）. According to the 48 hours LC50 of clam and distribution coefficient, metals were added in artificial seawater, and their speciation was determined at first and then after two days＇ incubation. It was found the bioavailability of heavy metals was reduced in the presence of humic acid. The obvious negative effect on Zn was observed, but the influence on Cd was not remarkable. In addition, the contents of Pb and Ni increased obviously in organic phase, and they are correlative with the concentrations of humic acid.  相似文献   

科尔沁沙地土地利用与耕作方式对土壤风蚀的影响   总被引：2，自引：1，他引：2  

张华  季媛  苗苗 《干旱区地理》2006,29(6):861-866

土壤风蚀造成的直接生态后果是土地资源的退化。在春播前两次沙尘暴事件中,对科尔沁沙地几种具有代表性的土地类型的土壤风蚀量及土壤特性进行了野外测定、分析,结果表明:(1)在同一沙尘暴天气下,由于土地利用和耕作方式的不同,土壤风蚀量存在着差异,新垦农地和翻耕农地的风蚀量显著高于未垦草地、免耕农地和麻黄地;免耕农地则与未垦草地的风蚀量相差不大,风蚀危害较轻;麻黄地几乎不受风蚀侵害。新垦农地、翻耕农地、免耕农地、未垦草地、麻黄地两次观测的土壤风蚀量平均值依次为24.59、15.60、2.26、1.46和0.22 g/h.cm2。(2)基于土壤特性计算的土壤退化指数结果表明,新垦农地和翻耕农地发生了较为严重的退化。  相似文献