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251.
Sewage sludges are dewatered end products of human sewage waste and are recognised repositories of organic pollutants and heavy metals. They may be considered targets for economic extraction of Au because of the documented Au content of sewage sludges worldwide which are of the order of some ore deposits currently mined for Au. They are also highly nutrient enriched (nitrogen and phosphorus) and therefore amenable to use as agricultural fertiliser or as covers for mine wastes. The sewage of Melbourne, Australia, a city with a current population of 3.3 million, was stockpiled in large, closed, lagoonal tanks from 1898 until 1980. In 1995 Echidna Mining, an Australian gold exploration company, acquired the exploration rights to the ground surrounding the historic sludge reserves and commenced a program of resource evaluation, utilising RNAA, INAA, GFAAS, ICP–MS and FLAAS to determine 31 elements, including Au, Ag, Sb, As, Cd, Hg, Zn, Cu, and Pb. The study was initiated to determine Au, Ag and other metal variations in both space and time and to investigate the economics of chemical extraction of the precious metals. A total of 149 samples from over 50 hand-auger drillholes to a depth up to 4 m have been analysed from the stockpiles, with Au assays yielding remarkably consistent results. Average grades of 0.77 g/t Au and 18.8 g/t Ag have been documented for a measured resource of 770,000 m3 (of an estimated 1.6–2.5 million m3 contained) at a density of 1.0 g/cm3 and an average moisture content of around 40%. Laboratory-based extractive metallurgy of the Werribee sludges has demonstrated that Au, Ag and Zn can be removed with relative ease by heap-leaching using modified conventional technology, albeit with prohibitive reagent consumption. The extraction of the precious metals also results in the variable removal of contaminant metals such as Cd, As, Sb, Hg and Cr which may render the sludges fit for sale as agricultural fertiliser, provided organic pollutants and pathogenic organisms are below governmental environmental protection limits, an area beyond the scope of this paper. Another potential avenue of the exploitation of sewage sludges is discussed: that of the utilisation of sludges to extract contaminant metals from waste water and contaminated mine waters, which we demonstrate on pure aqueous synthetic samples. This paper presents a study of the exploitation of an historic sludge resource for its contained Au and residue post-metal extraction. 相似文献
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L. W. Sinton 《新西兰海洋与淡水研究杂志》2013,47(3-4):317-326
A baseline groundwater quality survey of 120 household wells in an unsewered area at Yaldhurst, near Christchurch, was carried out between September and December, 1976. Ammonia‐N levels were below the detection limit (0.02 g m‐3) in all samples. Nitrate‐N, conductivity, and chloride levels tended to vary according to well depth and location, being lower in the deeper wells and in wells located in an area of shallow, stony soils. Approximately 33% of the wells contained coliform bacteria, faecal coliform bacteria or faecal streptococci. A subset of 25 wells was sampled fortnightly from January to August 1977. From January to June, mean nitrate‐N and conductivity levels remained stable at approximately 1.5 g m‐3 and 11.2 mS m‐1 respectively. An increase in these levels to 3.3 g m‐3 and 15.8 mS m‐1 in July‐August corresponded with a rise in the water table. Leaching losses from soils probably accounted for most of the nitrate entering the Yaldhurst aquifers, the contribution by septic tank systems being estimated at 20–30%. No direct evidence of contamination of the wells by septic tank effluent was found, although 23 of the 25 wells exhibited intermittent contamination by indicator bacteria throughout the 8 month sampling programme. Although a localised health hazard may exist, septic tank systems in the area were not considered likely to constitute a health threat to the confined aquifers underlying Christchurch city. 相似文献
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UASB和ABR在常温下处理生活污水的性能比较研究 总被引:1,自引:0,他引:1
沿海城市生活污水的排放,对海洋环境有着重要影响。通过试验,在常温条件下研究了升流式厌氧污泥床反应器(Upflow Anaerobic Sludge Blanket Reactor,简称UASB)与厌氧折流板反应器(Anaerobic Baffled Reactor,简称ABR)处理生活废水的性能。试验结果表明:UASB与ABR对生活污水都有良好的处理效果,在HRT较长时,ABR反应器对COD和SS的去除效果优于UASB反应器;而当HRT缩短,小于12 h,UASB反应器内上升流速增加,改善了对COD的去除效果。ABR和UASB反应器对COD的去除效果都随温度的降低而降低。 相似文献
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